Modelling future soil chemistry at a highly polluted forest site at Istebna in Southern Poland using the "SAFE" model

The multi-layer dynamic model SAFE was applied to the forested catchment Istebna (Southern Poland), to study recovery from acidification. Environmental pollution in the area has been historically high. The model uses data from an intensive monitoring plot established in 1999 in a spruce stand, which was planted in 1880. Observations showed that the soil was depleted of base cations. The measured base saturation in 1999 was between 5 and 8% in the different soil layers. Model predictions assuming full implementation of the UNECE 1999 Gothenburg Protocol and present day base cation deposition show that the base saturation will slowly increase to 20% by 2100. Despite large emission reductions, Istebna still suffers from the very high loads of acidifying input during the past decades. Soil recovery depends on future emissions especially on base cation deposition. The recovery will be even slower if the base cation deposition decreases further.     

Mercury Air Emission from Coal-Fired Public Power Sector: Uncertainty and Its Monthly Distribution. Case Study from Poland

The paper presents two aspects concerned with the mercury air emission inventory from coal-fired public power and energy plants: an uncertainty analysis, using Monte Carlo simulation (Journal of the American Statistical Association, 44(247), 335–341 1949) and the monthly distributions applying the Denton-Cholette approach (Dagum & Cholette 2006). The analysis determines uncertainty about the estimates mercury air emission from 1990 to 2012 including the development of air pollution control (APC) technologies in the Polish public power and energy sector, also the monthly distributions in comparison with previously obtained results (H?awiczka 2008). The uncertainty of mercury (Hg) content in fuel is 31.6% for hard coal and 42.4% for brown coal. The confidence interval for the estimated emission changed from [kg] (16,082.2; 16,242.2) in 1990 to (10,525.9;10,671.1) in 2012. However, the Denton-Cholette approach overestimates the emissions for the warmer periods of the year, but it could, however, in our view, be applied to attain the monthly distributions.     

Wild boar (Sus scrofa) as a bioindicator of organochlorine compound contamination in terrestrial ecosystems of West Pomerania Province, NW Poland

The aim of this study was to detect the presence and determine the residue levels of DDT, lindane, endrin and polychlorinated biphenyls (PCBs) in the liver of wild boars from the area of West Pomerania, NW Poland; to determine the activity of glutathione S-transferase (GST) as a biomarker of biological response and to assess the toxicological risk for consumers of the wild boar offal. The presence of pesticide residues and PCBs was found in all examined liver samples. The highest concentration was observed for endrin, and then, the descending order was PCBs >DDTs >lindane >dl-PCBs. The mean hepatic concentrations of endrin, PCBs, DDTs and lindane were 117.28, 78.59, 67.95 and 7.24 ng/g lipid weight, respectively. Among the dioxin-like PCB congeners, 118 and 156 were dominant in liver samples. The mean toxic equivalent (TEQ) level calculated for dl-PCBs was 2.10?±?1.11 pg WHO-PCB-TEQ/g. There was a statistically significant (p?<?0.05) negative correlation between the concentration of lindane, DDTs and PCBs (as a sum of indicator congeners) in the liver and in the activity of GST. However, GST activities showed no significant correlation with any of the dl-PCBs. In five boar liver samples, the levels of certain organochlorine compounds exceeded the maximum residue levels (MRLs). In one sample, the MRLs were exceeded simultaneously for PCBs, endrin and DDTs and in another one—for endrin and DDTs. In the remaining three samples, only PCB levels were exceeded.     

The monitoring of cadmium,zinc and copper in the kidneys and liver of humans deceased in the region of Cracow (Poland)

Cadmium, zinc and copper levels were determined in the renal cortex and liver of 60 inhabitants of Cracow, Poland. Cadmium levels in the renal cortex were contained in broad limits of 5–176 g/g, mean 50.6 g/g (wet weight). Maximum levels were found in the age group of about 50–60 years. The levels were slightly higher in men (53 g/g) than in women (45 g/g), with no effect of location within the region. The levels in smokers (62 g/g) were much higher than in non-smokers (32 g/g). The above relations were less pronounced for cadmium levels in the liver. Whole body retention of cadmium followed the pattern of cadmium in renal cortex. The level of zinc in renal cortex reflected those of cadmium. A significant proportion of the population (54% in smokers, 9% in non-smokers) showed cadmium levels in renal cortex exceeding the reference level of 50 g/g recently accepted for general population. In the view of the authors the exposure to cadmium of the population of Cracow is excessive and calls for attention.The study was performed under a KBN grant No 40106 91 01.     

The evolution of December 2004 tsunami deposits: Temporal and spatial distribution of potentially toxic metalloids

The article presents the results of research into the content of metalloid fractions in the tsunami deposits from southern Thailand. The following fractions, which are potentially most easily released from deposits to the environment, have been distinguished: the water soluble fraction, the exchangeable fraction extracted with the phosphate buffer and the fraction eluted with the solution of hydrochloric acid. The analytical technique atomic absorption spectrometry with hydride generation was applied. Spatial variability of the metalloid fractions in deposits and changes occurring in deposits over a period of several years of observation were determined. Based on the statistical analysis of the results, an attempt was made to determine the post-depositional release of deposits components to the environment. Based on the conducted research, the 4 years forming process of the arsenic, antimony and selenium occurrence after the deposition of sediments on land were described, as well as the balance in the amount of deposit components released to the environment.     

