静电自组装聚电解质/有机染料插层蒙脱土光致变色纳米复合膜

从构筑静电自组装聚电解质／有机染料插层蒙脱土光致变色纳米复合膜所必需 的基本纳米构件--有机染料插层蒙脱土光致变色纳米复合物的设计出发，制备了具有光致 变色功能的蒙脱土／阳离子偶氮染料（GTL）均插层纳米复合物现，插人蒙脱土层 间的GTL热稳定性大幅度提高．由于GTL在纳米受限空间的超分子有序结构共轭，使 偶氮基发生了高达91 nm的显著红移．使用该插层纳米复合物构件与阳离子聚电解 质（PDAC）通过静电自组装得到了生长均匀、排列规整有序的光致变色聚电解质／ 阳离子偶氮染料插层蒙脱土纳米复合膜.     

十四烷基芳基磺酸盐形成的分子有序组合体

以表面张力法、碘光谱法、水增溶法和相态图法研究了自制的三种十四烷基芳基磺酸盐在不同条件下形成的分子有序组合体(胶束、反胶束和微乳液),并考察了分子结构、溶剂、无机盐和短链醇等对其的影响.结果表明:增加十四烷基芳基磺酸盐分子亲油基支化度,不利于其在水溶液或混合极性溶剂(乙二醇-水)中形成胶束而有利于其在非极性溶剂正庚烷中形成反胶束;溶剂极性的降低,促使表面活性剂溶液由胶束溶液→单体溶液→反胶束溶液转变;无机盐或短链醇的加入促进了水溶液中胶束的形成,且反离子价态数或醇烷基碳原子数越大,越有利于胶束形成;无机盐浓度的增加导致表面活性剂/正丁醇/正辛烷/NaCl/水形成的微乳液体系在一定温度下发生由WinsorI→WinsorIII→WinsorII型的转变.     

自由能微扰法研究系列烷基芳基磺酸盐的胶束化焓-熵补偿现象

为了研究不同结构的表面活性剂分子在水溶液中的胶束化焓-熵补偿现象, 采用自由能微扰(FEP)法计算了系列烷基芳基磺酸盐的溶剂化自由能, 并根据胶团化过程的质量作用模型讨论了相关热力学性质. 结果表明: 自由能微扰法得到的溶剂化自由能大小与用传统热力学表面张力法测定的吉布斯自由能相近, 能够用于比较不同结构的烷基芳基磺酸盐间胶束化能力; 烷基芳基磺酸盐在水溶液中的胶束化过程是自发进行的, 且存在焓-熵补偿现象, 补偿温度范围均在(302±2) K; 随着分子结构中芳环向长烷基链中间位置移动, 胶束化能力和胶束的稳定性均下降; 而随着芳环上短烷基链或长烷基链碳数的增加, 形成胶束的能力与稳定性均提高.     

Simulation of loss of uranium ions due to charge changing processes in the CSRm ring

Significant beam loss caused by the charge exchange processes and ion impact-induced outgassing may restrict the maximum number of accelerated heavy ions during the high intensity operation of an accelerator. In order to control beam loss due to charge exchange processes and confine the generated desorption gas, tracking of the beam loss distribution and installation of absorber blocks with low-desorption rate material at appropriate locations in the main Cooler Storage Ring (CSRm) at the Institute of Modern Physics, Lanzhou, will be performed. The loss simulation of uranium ions with electron-loss is presented in this report and the conclusion is that most charge changed particles are lost in the second dipole of the super-period structure. The calculation of the collimation efficiency of the CSRm ring will be continued in the future.     

系列烷基芳基磺酸盐在水溶液中胶束化的焓-熵补偿现象

以表面张力法研究了系列烷基芳基磺酸盐在水溶液中胶束化的热力学性质,并考察了温度与分子结构对胶束化的影响.结果表明,烷基芳基磺酸盐在水溶液中胶束化是一个自发过程,主要来自熵驱动;随着温度升高,先有利于胶束化而后又不利于胶束化,且熵变对吉布斯自由能变的贡献有下降趋势,而焓变的贡献有增大趋势;胶束化存在焓-熵补偿现象,补偿温度Tc均在(306±2)K,基本不随烷基芳基磺酸盐的分子结构的改变而变化;随着芳环上短烷基链或长烷基链碳数的增加,胶束化能力和胶束的稳定性均提高,而随着芳环向长烷基链中间位置移动,胶束化能力和胶束的稳定性均下降.     

