Development of Cellulose Aerogel as a New Material for the Reduction of Harmful Substances in Cigarette Smoke

The current study proposes a novel and improved cigarette filtration design comprising cellulose nanofibers (CNFs) and powdered activated carbons (PACs) with different dry matter contents. The proposed filter samples were primarily analyzed to verify their applicability as cigarette filters via measurements and standard tests, such as SEM, BET, DSC, and airflow permeability analysis. The results were compared with the cellulose acetate (CA) sample used as a conventional cigarette filter. The preliminary results indicated noticeable improvement compared to the reference CA. Also, the cigarettes were tested using a smoking machine, and the filtered smoke was analyzed using GC–MS to evaluate the filters' performance in reducing the harmful substances present in the smoke. The results showed that the filters made of CNF and PAC significantly decreased the toxic substances compared with the reference but did not affect the nicotine substantially and therefore will not negatively impact the trance level of smokers.

     

A Comparison of Modified and Unmodified Cellulose Nanofiber Reinforced Polylactic Acid (PLA) Prepared by Twin Screw Extrusion

The goal of this work was to evaluate the effect of chemical modification of cellulose nanofibers (CNF) on the properties of polylactic acid (PLA) nanocomposites. Acetylated nanofibers (ACNF), with degree of substitution 1.07, were isolated from acetylated kenaf fibers by mechanical treatments. Acetylated nanofibers showed more hydrophobic properties compared to non-acetylated ones. The results showed that both crystallinity and thermal stability of acetylated nanofibers were lower than non-acetylated ones. The nanocomposites were prepared by premixing two PLA master batches, one with a high concentration of ACNF and the second with CNF. These were diluted to final concentrations (5?wt%) during the extrusion. The morphology studies of PLA and its nanocomposites showed nanofiber aggregates in both materials. The results showed that the tensile and dynamic mechanical properties were enhanced for both acetylated and non-acetylated nanocomposites compared to the neat PLA matrix while no significant improvement was observed for the acetylated nanocomposites compared to non-acetylated ones. However, the storage modulus increased slightly for acetylated nanocomposites compared to non-acetylated ones.