稀土-β-二酮配合物的合成及其应用研究进展

介绍了稀土－β－二酮配合物的合成方法，评述了其在催化、发光、紫外线主护等领域的应用。     

Preparation and mechanical properties of polypropylene fiber reinforced calcined kaolin-fly ash based geopolymer

To improve the environmental benefits and solve the problems of large shrinkage and high brittleness, the partial replacement of calcined kaolin by fly ash as a raw material for geopolymer synthesis and the influences of polypropylene (PP) fiber on the mechanical properties and volume stability were investigated. The results show that compressive strength of the geopolymer containing 33.3%(mass fraction) fly ash by steam curing at 80 °C for 6 d is improved by 35.5%. The 3-day compressive strength, flexural strength and impacting energy of geopolymers containing 0.05%PP fiber increase by 67.8%, 36.1% and 6.25%, while the shrinkage and modulus of compressibility decrease by 38.6% and 31.3%, respectively. The results of scanning electron microscopy (SEM) and the appearances of crack growths confirm that PP fiber can offer a bridging effect over the harmful pores and defects and change the expanding ways of cracks, resulting in a great improvement of strength and toughness. Foundation item: Project(2006AA06Z225) supported by the National High-Tech Research and Development Program of China     

水热条件下偏高岭土-矿渣基地聚合物的抗碳化性能

采用高温纯CO2水溶液加速碳化的方法,通过对不同龄期碳化试样的抗压强度和孔结构测试、渗透率测定及微观形貌分析,并结合净浆水泥石的碳化性能进行同步比较,对偏高岭土-矿渣基地聚合物的碳化性能进行了研究.结果表明:偏高岭土-矿渣基地聚合物的抗碳化能力明显优于净浆水泥石.地聚合物碳化28 d和90 d时,试样的抗压强度分别比同...     

小径管椭圆成像上焊缝中的圆形缺陷的等级评定

讨论小口径管(外径D≤89mm)双壁双影椭圆成像上焊缝中的圆形缺陷等级的评定计算,修正了同一当量大小的圆形缺陷分别存在于上、下焊缝时的变化情况,对合理的评定焊缝质量等级具有一定的参考价值。     

掺废陶瓷粉对碱激发矿渣早期反应、硬化体强度及收缩性能的影响

碱激发矿渣(Alkali activated slag—AAS)水泥具有强度发展快、胶结性能好的特点,但大收缩和高成本限制了其工程应用。本研究探索了废陶瓷粉作为新的原材料,其用量对AAS体系早期反应、硬化体的抗压强度和收缩性能以及微观结构的影响。研究表明,废陶瓷粉因活性较低,其掺入会延缓AAS凝结时间;碱激发100%废陶瓷粉甚至不能在常温下正常凝结硬化。掺10%～50%废陶瓷粉的碱激发净浆强度7 d前发展慢,但到90 d时抗压强度提高且超过碱激发100%矿渣的抗压强度;更高掺量会导致碱激发净浆及砂浆强度的显著下降。AAS中掺废陶瓷粉可有效降低砂浆的自收缩,但会不同程度地增加干缩,掺量低于20%时对碱激发水泥砂浆的干缩影响小。综合考虑净浆和砂浆的各项性质,认为废陶瓷粉在AAS中具有应用价值。     

地下室混凝土连续外墙裂缝产生原医及防治措施的探讨

地下室混凝土的连续外墙裂缝和渗漏会对建筑结构整体性、耐久性及使用性产生直接的影响。本文主要对裂缝及其产生的原因各要素进行分析,并就这些因素提出一些对于裂缝进行预防的相应措施及处理方法。     

硅灰对高强地聚物胶凝材料性能的影响

以矿渣、粉煤灰和硅灰为原材料制备高强地聚物,利用单一质心设计法对原材料组成进行设计优化,研究了硅灰对凝结硬化过程以及对硬化浆体抗压强度的影响。结果表明:硅灰充分发挥了细颗粒作用,充填在矿渣和粉煤灰堆积空隙中,由此释放的激发剂提高了固体颗粒表面的液膜厚度,从而改善地聚物的流动性,降低浆体的触变性、屈服应力和塑性黏度;由于高活性,部分硅灰在强碱性溶液中快速溶解,使得激发剂中硅酸根离子浓度提高,碱度降低,从而使矿渣和粉煤灰的反应速率降低,减缓C—A—S—H凝胶形成,宏观上表现为凝结时间延长,加速期迟滞,反应热峰值和累计放热量降低,硬化体早期强度发展受到影响。当矿渣含量>50%、粉煤灰含量<30%且硅灰含量<30%时,地聚物砂浆强度超过100MPa,满足新拌性能要求,具有制备超高性能混凝土的可行性。     

强化安全管理 确保安全生产

电力企业生产的特殊性,决定了安全管理在整个电力生产过程中的重要性,安全管理工作的好坏直接影响到电力企业的安全生产以及社会的稳定和经济的发展,强化安全管理确保安全生产是电力企业工作的重要任务。     

CLDH对矿渣基地聚合物微观结构和性能的影响

地聚合物因其节能减排、性能优异而广受关注。本工作提出了地聚合物相调控的概念,并在矿渣基地聚合物体系中,使用煅烧层状双氢氧化物(CLDHs),研究其对微观结构和性能的影响。同步辐射高能XRD及PDF计算、TEM等表征结果揭示了CLDH的再水化反应,在微观结构上提高了晶胶比和凝胶的短程有序性。在宏观性能上,掺入CLDH的地聚合物力学性能和保水性得到提高,自收缩和干燥收缩显著降低。掺用CLDH作为改善地聚合物微观结构的一种技术方法,有助于解决地聚合物的性能缺陷问题,为制备高性能地聚合物提供了一个新思路。     

Activating process of geopolymer source material: Kaolinite

The calcining process was recorded by differential scanning calorimetry and thermogravimetry (DSC-TG). The dehydroxylation (activating process) was partitioned into two steps by calculating and comparing the O—H bond lengths between inner hydroxyl group and surface hydroxyl group, as well as the ionic bond of Al—OH and position of —OH. X-ray diffraction (XRD) and compressive strength measurement show that the activity of calcined materials increases with the increasing of temperature in dehydroxylation region but decreases abruptly in the “spinel” region. The suggested temperature for activating kaolinite is 900 °C. Funded by the National High-Tech Research and Development Program of China(No. 2006AA06Z225)