Estimation of radon exhalation rate, natural radioactivity and radiation doses in fly ash samples from Durgapur thermal power plant, West Bengal, India

Coal and its by products often contain significant amounts of radionuclides, including uranium which is the ultimate source of the radioactive gas radon. Burning of coal and the subsequent emission to the atmosphere cause the re-distribution of toxic trace elements in the environment. Due to considerable economic and environmental importance and diverse uses, the collected fly ash has become a subject of worldwide interest in recent years. In the present study, radon exhalation rate and the activity concentration of (238)U, (232)Th and (40)K radionuclides in fly ash samples from Durgapur thermal power plant (WB) have been measured by "Sealed Can technique" using LR-115 type II detectors and a low level NaI (Tl) based gamma ray spectrometer, respectively. Radon exhalation rate varied from 360.0 to 470.0 mBq m(-2)h(-1) with an average value of 406.8 mBq m(-2)h(-1). Activity concentrations of (238)U ranged from 84.8 to 126.4 Bq kg(-1) with an average value of 99.3Bqkg(-1), (232)Th ranged from 98.1 to 140.5 Bq kg(-1) with an average value of 112.9 Bq kg(-1) and (40)K ranged from 267.1 to 364.9 Bq kg(-1) with an average value of 308.9 Bq kg(-1). Radium equivalent activity obtained from activity concentrations is found to vary from 256.5 to 352.8 Bq kg(-1) with an average value of 282.5 Bq kg(-1). Absorbed gamma dose rates due to the presence of (238)U, (232)Th and (40)K in fly ash samples vary in the range 115.3-158.5 nGy h(-1) with an average value of 126.4 nGy h(-1). While the external annual effective dose rate varies from 0.14 to 0.19 mSv y(-1) with an average value of 0.15 mSv y(-1), effective dose equivalent estimated from exhalation rate varies from 42.5 to 55.2 microSv y(-1) with an average value of 47.8 microSv y(-1). Values of external hazard index H(ex) for the fly ash samples studied in this work range from 0.69 to 0.96 with a mean value of 0.77.     

A simple and robust method for determination of neem (Azadirachta indica A. Juss) oil in neem oil coated urea

The production of neem oil coated urea (NOCU), a technology developed by the Indian Agricultural Research Institute, has been grown to over 2.0 million tons per year. The estimation of neem oil content in NOCU is important due to its significance in ensuring agronomic efficiency. Therefore, this study was taken up to develop a simple method for the determination of neem oil in NOCU. The procedure involves extraction of neem oil from NOCU; saponification of extracted oil; oxidation of released glycerol to formaldehyde, and subsequent conversion of formaldehyde to a dihydrolutidine derivative. Its concentration was determined spectrophotometrically. The recoveries of neem oil from NOCU with oil load of 500 and 1000?ppm were 87.6?±?3.0% and 90.0?±?4.8% respectively with direct method; and improved to 92.6?±?4.0% and 96.7?±?3.8% after including the in situ purification. A simple method based on the Hantzsch reaction was developed for the determination of neem oil in NOCU. This method is superior to earlier methods in terms of sensitivity, simplicity, and time required.     

Atmospheric deposition of heavy metals (Cu, Zn, Cd and Pb) in Varanasi City, India

Rapid growth in urbanization and industrialization in developing countries may significantly contribute in heavy metal contamination of vegetables through atmospheric depositions. In the present study, an assessment was made to investigate the spatial and seasonal variations in deposition rates of heavy metals and its contribution to contamination of palak (Beta vulgaris). Samples of bulk atmospheric deposits and Beta vulgaris for analysis of Cu, Zn, Cd and Pb were collected from different sampling locations differing in traffic density and land use patterns. The results showed that the sampling locations situated in industrial or commercial areas with heavy traffic load showed significantly elevated levels of Cu, Zn and Cd deposition rate as compared to those situated in residential areas with low traffic load. The deposition rates of Cu, Zn and Cd were significantly higher in summer and winter as compared to rainy season, however, Pb deposition rate was significantly higher in rainy and summer seasons as compared to winter season. Atmospheric depositions have significantly elevated the levels of heavy metals in B. vulgaris collected during evening as compared to those collected in morning hours. The study further showed that local population has maximum exposure to Cd contamination through consumption of B. vulgaris. The present study clearly points out the urban and industrial activities of a city have potential to elevate the levels of heavy metals in the atmospheric deposits, which may consequently contaminate the food chain and thus posing health risk to the local population.     

A Solvent-Free Approach for Production of Films from Pectin and Fungal Biomass

Self-binding ability of the pectin molecules was used to produce pectin films using the compression molding technique, as an alternative method to the high energy-demanding and solvent-using casting technique. Moreover, incorporation of fungal biomass and its effects on the properties of the films was studied. Pectin powder plasticized with 30% glycerol was subjected to heat compression molding (120 °C, 1.33 MPa, 10 min) yielding pectin films with tensile strength and elongation at break of 15.7 MPa and 5.5%, respectively. The filamentous fungus Rhizopus oryzae was cultivated using the water-soluble nutrients obtained from citrus waste and yielded a biomass containing 31% proteins and 20% lipids. Comparatively, the same strain was cultivated in a semi-synthetic medium resulting in a biomass with higher protein (60%) and lower lipid content (10%). SEM images showed addition of biomass yielded films with less debris compared to the pectin films. Incorporation of the low protein content biomass up to 15% did not significantly reduce the mechanical strength of the pectin films. In contrast, addition of protein-rich biomass (up to 20%) enhanced the tensile strength of the films (16.1–19.3 MPa). Lastly, the fungal biomass reduced the water vapor permeability of the pectin films.     