Optical Rotatory Feature of (R or S)-1,1′-Binaphthalene-2,2′-diol (BINOL) in Various Solvents

IntroductionElieletal.1,2 haveeverreportedthatsolventtypeandconcentrationwouldaffecttheequilibriumofcis 3 hydrox ythiane S oxideconformationwhichwascausedbyintermolec ularandintramolecularhydrogenbondformedwiththeinter actionbetweenthesolute solventandthesolute soluteinthesolutionandhaveimportantinfluenceonitsspecificrotation .Uptonowitisnotveryclear,however,whetherhydrogenbondingaffectsspecificrotation (inmagnitudeandoccasion allyinsign)directlyorwhetheritdoessoindirectly (byaf fectingconform…     

Conceptional design of a heavy ion linac injector for HIRFL-CSRm

A room temperature heavy ion linac has been proposed as a new injector of the main Cooler Storage Ring(CSRm) at the Heavy Ion Research Facility in Lanzhou(HIRFL), which is expected to improve the performance of HIRFL. The linac injector can supply heavy ions with a maximum mass to charge ratio of 7 and an injection kinetic energy of 7.272 MeV/u for CSRm; the pulsed beam intensity is 3 emA with the duty factor of 3%. Compared with the present cyclotron injector, the Sector Focusing Cyclotron(SFC), the beam current from linac can be improved by 10–100 times. As the pre-accelerator of the linac, the 108.48 MHz 4-rod Radio Frequency Quadrupole(RFQ) accelerates the ion beam from 4 keV/u to 300 keV/u, which achieves the transmission efficiency of 95.3% with a 3.07 m long vane.The phase advance has been taken into account in the analysis of the error tolerance, and parametric resonances have been carefully avoided by adjusting the structure parameters. Kombinierte Null Grad Struktur Interdigital H-mode Drift Tube Linacs(KONUS IH-DTLs), which follow the RFQ, accelerate ions up to the energy of 7.272 MeV/u for CSRm. The resonance frequency is 108.48 MHz for the first two cavities and 216.96 MHz for the last 5 Drift Tube Linacs(DTLs). The maximum accelerating gradient can reach 4.95 MV/m in a DTL section with the length of17.066 m, and the total pulsed RF power is 2.8 MW. A new strategy, for the determination of resonance frequency,RFQ vane voltage and DTL effective accelerating voltage, is described in detail. The beam dynamics design of the linac will be presented in this paper.     

HIAF-CRing 中的俘获加速效率研究(英文)

以HIAF-CRing上典型离子238U34+为研究对象,对其纵向俘获和加速的动力学过程进行了研究。累积后的粒子能量为800 MeV/u, 经过绝热俘获和加速后,粒子被加速至1 130 MeV/u。研究结果表明,通过选择适当的俘获时间、绝热参数以及相空间面积因子等参数,应用优化后的高频俘获加速曲线,可以获得更高的俘获和加速效率。通过粒子纵向动力学追踪软件ESME 上进行模拟,得到了优化后的高频相位、高频电压曲线,使得俘获效率达到99.3%,加速效率近乎100%。同时确定出了CRing 高频腔加速U34+ 所需满足的特性参数,即电压需达到40 kV,频率范围是0:31s0:34 MHz。To reduce the beam loss during the capture and acceleration processes of CRing in HIAF project, the longitudinal beam motion is investigated using the typical ion of 238U34+during the two processes mentioned above. The ions will be captured adiabatically firstly and then will be accelerated from 800 to 1130 MeV/u with a high efficiency using optimized RF voltage and RF phase program. After that the bunched beam will be debunched for the later beam compression. Simulation of these processes by tracking appropriate distributions with the longitudinal beam dynamics code ESME has been used tofind optimum parameters such as RF phase, RF voltage. The variation of the parameter during the RF cycle and the character parameters of the RF cavity are presented.      

