A comparison of results from two test methods for assessing the toxicity of aminotriazole to Selenastrum capricornutum

Two different test methods for assessing the toxicity of aminotriazole to Selenastrum capricornutum are compared. Growth medium composition is demonstrated to have a significant effect on the toxicity of aminotriazole.     

Octachlorodibenzo-p-dioxin in wood treatment materials and treated wood

The octachlorodibenzo-p-dioxin (OCDD) concentrations have been determined in aged samples of commercial pentachlorophenol (PCP), in wood protection formulations containing PCP and in wood treated with PCP as a preservative or as an anti-sapstain treatment. The concentrations of OCDD found in the various samples are within the range expected from the amount of commercial PCP initially present in the samples. In view of the known stability of OCDD the results are interpreted as indicating that the formulation, treatment and ageing processes have not led to any substantial conversion of PCP to OCDD; although one result indicates that outdoor exposure of treated samples increased the OCDD concentration by a factor of approximately 2 after $\text{3}\text{1}\text{2}$ years. Analysis of aged samples of treated wood indicate that OCDD is lost much less rapidly from the wood than PCP.     

Polychlorodibenzo-p-dioxins and dibenzofurans in technical pentachlorophenol - results of a collaborative analytical exercise

Results of analyses of eight samples of technical pentachlorophenol conducted by three different analytical methods are presented and discussed.     

Modeling and Measurement of Structural Changes at a Landscape Scale in Dryland Areas

We present a technique to quantify and model the intensity of structural changes produced by management of dry grazing lands at a landscape scale. The technique is illustrated with the analysis of digitized black–white (b/w) imagery and an application to the study of changes induced by grazing gradients. Structural changes in patchy vegetation canopies were studied in the Patagonian Monte (Chubut, Argentina) at two resolution scales by means of linear transects in the field (50 m) and others drawn on aerial b/w photographs (2–5 km) of grazed paddocks. Spatial series of plant cover values along transects in the field and on photographs were analyzed with standard techniques of spectral analyses, including auto-correlation spectra and Fourier transforms. In order to test the internal consistency of the techniques used, synthetic plant canopies with patches of varying cover and size were generated by means of a stochastic model of plant growth under different stocking rates or after varying periods of recovery. The behavior of the simulation model is consistent with the observed dynamics of plant canopies in semiarid environments. There is a consistent relation between the number and geometric properties of plant patches (patch number, patch size, patch connectivity) and the signal/noise ratios of the Fourier decomposition describing plant density data. Signal/noise ratios corresponding to plant cover data in paddocks with different grazing treatment are consistent with the assumptions derived from modeled canopies, as well as those estimated from optical density of b/w aerial photographs of paddocks. We tested the hypotheses that patch arrangements as quantified by the signal/noise ratios vary in accordance with grazing gradients in paddocks with a permanent corner-located watering point. The use of digitized b/w images allows inspecting permanent changes over time periods when other types of images were not yet available.     

Analysis of polychlorobiphenyls from used transformers for polychlorodibenzofurans

The results of analyses for polychlorodibenzofuran (PCDF) content in two samples of polychlorobiphenyl (PCB) from used electrical transformers are presented and discussed. In neither sample was there evidence for enhanced PCDF concentrations even though one of them had been subjected to overheating while in service.     

Long term changes in polychlorodibenzo-p-dioxin concentrations in wood treated with technical pentachlorophenol

Wood samples treated with technical pentachlorophenol (PCP), technical sodium pentachlorophenoxide (NaPCP) and octachlorodibenzo-p-dioxin have been exposed outdoors for periods up to $\text{2}\text{1}\text{2}$ years. Analysis of extracts from the samples show that photolytic reductive dechlorination of highly chlorinated dibenzo-p-dioxins to less chlorinated isomers occurs. However there is no discernible increase in polychlorodibenzo-p-dioxin concentrations in the technical PCP treated wood presumably because further photolytic reactions and volatilisation compete effectively with the photolytic formation. There is no evidence for formation of octachlorodibenzo-p-dioxin (OCDD) in technical PCP treated wood in this study, probably because photolytic destruction and volatilisation compete effectively with formation reactions when the initial OCDD concentration is relatively high.     

An investigation of aqueous activity coefficients at low concentrations

The activity of a chemical in solution determines its tendency to move into other media. At low concentrations (<0.01M) it is generally considered to be linearly related to concentration. A hypothetical model based on the structure of liquid water is discussed which could cause deviations from this linearity in the ppb region, a concentration much lower than that normally investigated thermodynamically, but one of great importance environmentally. Headspace experiments are reported with carbon tetrachloride and chloroform in water at concentrations down to ～10^?3 ppb but no such deviations were discerned.