The unique structure of [(C4H9)4N]3[Pb(NO3)5]—one step forward in understanding transport properties in tetra-n-butylammonium-based solid electrolytes

Structural Chemistry - The crystal and molecular structure of tris(tetrabutylammonium) pentanitratoplumbate(II) was determined and characterized by single-crystal and powder X-ray diffraction and...     

Electret Materials Based on Fluoropolymers Modified with Vanadium- and Phosphorus-Containing Structures

Russian Journal of Applied Chemistry - Organo-inorganic composite materials based on films of polytetrafluoroethylene and tetrafluoroethylene–hexafluoropropylene copolymer, modified with...     

Precipitation of yellowcake from pregnant regenerate by various reagents

Journal of Radioanalytical and Nuclear Chemistry - In the present paper the development and application of a novel somatostatin radioimmunoassay are described. 125I-labeling of...     

On Restrictions and Extensions of the Besov and Triebel-Lizorkin Spaces with Respect to Lipschitz Domains

The restrictions B^s_pq() and F^s_pq() of the Besov and Triebel–Lizorkinspaces of tempered distributions B^s_pq(Rⁿ) and F^s_pq(Rⁿ) to Lipschitzdomains Rⁿ are studied. For general values of parameters (sR,p>0, q>0) a ‘universal’ linear bounded extensionoperator from B^s_pq() and F^s_pq() into the corresponding spaceson Rⁿ is constructed. The construction is based on a new variantof the Calderón reproducing formula with kernels supportedin a fixed cone. Explicit characterizations of the elementsof B^s_pq() and F^s_pq() in terms of their values in are also obtained.     

New hydrophobic L‐amino acid salts: maleates of L‐leucine,L‐isoleucine and L‐norvaline

Crystals of maleates of three amino acids with hydrophobic side chains [L‐leucenium hydrogen maleate, C₆H₁₄NO₂⁺·C₄H₃O₄⁻, (I), L‐isoleucenium hydrogen maleate hemihydrate, C₆H₁₄NO₂⁺·C₄H₃O₄⁻·0.5H₂O, (II), and L‐norvalinium hydrogen maleate–L‐norvaline (1/1), C₅H₁₁NO₂⁺·C₄H₃O₄⁻·C₅H₁₂NO₂, (III)], were obtained. The new structures contain C₂²(12) chains, or variants thereof, that are a common feature in the crystal structures of amino acid maleates. The L‐leucenium salt is remarkable due to a large number of symmetrically non‐equivalent units (Z′ = 3). The L‐isoleucenium salt is a hydrate despite the fact that L‐isoleucine is a nonpolar hydrophobic amino acid (previously known amino acid maleates formed hydrates only with lysine and histidine, which are polar and hydrophilic). The L‐norvalinium salt provides the first example where the dimeric cation L‐Nva...L‐NvaH⁺ was observed. All three compounds have layered noncentrosymmetric structures. Preliminary tests have shown the presence of the second harmonic generation (SGH) effect for all three compounds.     

Precipitation of uranium from nitrate-sulfuric eluates by aqueous ammonia solution

The process of uranium precipitation from nitrate-sulfuric acid eluates by a 25% aqueous solution of ammonia was investigated. The effect of precipitation pH value on the impurity composition, particle size and bulk density of the yellow cake was studied. It was found, that precipitation should be carried out at pH 6.7 to obtain a high-purity concentrate. The method makes it possible to obtain a concentrate with an uranium content of 71.79%, a high bulk density of 970 kg m^?3, an average particle diameter of 10.3 μm. The impurity composition of concentrate obtained at pH 6.7 meets the requirements of ASTM C967-13.     

Littlewood–Paley Theory and Function Spaces with Alocp Weights

Characterizations via convolutions with smooth compactly supported kernels and other distinguished properties of the weighted Besov–Lipschitz and Triebel–Lizorkin spaces on ℝⁿ with weights that are locally in A_p but may grow or decrease exponentially at infinity are investigated. Square–function characterizations of the weighted L^p and Hardy spaces with the above class of weights are also obtained. A certain local variant of the Calderón reproducing formula is constructed and widely used in the proofs.