重离子治癌装置4 MeV/u IH型漂移管直线注入器的动力学设计

基于KONUS束流动力学理论,完成了一台工作频率为162.5 MHz、占空比为1%的交叉指型漂移管直线注入器（IH-DTL）的动力学设计。该IH-DTL内置两套三组合四极透镜,共有41个加速单元,可为同步加速器提供流强400 eμA、能量4 MeV/u的C4+束流。在动力学设计过程中着重对每个加速间隙的同步能量偏差、注入相位和间隙电压等参数进行优化,使得该IH-DTL的横向归一化RMS接收度达到0.24 πmm·mrad,且横纵向归一化发射度增长小于10%,有利于提高同步环的注入效率。然后根据动力学设计的结构参数进行IH-DTL的高频仿真计算,将得到的三维电磁场分布导入PIC粒子跟踪程序中进行束流动力学模拟。动力学模拟结果显示,束流在IH-DTL出口的横向自然发射度小于13 πmm·mrad,达到了同步环的注入要求,而且在7%的垂直二极场分量下,束流中心的横向偏移在±0.5 mm以内,整体的束流传输效率高于99%。An interdigital H-mode drift tube linac (IH-DTL) with KONUS beam dynamic has been designed, which operation frequency was chosen 162.5 MHz. This IH-DTL consists of 41 accelerating cells and two quadrupole magnets triplets, can provide the C4+ with the current of 400 eμA and energy of 4 MeV/u for the synchrotron. In the beam dynamic design, the synchronous particle energy, inject RF phase and the acceleration voltage of each gap are optimized carefully to make the transverse normalized RMS acceptance of the IH-DTL to be 0.24 πmm·mrad and the beam emittance growth small than 10%. Then the RF structure was designed and the 3D electromagnetic field was imported into the PIC particle tracking code for the beam dynamic simulation. The transverse beam emittance at the exit of the IH-DTL is small than 13πmm·mrad which meets the injection requirement of the synchrotron. What is more, under the 7% vertical dipole fields component, the offset between the beam center and the drift tube's axis is ±0.5 mm at most. The transmission efficiency of the IH-DTL is higher than 99% for the whole beam in the acceptance.     

IH型漂移管直线加速器的束流动力学研究（英文）

为了提高兰州重离子加速器冷却储存环（HIRFL-CSR）的运行效率、改善加速器输出束流品质,并实现几个加速装置分时供束,提高整个重离子加速装置的利用率,特为（HIRFL-CSR）增建一台新的注入器--CSRLINAC。在108.48 MHz的RFQ之后的CSR-LINAC主加速段,主要由一台108.48 MHz和两台216.96 MHz的IH型漂移管直线加速器组成,用于加速荷质比为1/8.5~1/3之间的重离子,其最大的束流流强为3 mA,并将粒子从0.3 MeV/u加速到3.71 MeV/u。运用KONUS动力学原理,在满足设计指标的情况下,首先利用TraceWin程序进行中能束线MEBT设计,后针对高频腔体设计和束流匹配的基本参数的系列讨论,特别是对CSR-LINAC的中能束流匹配线、参数选择和IH型KONUS结构的漂移管直线加速器进行设计模拟优化。最终得出,在保证腔体设计指标和95.3%的传输效率的情况下,该紧凑型直线加速结构经过三个腔体的加速后,束流的纵向归一化均方根发射度增长仅有25%;同时发现,当流强达到3 mA时,存在空间电荷效应,导致其纵向相宽增长约25%,最大横向包络也存在16.5%的涨落。In order to improve the operation efficiency of the Cooling Storage Ring of Heavy Ion Research Facility in Lanzhou (HIRFL-CSR), a heavy ion linac (linear accelerator) was proposed and designed as a new injector for HIRFL-CSR. Following the 108.48 MHz Radio-Frequency Quadrupole (RFQ), three tanks in total with Interdigital H-mode drift tube linac (IH-DTL) structure are installed to boost the beam energy from 0.3 to 3.71 MeV/u, and the beam current of ions with charge-to-mass ratio from 1/8.5 to 1/3 can reach to 3 mA. The first tank operatesat the same frequency as the RFQ, and the rest two operate at 216.96 MHz. The “Combined Zero-Degree Synchronous Particle Structure” (KONUS) beam dynamics was used in the beam dynamics design. The overview of the physics design on the main accelerating components, including RF design and beam dynamics design are introduced in this paper. The optimized structure design, fabrication status and simulation results are presented in this contribution. It shows that under the condition of assurance of 95.3% transmission efficiency, the normalized rms emittance is about 25%. When the beam current is up to 3 mA, owing to the space charge effect, the increase of longitudinal phase spread and transverse envelope are about 25% and 16.3%, respectively.