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1.
J. Kircher M. Cardona M. Alouani S. Gopalan O. Jepsen O. K. Andersen
E. Kaldis
J. Karpinski S. Rusieki 《Physica C: Superconductivity and its Applications》1992,200(3-4):413-417We report results of ellipsometric measurements of the dielectric tensor of YBa2Cu4O8 as well as calculations employing density functional theory in the local density approximation (LDA). For the computation of the one-electron eigenvalues and states the linear-muffin-tin-orbital method (LMTO) was used. Measured and calculated results show good agreement. In particular, the calculation predicts different band structures for YBa2Cu3O7 and YBa2Cu4O8 in the vicinity of the Fermi energy which lead to significant differences in the optical spectra. One such difference is a region of small ε2 in the near infrared which is a fingerprint of the high (relative to the top of the highest fully occupied band) Fermi energy as compared to the situation in YBa2Cu3O7. Our experimental results confirm the theoretical findings. 相似文献
2.
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4.
S. V. Meshkov
D. V. Berkov
《Physics letters. A》1992,170(6):448-453We investigate this problem by two methods. In the first one the density of states is determined from its moment expansion. In the second approach an imaginary time Green function obtained by a special world line Monte Carlo algorithm is analytically continued to the real frequency axis. 相似文献
5.
V. I. Karpman
A. G. Shagalov
《Physics letters. A》1991,160(6):538-540The self-focusing described by the nonlinear Schrödinger equation with a higher-order derivative term is investigated numerically. We demonstrate that, depending on the sign before this term, it may lead in the final stage either to defocusing or to a steady homogeneous wave beam. In both cases the transition to the final state is shown to be oscillatory. 相似文献
6.
A. Yu. Khodjamirian
A. G. Oganessian
《Nuclear Physics B》1992,380(3):431-443The leading nonperturbative contribution to the cross section of charm production in two-photon collisions is calculated in QCD. Operator expansion is used and the c-quark interaction with vacuum gluon condensate is taken into account. As a result, the moments of the charm contribution to the photon structure function are obtained. The moments with sufficiently high numbers turn out to be sensitive to the gluon condensate. 相似文献
7.
The deep-inelastic deuteron structure function (SF) F2D in the covariant approach in the light-cone variables is considered. The neutron SF F2n is extracted from the deuteron and proton experimental data taking into account the relativistic deuteron model and the parametrization of F2n is obtained. The effect of the relativistic Fermi motion is estimated to be 6% at x0.7. The extracted neutron SF is used to verify the Gottfried sum rule. It is shown that the violation of the flavour symmetry of the sea can be large with increasing Q2. 相似文献
8.
Allen I. Cohen
Louis Gordon
《Talanta》1961,7(3-4):195-211Studies have been made of the distribution behaviour of tracers with alkaline earth sulphates, using the technique of precipitation from homogeneous solution. The co-precipitation of strontium with barium sulphate and of lead, lanthanum, and yttrium, separately, with barium sulphate, and with strontium sulphate, were investigated. Although there was qualitative correlation between the observed values of the distribution coefficient and the theoretical solubility product ratios for each of the binary systems studied, the divergence between theory and observation was so great that it seems unlikely that there is any quantitative correlation. 相似文献
9.
J. Nasielski S. Heilporn R. Nasielski-Hinkens
B. Tinant
J. P. Declercq 《Tetrahedron》1989,45(24):7795-7804When quinoxaline-N-oxide 1 is reacted with KCN and benzoyl chloride in water (the Reissert reaction) or methanol, the products are 2-,5- and 6- chloroquinoxaline (the latter being the major product: 42±6 %) and small amounts of 2-cyanoquinoxaline. Using three equivalents of trimethylsilyl cyanide instead of KCN, and dichloromethane as the solvent, leads to a 72 % yield of 2-cyanoquinoxaline. The reaction of trimethylsilyl cyanide and benzoyl chloride with 2,3-diphenylquinoxaline-N-oxide 2 leads to an unexpected ring-opening product 13; its structure is based on spectroscopic data and on an X-ray crystallographic analysis. 相似文献
10.
G. Menchi
S. Paganelli
U. Matteoli A. Scrivanti C. Botteghi 《Journal of organometallic chemistry》1993,450(1-2):229-235The unsaturated compounds 1,2-dicarbethoxy-1,2,3,6-tetrahydropyridazine 1 and 1,2-dicarbethoxy-1,2,3,4-tetrahydropyridazine 2 have been hydroformylated and hydrocarbethoxylated in the presence of some well known cobalt, rhodium, palladium and platinum catalysts. The hydroformylation reaction can be tuned by a suitable choice of the catalyst precursor and reaction conditions, thus allowing the synthesis with high selectivity of one of the two possible isomeric aldehydes. The carbonylation reaction is less synthetically useful, since it shows low activity and unsatisfactory chemo- and regio-selectivity. However, the ester 1,2,4-tricarbethoxyhexahydropyridazine 10 can be prepared in good yield from olefin 1 by using the complex [PdCl2(PPh3)2] as the catalyst precursor. 相似文献