荆江分洪区1998年洪水转移调查分析

对荆江分洪区１９９８年洪水期间安全转移的调查表明,叶然有分洪预案,但实际转移时仍出现了相当程度的拥挤与混乱。完善分洪转移的组织与管理,已成为分洪区居民１９９８年转移后关注的焦点,分洪区居民普遍表现出对分洪洪水情不甚了解,通过各种方式开展有关洪水的宣伟,提高区内居民的防洪意识,是荆江分洪区未来防洪减灾的重点工作之一,由于是国家为保护更重要的地区而主动分洪。对分洪区历分洪蒙受的损失给预某种形式的补偿已     

Analysis of metabolic changes in Trichoderma asperellum TJ01 at different fermentation time-points by LC-QQQ-MS

Trichoderma spp. are among the most widely recognized biocontrol fungi used to inhibit pathogens and promote plant growth. These functions are related to primary and secondary metabolites. This study investigated the different metabolites in Trichoderma asperellum TJ01 cultured for 24 and 72?h using liquid chromatography with triple-quadrupole mass spectrometry. Compared to the 24?h culture of T. asperellum TJ01, the 72?h culture with amino acid metabolism tended to decrease while sugar and lipid metabolisms tended to increase. Furthermore, the 72?h culture had a higher proportion of upregulated flavonoids, in combination with a higher proportion of downregulated alkaloids, and equal proportions of upregulated and downregulated polyphenols and hormones. This study also identified a few valuable medicinal substances such as trigonelline and 5-hydroxytryptophan in T. asperellum TJ01 fermentation cultures.     

Investigation on the influence of methanol on adsorption and leaching of pesticides with soil column liquid chromatography

The effect of methanol of low concentration on adsorption and leaching of atrazine and tebuconazole was studied in this paper. The adsorption coefficients and the retardation factors (R^m) of pesticides on EUROSOIL 3# log-linearly decreased as volumetric fraction of methanol (f^c) was increased in the binary solvent mixtures of methanol and water. These data are consistent with solvophobic theory formerly outlined for describing the adsorption and transport of hydrophobic organic chemicals from mixed solvents. Nevertheless, the adsorption of these pesticides in soil–water system slightly increased when the soil was pre-washed with methanol in comparison with that pre-washed with water (pure water system). Furthermore, their adsorption coefficients were still higher in binary solvent systems with methanol of very low concentrations, i.e. f^c<0.03 for atrazine and f^c<0.01 for tebuconazole, than those in pure water system. The adsorption coefficients (logK^w) of atrazine and tebuconazole predicted by solvophobic theory were 0.5792 and 1.6525, respectively, and their experimental logK^w were 0.3701 and 1.6275 in pure water system. Obviously, the predicted logK^w of the two pesticides was higher than the experimental log K^w in pure water system. The predicted K^w and the retardation factor (R^w) in pure water system by solvophobic theory are thus possibly inaccurate.     

Incidence of organochlorine pesticides in soils of Shenzhen, China

To determine the incidence of organochlorine pesticides (OCPs) in soil in a rapid urbanization region, soil samples from various land use types in Shenzhen were collected in winter, 2007. The concentration of dichlorodiphenyltrichloroethanes (DDTs) and hexachlorocyclohexanes (HCHs) ranged from non-detected to 149 ng g(-1) and 19 to 88 ng g(-1), respectively. The highest levels of OCPs were observed in soil from traffic and industry areas, reflecting that intensive human disturbance make the soil pollution accumulation more disperse. HCHs and DDTs profiles revealed that the sources were associated mainly with lindane and technical DDTs, respectively, while HCHs in the soil of Shenzhen might originate from both recent and historical sources. The loss of OCPs by soil erosion will enter surface runoff and impose impact on the water environment. Non-dietary exposure estimation indicates that children were the most sensitive group. The average daily exposure to OCPs for males was more serious than for females. Non-dietary exposure to DDTs and HCHs in residential blocks of Shenzhen were far below the acceptable daily intake recommended by the Food and Agriculture Organization/World Health Organization.     

奎屯市区城市废水排污系统网络化的探讨

根据奎屯市区城市废水的排放量大、排污口多、污染物浓度高以及排污下水管道污水处理设施的建成现状等特点，提出了以污水处理厂为治理中心，市区排污管道网络化的改造设想、存在问题及对策。     

Quantifying the effect of wind on internal wave resonance in Lake Villarrica,Chile

Lake Villarrica, located in south central Chile, has a maximum depth of 167 m and a maximum fetch of about 20 km. The lake is monomictic, with a seasonal thermocline located at a depth of approximately 20 m. Field data show the presence of basin-scale internal waves that are forced by daily winds and affected by Coriolis acceleration. A modal linear and non-linear analysis of internal waves has been used, assuming a two-layer system. The numerical simulations show good agreement with the internal wave field observations. The obtained modes were used to study the energy dissipation within the system, which is necessary to control the amplitude growth. Field data and numerical simulations identify (1) the occurrence of a horizontal mode 1 Kelvin wave, with a period of about a day that coincides with the frequency of daily winds, suggesting that this mode of the Kelvin waves is in a resonant state (subject to damping and controlled by frictional effects in the field) and (2) the presence of higher-frequency internal waves, which are excited by non-linear interactions between basin-scale internal waves. The non-linear simulation indicates that only 10 % of the dissipation rate of the Kelvin wave is because of bottom friction, while the rest 90 % represents the energy that is radiated from the Kelvin wave to other modes. Also, this study shows that modes with periods between 5 and 8 h are excited by non-linear interactions between the fundamental Kelvin wave and horizontal Poincaré-type waves. A laboratory study of the resonant interaction between a periodic forcing and the internal wave field response has also been performed, confirming the resonance for the horizontal mode 1 Kelvin wave.     

The study on the dechlorination of OCDD with Pd/C catalyst in ethanol-water solution under mild conditions

Dechlorination of octachlorodibenzo-p-dioxin (OCDD) was carried out in ethanol-water (v/v=1:1) solution of NaOH in the presence of Pd/C catalysts with the use of H(2). The substrate was dechlorinated with Pd/C under mild conditions (atmospheric pressure and <100 degrees C) to give a chlorine-free product, dibenzo-p-dioxin (DD), in high yields. After reaction of 3h at 50 degrees C, 95.9% OCDD was degraded to low dechlorinated congeners and the yield of DD was 77.4%. We have also studied the dechlorination selectivity of chlorine atoms on the different substituted positions and postulated the dechlorination pathway of OCDD. For OCDD, the 2-position has higher reactivity than 1-position, but the difference is very small. From the distribution statistics of the intermediates during the reaction, we postulate that the steric effect plays an important role during the reaction and affect the dechlorination pathway of OCDD.     

长江三峡柑桔的冻害和热害（二）

本文从柑桔冻害和热害的危害因子和指标等级划分的研究和选取入手,着重探讨了长江三峡地区(湖北境内)两害显著的时空变化特征、差异与关联性及对柑桔生产的影响;揭示了80年代以来冬暖春热的重大气候变化是使两害向“两极分化”的根本原因;讨论了三峡水利工程对两害时空格局的可能调整及减灾原理;最后提出了可能的对策。