全文获取类型
收费全文 | 10767篇 |
免费 | 303篇 |
国内免费 | 22篇 |
学科分类
数理化 | 11092篇 |
出版年
2023年 | 72篇 |
2022年 | 208篇 |
2021年 | 258篇 |
2020年 | 188篇 |
2019年 | 181篇 |
2018年 | 215篇 |
2017年 | 215篇 |
2016年 | 383篇 |
2015年 | 327篇 |
2014年 | 382篇 |
2013年 | 775篇 |
2012年 | 669篇 |
2011年 | 812篇 |
2010年 | 490篇 |
2009年 | 439篇 |
2008年 | 665篇 |
2007年 | 670篇 |
2006年 | 574篇 |
2005年 | 486篇 |
2004年 | 398篇 |
2003年 | 307篇 |
2002年 | 285篇 |
2001年 | 132篇 |
2000年 | 107篇 |
1999年 | 88篇 |
1998年 | 70篇 |
1997年 | 75篇 |
1996年 | 71篇 |
1995年 | 68篇 |
1993年 | 52篇 |
1992年 | 64篇 |
1991年 | 54篇 |
1990年 | 56篇 |
1989年 | 55篇 |
1988年 | 50篇 |
1987年 | 54篇 |
1986年 | 46篇 |
1985年 | 67篇 |
1984年 | 79篇 |
1983年 | 71篇 |
1982年 | 67篇 |
1981年 | 43篇 |
1980年 | 56篇 |
1979年 | 48篇 |
1978年 | 73篇 |
1977年 | 41篇 |
1976年 | 52篇 |
1975年 | 42篇 |
1974年 | 48篇 |
1973年 | 40篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
2.
Functional Carbazole Liquid‐Crystal Block Codendrimers with Optical and Electronic Properties 下载免费PDF全文
Ismael Gracia Beatriz Feringán Prof. José Luis Serrano Dr. Roberto Termine Dr. Attilio Golemme Dr. Ana Omenat Prof. Joaquín Barberá 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(3):1359-1369
The synthesis and characterisation of a family of block codendrimers consisting of highly versatile mesogenic and carbazole‐containing 2,2‐bis(hydroxymethyl)propionic acid (bis‐MPA) dendrons are reported. The liquid‐crystal behaviour was investigated by means of differential scanning calorimetry, polarised‐light optical microscopy and X‐ray diffraction. Depending on the chemical structure of the constituent dendrons, the codendrimers show lamellar or columnar mesophases. On the basis of the experimental results, models both at the molecular level and in the mesophase are proposed. The physical properties of the block codendrimers derived from the presence of the carbazole moiety in their structure were investigated: photoluminescence in solution and in the mesophase, electrochemical behaviour and hole transport. Electrodeposition of carbazole dendrons afforded a globular supramolecular conformation in which the mesogenic molecular side plays a key role. 相似文献
3.
4.
5.
Highly Selective Copper‐Catalyzed Asymmetric [3+2] Cycloaddition of Azomethine Ylides with Acyclic 1,3‐Dienes 下载免费PDF全文
María González‐Esguevillas Ana Pascual‐Escudero Dr. Javier Adrio Prof. Dr. Juan C. Carretero 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(12):4561-4565
The first examples of the catalytic asymmetric 1,3‐dipolar cycloaddition of azomethine ylides with acyclic activated 1,3‐dienes (and 1,3‐enynes) are described. Under copper catalysis, a selective cycloaddition at the terminal γ,δ‐C?C bond is observed. In addition, depending on the ligand used, either the exo or the endo adduct can be obtained with high selectivity. Under appropriate reaction conditions, the acyclic 1,6‐addition product is detected, suggesting a stepwise mechanism. The resulting C4‐alkenyl‐substituted pyrrolidines are suitable substrates for further access to polycyclic systems, as highlighted by the preparation of hexahydrochromeno[4,3‐b]pyrrole and the tetracyclic core of the alkaloid gracilamine. 相似文献
6.
N. S. Simonović 《Few-Body Systems》2006,38(2-4):139-145
In agreement with the Kohn theorem the relative motion (rel) of three electrons in a two-dimensional parabolic trap separates
from the centre-of-mass (CM) motion. By introducing new coordinates the Hamiltonian for relative motion in the approximation
of non-interacting electrons can be taken to the normal form. The eigenstates of the normalized Hamiltonian are products of
the Fock-Darwin states for normal modes. The energy levels for relative motion are obtained by diagonalizing the exact Hamiltonian
in the eigenbasis for the non-interacting case. In this basis the interaction matrix elements can be obtained in the analytical
form. Since the rank of the Hamiltonian matrix is significantly reduced, the calculations are faster and more accurate than
those for the full (CM + rel) motion. This advantage is especially important for the calculations of excited states and the
analysis of energy spectra. 相似文献
7.
8.
Ana Luísa Daniel‐da‐Silva João Carlos Moura Bordado José Miguel Martín‐Martínez 《Journal of Polymer Science.Polymer Physics》2007,45(22):3034-3045
The degree of phase separation in several moisture‐cured poly(urethane urea)s (PUUs) was studied by FTIR spectroscopy, wide angle X‐ray diffraction (WAXD), and temperature‐modulated differential scanning calorimetry (TMDSC). This latter technique was shown to be particularly useful in analysing the degree of phase separation in PUU polymers. Both phase mixing and phase segregation coexisted in the PUUs and the degree of phase separation increased as the urea hard segment (HS) content in the PUU increased. The maximum solubility of urea HSs into the polyol soft segments (SSs) was achieved for 50 wt % urea HS content in diol‐based PUUs, whereas for triol‐based PUUs the highest solubility between HS and SS was reached for lower urea HS amount. Finally, the higher the urea HS content the higher the extent of phase separation in the PUU. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3034–3045, 2007 相似文献
9.
J‐F. Masson Slaana Bundalo‐Perc Ana Delgado 《Journal of Polymer Science.Polymer Physics》2005,43(3):276-279
Differential scanning calorimetry (DSC) does not allow for easy determination of the glass‐transition temperature (Tg) of the polystyrene (PS) block in styrene–butadiene–styrene (SBS) block copolymers. Modulated DSC (MDSC), which deconvolutes the standard DSC signal into reversing and nonreversing signals, was used to determine the (Tg) of both the polybutadiene (PB) and PS blocks in SBS. The Tg of the PB block was sharp, at ?92 °C, but that for the PS blocks was extremely broad, from ?60 to 125 °C with a maximum at 68 °C because of blending with PB. PS blocks were found only to exist in a mixed PS–PB phase. This concurred with the results from dynamic mechanical analysis. Annealing did not allow for a segregation of the PS blocks into a pure phase, but allowed for the segregation of the mixed phase into two mixed phases, one that was PB‐rich and the other that was PS‐rich. It is concluded that three phases coexist in SBS: PB, PB‐rich, and PS‐rich phases. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 276–279, 2005 相似文献
10.