排序方式: 共有19条查询结果,搜索用时 0 毫秒
1.
在丁二酮肟(DMG)和亚硝酸钠存在的氨水-氯化铵缓冲介质中,以EDTA作掩蔽剂,建立了测定锌电解液中钴的络合物吸附催化波极谱法。探究了掩蔽剂EDTA用量的选择,结果表明:所需EDTA的量与溶液中锌的含量有关,当EDTA与锌的物质的量比nEDTA/nZn为1.15时为最佳选择,此时可消除锌电解液中高浓度锌及其他共存杂质金属离子对测定痕量钴的干扰。对底液酸度、氨水-氯化铵缓冲液用量、丁二酮肟乙醇溶液用量和亚硝酸钠溶液用量,以及静置时间等进行了优化。结果表明,在优化的实验条件下,钴的浓度分别在5.0×10-11~5.0×10-9和5.0×10-9~3.2×10-7mol/L范围内时与其对应的二阶导数波峰电流Ip(nA)呈良好的线性关系,相关系数分别为0.9980和为0.9997,方法检出限为2.0×10-12mol/L。将实验方法应用于中性上清夜、锌电解新液和除钴后液等实际样品分析,测定值与国标方法GB/T 223.22—1994(亚硝基R盐分光光度法,NRS)比较,相对误差(RE)在±4.5%范围内,相对标准偏差(RSD,n=6)不大于2.7%。方法线性范围宽,对锌电解液中钴的测定具有很高选择性,适用于湿法冶金过程控制分析。 相似文献
2.
为了提高继电保护整定值在线校核的效率,提出按照各支路的重要度对继电保护整定值进行有序校验。部分支路受潮流冲击后易故障,且断开后易引起连锁故障,所以提出利用潮流熵评估支路重要度。利用基于潮流转移熵的指标Q1i评价了支路因故障断开后引发连锁故障的可能性,利用基于潮流分布熵的指标Q2i评价了支路抵抗潮流冲击的能力。采用Q1i、Q2i的乘积对支路重要度进行综合评价。利用IEEE 3机9节点系统上的仿真算例验证了所提方法的正确性。最后为了简化计算过程,提出采用分布系数法计算各支路的潮流变化。 相似文献
3.
4.
5.
近些年来,振荡反应受到了相当的重视,用途越来越广泛,本文概述了振荡反应的分类及其在分析化学领域中的应用,同时展望了化学振荡的未来。 相似文献
6.
The chemical components of the essential oils in the barks and leaves of Eucommia ulmoides Oliver were analyzed and compared by chromatograms and mass spectra technique, heuristic evolving latent projections (HELP),
alternative moving window factor analysis (AMWFA) algorithms and normalization method based on the peak areas; the flavones
in the barks and leaves of Eucommia ulmoides Oliver were separated on an ODS column by gradient elution carried out with the flow phase consisting of water, methanol
and phosphoric acid (0.1%), and their contents were quantitatively determined by standard curve method and diode array detection
(DAD) at 362 nm. The results show that 68 and 73 compounds respectively from essential oils of the barks and leaves of Eucommia ulmoides Oliver are identified, and there are 33 mutual compounds among 108 compounds determined. The total contents of these volatile
components of the two samples possess 92.9% and 97.75% of the gross of the relevant essential oils, respectively; the contents
of the rutin, quercetin and kaempferol in the barks and leaves of Eucommia ulmoides Oliver are 0.016 9, 0.003 6, 0.002 1 and 0.064 4, 0.030 2, 0.010 0 mg/g, respectively, and the determination recoveries are
95.2%–106.2%. The comparative analysis shows that for the barks and leaves of Eucommia ulmoides Oliver, there are significant differences in their components of the relevant essential oils and flavones.
Foundation item: Project(20235020) supported by the National Natural Science Foundation of China 相似文献
7.
8.
食醋非线性化学指纹图谱掺伪鉴别原理的研究 总被引:1,自引:0,他引:1
针对食醋掺伪问题对食醋非线性化学指纹图谱进行研究。通过对"溴酸钠-硫酸锰-硫酸-丙酮"体系的振荡机理的分析及食醋成分分析探讨食醋非线性化学指纹图谱的原理。通过正交试验考察建立食醋非线性化学指纹图谱的条件,并考察总酸、食盐、防腐剂对食醋非线性化学的影响。结果表明,食盐、山梨酸对食醋非线性化学指纹图谱影响较大,应在试验前去除食醋样品中的盐分;在检测过程中,应严格控制振荡体系中物种及其浓度、电极类型、温度、搅拌速率、食醋用量。食醋非线性化学指纹图谱是食醋众多成分的整体表征,而不是一种或几种物质的体现,能表达食醋的真正质量,为食醋的掺伪鉴别和质量评价提供一种新的方法。 相似文献
9.
10.
Systematically structural identification of nitriccompounds in crude oil with chemometric resolution
Aimed at the problem of classification of non-hydrocarbons of crude oil, the theoretical standpoint that the polarity of a compound depends on the whole structure and composition of molecule instead of a kind of heteroatom or its functional group was presented. A method was established for the systematically structural identification of nitric compounds in crude oil. The pre-fractionation of a crude oil sample into 7 fractions was performed by diadsorption column chromatography with neutral aluminum oxide and silica gel. Subsequently, the individual components were obtained by using capillary column gas chromatography, and the types of compounds were detected by a mass spectrometer. In combination with a chemometric resolution, the compounds of fraction were further identified. This method can relieve the difficulty of classical analysis in identifying those species with very low contents or without being completely separated. The structures of 168 nitric compounds in a crude oil sample were determined by this method. 相似文献