Monitoring of toxicity during degradation of selected pesticides using ionizing radiation

The optimization of experimental conditions for radiolytic removal of organic pollutants from water and waste with the use of ionizing radiation via controlling the concentration of target compound(s) requires also monitoring the toxicity changes during the process. Commonly used herbicides 2,4-D and dicamba were shown to increase toxicity measured with the Microtox test at low irradiation doses resulting from formation of more toxic transient products, which can be decomposed at larger doses. The changes of toxicity were examined with respect to dose magnitude and the presence of commonly occurring scavengers of radiation.     

Comparative studies of health hazard from radon (Rn-222) in two selected lithologic formations in the Suwałki region (in Poland)

The aim of this work was to make a comparison of indoor radon concentrations in dwellings and in soil air in the area of two geological formations in the Suwa?ki region (Poland). The mean arithmetic airborne concentration was found to be the highest (301 Bq m (-3)) in the basements of buildings in the gravel and sand areas, whereas in the boulder clay areas it reached 587 Bq m (-3). Out of 54 measurements of radon concentrations performed at the ground floor, in eight cases concentrations were found to exceed 200 Bq m (-3) - permissible radon level in new-built houses in Poland and in three cases these values were even higher than 400 Bq m (-3). The highest radon levels were noted in houses with earthen basement floors and with direct entrance from the basement to rooms or kitchens. The mean arithmetic radon concentration in the soil air in the sandy and gravel formations was 39.7 kBq m (-3) and in clay formation it was 26.5 kBq m (-3). Higher radon levels were also found in the water obtained from household wells reaching 8367 Bq m (-3) as compared with tap water (2690 Bqm (-3)). The mean indoor concentration for the whole area under study was found to be 169.4 Bq m (-3), which is higher than the mean value for Poland (49.1 Bq m (-3)) by a factor of 3.5.     

New international long-term ecological research on air pollution effects on the Carpathian Mountain forests,Central Europe

An international cooperative project on distribution of ozone in the Carpathian Mountains, Central Europe was conducted from 1997 to 1999. Results of that project indicated that in large parts of the Carpathian Mountains, concentrations of ozone were elevated and potentially phytotoxic to forest vegetation. That study led to the establishment of new long-term studies on ecological changes in forests and other ecosystems caused by air pollution in the Retezat Mountains, Southern Carpathians, Romania and in the Tatra Mountains, Western Carpathians on the Polish-Slovak border. Both of these important mountain ranges have the status of national parks and are Man & the Biosphere Reserves. In the Retezat Mountains, the primary research objective was to evaluate how air pollution may affect forest health and biodiversity. The main research objective in the Tatra Mountains was to evaluate responses of natural and managed Norway spruce forests to air pollution and other stresses. Ambient concentrations of ozone (O(3)), sulfur dioxide (SO(2)), nitrogen oxides (NO(x)) as well as forest health and biodiversity changes were monitored on densely distributed research sites. Initial monitoring of pollutants indicated low levels of O(3), SO(2), and NO(x) in the Retezat Mountains, while elevated levels of O(3) and high deposition of atmospheric sulfur (S) and nitrogen (N) have characterized the Tatra Mountains. In the Retezat Mountains, air pollution seems to have little effect on forest health; however, there was concern that over a long time, even low levels of pollution may affect biodiversity of this important ecosystem. In contrast, severe decline of Norway spruce has been observed in the Tatra Mountains. Although bark beetle seems to be the immediate cause of that decline, long-term elevated levels of atmospheric N and S depositions and elevated O(3) could predispose trees to insect attacks and other stresses. European and US scientists studied pollution deposition, soil and plant chemistry, O(3)-sensitive plant species, forest insects, and genetic changes in the Retezat and Tatra Mountains. Results of these investigations are presented in a GIS format to allow for a better understanding of the changes and the recommendations for effective management in these two areas.     

El Niño platforms: participatory disaster response in Peru

Climate change is expected to lead to greater extremes (droughts and floods) in river regimes around the world. While the number of major calamities is predicted to rise, the efforts of the public sector, experts and local stakeholders are badly coordinated. Consequently, aid does not reach target groups, resulting in unnecessary losses. Hence, there is a need for more participatory and integrative approaches. To ensure a more concerted response to climate-induced disasters, stakeholders could coordinate and negotiate within Multi-Stakeholder Platforms. Such roundtables are increasingly being established for vision-building and integrated water resource management, but could be employed in disaster management as well. After discussing the advantages and disadvantages of participation, this article trace the rise of and the problems facing two 'El Ni?o' platforms: one in Ica, a city on the Peruvian coast that flooded unexpectedly in January 1998, and one in Ayacucho, which saw a climate change-induced drought around the same time. The issue of internal and external legitimacy receives particular emphasis.     

Future climate and adverse health effects caused by fine particulate matter air pollution: case study for Poland

Ground level air pollution, especially fine particulate matter (PM_2.5), has been associated with a number of adverse health effects. The dispersion of PM_2.5 through the atmosphere depends on several mutually connected anthropogenic, geophysical and meteorological parameters, all of which are affected by climate change. This study examines how projected climate change would affect population exposure to PM_2.5 air pollution in Poland. Population exposure to PM_2.5 in Poland was estimated for three decades: the 1990s, 2040s and 2090s. Future climate conditions were projected by Regional Climate Model RegCM (Beta), forced by the general atmospheric circulation model ECHAM5. The dispersion of PM_2.5 was simulated with chemical transport model CAMx version 4.40. Population exposure estimates of PM_2.5 were 18.3, 17.2 and 17.1 μg/m³ for the 1990s, 2040s and 2090s, respectively. PM_2.5 air pollution was estimated to cause approximately 39,800 premature deaths in the population of Poland in the year 2000. Our results indicate that in Poland, climate change may reduce the levels of exposure to anthropogenic particulate air pollution in future decades and that this reduction will reduce adverse health effects caused by the air pollution.