Performance of a naturally growing Parmelioid lichen Remototrachyna awasthii against organic and inorganic pollutants

The present study aims to assess the level and possible sources of organic and inorganic pollutants in Mahableshwar city in Western part of India and their effect on naturally growing foliose lichen Remototrachyana awasthii (Hale & Patw.) Divakar & A. Crespo. This lichen species growing abundantly in the area was collected from eight different sites on the basis of anthropogenic activities detected in the area. The concentration of inorganic heavy metals (Al, As, Cd, Cr, Fe, Pb, Mn, and Zn) and polycyclic aromatic hydrocarbons (PAHs) were analyzed and correlated with photosynthetic pigments (Chl a, Chl b, total chlorophyll, and carotenoid) together with chlorophyll degradation and protein contents. The concentration of most of the metals at different sites was significantly greater than at the control site (P?<?0.001). The highest metal content was found at Bus Stand and Panchgani, a tourist place that experiences heavy traffic activities. The concentration of PAHs, particularly of two-and three-ringed PAHs, was also found to be the highest in samples collected at Bus Stand area. The chlorophyll degradation and protein content were found to be the most sensitive parameters to assess the vitality of lichen thallus against wide range of air pollutants. The effectiveness of R. awasthii as a biomonitor will be investigated in the near future by comparing this species with other biomonitors.     

Variations in some environmental characteristics including C and N stable isotopic composition of suspended organic matter in the Mandovi estuary

Chemical and isotopic (??¹³C and ??¹⁵N) investigation of the Mandovi estuary along the Indian west coast affected strongly by the seasonal monsoon cycle was carried out. The Mandovi estuary is a major waterway for Goa and extensively used for transportation of iron and manganese ore. In addition, with large population centers as well as agricultural fields located on its shores, the estuary is assumed to have been influenced by human activities. Measurements of chemical and isotopic parameters made in the lower part of the estuary during the southwest (SW) monsoon and post-monsoon seasons reveal distinct changes, and it is observed that despite considerable enrichment of macronutrients during the SW monsoon, productivity of the estuary (phytoplankton biomass), as inferred from the chlorophyll-a content, is not as high as expected. This is due to occurrences of high turbidity and cloud cover that limits photosynthetic productivity. The isotopic characterization (C and N isotopes) of suspended organic matter produced/transported during the monsoon and post-monsoon seasons of year 2007 provides a baseline dataset for future isotopic studies in such type of tropical estuaries.     

Design and manufacturing of femoral stems for the Indian population

Several researchers have stressed the need for a proper implant-patient match in hip joint replacements, in particular, for cementless femoral stems. Some of the complications of mismatch are aseptic loosening, improper load distribution, and discomfort. In this study, the differences in dimensions between femurs of elderly Indians and those of populations from other regions are compared in order to solve the problem of a possible geometric mismatch between a selected implant and the femurs of an Indian patients are concerned. This paper also describes a methodology for implant designing from measured anthropometric data, fit evaluation, finite element (FE) stress analysis and subsequently implant manufacturing using the CAM (Computer Aided Manufacturing) technique. The machining of the Titanium alloy femoral stem is usually performed on a 5 Axis CNC (Computer Numerical Control) machining center. However, in this study the machining of the femoral stem was effectively performed on a 3 Axis CNC machining center to emphasize on economical benefits for low cost manufacturing strategy.     

Cure,Mechanical and Swelling Properties of Biocomposites from Chicken Feather Fibre and Acrylonitrile Butadiene Rubber

Biocomposites of acrylonitrile butadiene rubber (NBR) reinforced with chicken feather fibre (CF) were prepared using dicumyl peroxide (DCP) as vulcanizing agent. Composites with three series of chicken feather fibres were studied i.e., raw (RCF), sterilized (SCF) and alkali treated (ACF). The cure characteristics of composites were studied. The mechanical properties of NBR were found to be improved by the incorporation of chicken feather fibre in all forms. Surface modification of the fibre was done by alkaline treatment to improve the interfacial adhesion and it characterised by FTIR. Better properties are shown by the composites with ACF. The swelling behaviour of the composites in N,N-dimethylformamide, acetonitrile, dimethyl sulfoxide and water were analyzed for the swelling coefficient values. The biodegradable characteristics of CF reinforced NBR composites were studied by soil burial test which indicated that it is an eco-friendly and acceptable material. Scanning electron microscopy studies support the results of mechanical properties. The outcome obtained from this study is believed to assist the development of environmentally–friendly composites especially for specific product applications like oil seals, hoses and automobile bushes etc.