泡沫镍载 NiCO2O4电极的制备及其催化 H2O2电氧化的性能

本文以水热法结合热处理法原位制备了泡沫镍载 NiCo₂O₄纳米线电极,使用XRD、SEM和TEM对合成的 NiCo₂O₄纳米线进行了表征,NiCo₂O₄纳米线直径约80 nm,长度约 3 ~ 5 μm. 使用循环伏安和计时电流法测试了泡沫镍载NiCo₂O₄纳米线催化H₂O₂的电氧化性能,结果表明泡沫镍载NiCo₂O₄纳米线对H₂O₂电氧化有着优良的催化活性、稳定性和传质性能,在0.3 V电位下0.4 mol·L ^-1 H₂O₂和2 mol·L ^-1 NaOH溶液中氧化电流可达380 mA·cm ^-2.     

Research progress in mass spectrometry analysis for samples containing non-volatile saltsEI北大核心CSCD

It’s still a challenge for mass spectrometers （MS） to analyze samples in non-volatile salts systems. On the one hand， non-volatile salts are easy to crystallize， which will seriously contaminate and clog the transmission system of mass spectrometry， such as capillaries， ion transfer tubes， sampling cones， etc.， thus the analysis results can be affected and the MS can be damaged. On the other hand， non-volatile salts always bring ion suppression， which significantly reduces the signal intensity of the analytes. At the same time， the mass spectrum will be dominated by a large number of salt cluster peaks， interfering with the discrimination of charge state. Recently， different methods have been developed to solve above two problems. This article reviewed the present research progress of mass spectrometry analysis for salt-containing samples， focusing on the role of conventional ion source modification and ambientionization mass spectrometry in the analysis of salt-containing samples. Pretreatment methods were also summarized briefly. Finally， the development tendency of mass spectrometry analysis for salt containing samples is predicted and prospected. © 2023, Youke Publishing Co.,Ltd. All rights reserved.