首页 | 官方网站   微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   14852篇
  免费   405篇
  国内免费   323篇
数理化   15580篇
  2022年   159篇
  2021年   190篇
  2020年   181篇
  2019年   178篇
  2018年   172篇
  2017年   144篇
  2016年   333篇
  2015年   306篇
  2014年   368篇
  2013年   792篇
  2012年   635篇
  2011年   738篇
  2010年   531篇
  2009年   502篇
  2008年   668篇
  2007年   708篇
  2006年   577篇
  2005年   587篇
  2004年   583篇
  2003年   588篇
  2002年   618篇
  2001年   443篇
  2000年   400篇
  1999年   311篇
  1998年   225篇
  1997年   204篇
  1996年   227篇
  1995年   242篇
  1994年   236篇
  1993年   182篇
  1992年   176篇
  1991年   178篇
  1990年   196篇
  1989年   157篇
  1988年   143篇
  1987年   139篇
  1986年   123篇
  1985年   217篇
  1984年   233篇
  1983年   162篇
  1982年   180篇
  1981年   148篇
  1980年   151篇
  1979年   140篇
  1978年   117篇
  1977年   163篇
  1976年   143篇
  1975年   119篇
  1974年   110篇
  1973年   114篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
2.
Let κ be non-negative integer. The unoriented bordism classes, which can be represented as [RP(ξ^κ)] where ξ^κ is a k-plane bundle, form an ideal of the unoriented bordism ring MO.. A group of generators of this ideal expressed by a base of MO. and a necessary and sufficient condition for a bordism class to belong to this ideal are given.  相似文献   
3.
In this paper we obtain a number of Maharam-type slice integral representations, with respect to scalar measures, for positive projections in Dedekind complete vector lattices and f-algebras. AMS Classification: 47B65, 46A40, 06F25  相似文献   
4.
Molecular electroactive monolayers have been produced from vinylferrocene (VFC) via light-assisted surface anchoring to H-terminated n- and p-Si(1 0 0) wafers prepared via wet chemistry, in a controlled atmosphere. The resulting Si-C bound hybrids have been characterized by means of XPS and AFM. Their performance as semiconductor functionalized electrodes and their surface composition have been followed by combining electrochemical and XPS measurements on the same samples, before and after use in an electrochemical cell. White-light photoactivated anchoring at short (1 h) exposure times has resulted in a mild route, with a very limited impact on the initial quality of the silicon substrate. In fact, the functionalized Si surface results negligibly oxidized, and the C/Fe atomic ratio is close to the value expected for the pure molecular species. The VFC/Si hybrids can be described as (η5-C5H5)Fe2+(η5-C5H4)-CH2-CH2-Si species, on the basis of XPS results. Electrochemical methods have been applied in order to investigate the role played by a robust, covalent Si-C anchoring mode towards substrate-molecule electronic communication, a crucial issue for a perspective development of molecular electronics devices. The response found from cyclic voltammograms for p-Si(1 0 0) functionalized electrodes, run in the dark and under illumination, has shown that the electron transfer is not limited by the number of charge carriers, confirming the occurrence of electron transfer via the Si valence band. The hybrids have shown a noticeable electrochemical stability and reversibility under cyclic voltammetry (cv), and the trend in peak current intensity vs. the scan rate was linear. The molecule-Si bond is preserved even after thousands of voltammetric cycles, although the surface coverage, evaluated from cv and XPS, decreases in the same sequence. An increasingly larger surface concentration of Fe3+ at the expenses of Fe2+ redox centers has been found at increasing number of cv’s, experimentally associated with the growth of silicon oxide. Surface SiO groups from deprotonated silanol termination, induced by the electrochemical treatments, are proposed as the associated counterions for the Fe3+ species. They could be responsible for the observed decrease in the electron transfer rate constant with electrode ageing.  相似文献   
5.
2-Deoxy-2-iodo-glycosylamides have been prepared from a variety of protected d-glucals by their reaction with N-iodosuccinimide and amides. Benzyl protected 2-iodoamides, when treated with sodium hydride and 15-crown-5, gave stable C1 N-linked 2-glycooxazolines as the major products. Silyl protected 2-iodoamides afforded the C1 O-linked 2-glycooxazolines; presumably by the rearrangement of unstable N-acylaziridine intermediates.  相似文献   
6.
7.
The basic features of a chemical measurement   总被引:2,自引:0,他引:2  
  相似文献   
8.
两个回归参数相等性检验一直是统计界感兴趣的问题之一.在这篇文章中,四个检验统计量被用于度量两曲线的差异,在原假设下统计量的分布采用向量数据的重复抽样来逼近,并给出了—些模拟结果.  相似文献   
9.
We report new results on the diffraction properties of photoinduced gratings in InGaAs/InGaAsP MQW structures. The original feature of this device is that the QWs are enclosed in an asymmetric Fabry–Perot microcavity in order to increase the diffraction efficiency. We observe oscillations in the diffraction efficiency due to resonant effects in the microcavity. The experimental spectra are compared with theory. Diffraction efficiency at 1.55 μm attains a maximum value of 2.7% at a write beam fluence of 260 μ J cm−2, and then decreases at higher fluences. We explain this phenomenon by an absorption saturation at high excitation.  相似文献   
10.
一种漂移室定位子性能反常现象的研究   总被引:1,自引:0,他引:1  
研究了一种漂移室定位子性能的反常现象,它关系到定位子的使用寿命.着重测量了暗电流和随机噪声与时间、高压及温度的关系.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司    京ICP备09084417号-23

京公网安备 11010802026262号