H_2O_2增效TiO_2/凹凸棒石光催化体系降解亚甲基蓝

以钛酸四丁酯为前驱体,天然凹凸棒石为载体,采用溶胶凝胶法制备了TiO_2/凹凸棒石复合光催化剂,并用XRD、TEM对其进行表征.以亚甲基蓝染料为模拟污染物,采用300 W汞灯为紫外光源,以光催化实验来评价该催化剂的活性,并研究了H_2O_2的引入对光催化活性的影响.实验结果表明,H_2O_2能显著提高染料的脱色效率:亚甲基蓝的初始浓度为50 mg/L,催化体系为2 mmol/L H_2O_2+0.5 g/L TiO_2/凹凸棒石+UV(紫外线),光催化10 min后其脱色率为95%,相对于单独的0.5 g/L TiO_2/凹凸棒石+UV催化体系,其脱色率提高了约50%.全波段扫描显示,加入H_2O_2后,亚甲基蓝在290 nm对应的苯环吸收蜂急剧下降,665 nm对应的最大吸收峰则近乎消失,且没有新的吸收峰产生.     

基于ARM的温度采集与以太网传输系统的设计

基于ARM的温度采集与以太网传输系统重点是实现稳定地采集实时温度、批量传送采集结果。系统采用基于ARM内核LPC2214对温度传感器LM235输出的模拟信号进行采集;用DM9000控制以太网传输采集结果。基于DM9000的以太网传输具有较高的可靠性,适合批量数据传输,并且可实现较远距离通信。此外,为方便调试和扩展,设计串口通信模块和JTAG仿真调试接口模块。最终,实现对温度的实时采集与传输。     

基于DSP TMS320VC5509A图像采集的脱机系统设计与实现

首先介绍了脱机系统的结构,并给出系统中核心芯片DSP TMS320VC5509A与存储芯片EEPROMAT25640的硬件电路设计方案,从该DSP的各种BOOTLOADER方式中分析研究,考虑到烧写速度及电路设计简洁性等因素,采用了SPI EEPROM模式。随后介绍了加载过程中的数据表——BOOT表的概念及生成方式,详细介绍了程序烧写至存储器的过程及软件实现的流程图,最终用一个实例实现系统的脱机运行。     

Rare earth element geochemistry of dolomites in the Middle Devonian Presqu'ile barrier, Western Canada Sedimentary Basin: implications for fluid-rock ratios during dolomitization

Rare earth elements (REE) were determined in fine, medium and coarse crystalline replacement dolomites, and for saddle dolomite cements from the Middle Devonian Presqu'ile barrier from Pine Point and the subsurface of the Northwest Territories and north-eastern British Columbia. REE patterns of the fine crystalline dolomite are similar to those of Middle Devonian limestones from the Presqu'ile barrier. Fine crystalline dolomite occurs in the back-barrier facies and may represent penecontemporaneous dolomitization at, or just below, the sea floor. Medium crystalline dolomite is widespread in the lower southern and lower central barrier. Medium crystalline dolomite is slightly depleted in heavy REE compared with Devonian marine limestones and fine crystalline dolomite, and has negative Ce and Eu anomalies. Medium crystalline dolomites replaced pre-existing limestones or were recrystallized from earlier fine crystalline dolomites. During these processes, the REE patterns of their precursors were modified. Late stage, coarse crystalline replacement dolomite and saddle dolomite cements occur together in the upper barrier and have similar geochemical signatures. Coarse crystalline dolomites have negative Eu anomalies, and those from the Pine Point area also have positive La anomalies. Saddle dolomites are enriched in light REE and have positive La anomalies. The REE patterns of coarse crystalline dolomite and saddle dolomite differ from those of marine limestones and fine and medium crystalline dolomites, suggesting that different diagenetic fluids were responsible for these later dolomites. Although massive dolomitization requires relatively large volumes of fluids in order to provide the necessary amounts of Mg^2-. dolomitization and subsequent recrystallization may not necessarily modify the REE signatures of the precursor limestones because of the low concentrations of REE in most natural fluids. Thus, relative fluid-rock ratios during diagenesis may be estimated from REE patterns in the diagenetic and precursor minerals. Fine crystalline dolomites retain the REE patterns of their limestone precursors. In the medium and coarse crystalline dolomites the precursor REE patterns were apparently altered by large volumes of fluids involved during dolomitization. This study suggests that REE compositions of dolomites and their limestone precursors may provide important information about the relative amounts of fluids involved during diagenetic processes, such as dolomitization.     

最新GPM遥感数据在淮河和海河流域的误差分析

为了加深对最新GPM卫星降水产品在具体流域的误差特性的了解,利用中国日降水分析产品(CPAP),选取相关系数(CC)、平均误差(ME)、探测率(POD)、错报率(FAR)以及6个极端降雨指标评估2014年4月至2016年3月期间IMERG卫星降水产品和GSMap-Gauge卫星降水产品在淮河、海河流域的误差特性及性能表现。结果表明:(1)两种卫星降水产品的总误差的空间分布完全不同,以高估为主要表现。(2)产品在百分位指标(RR99p及RR95p)和绝对阈值指标(R20及R20TOT)的表现非常好,相关系数超过0.84。对于持续时间指标(CWD及CDD),表现则均不理想,但GSMap-Gauge产品仍优于IMERG产品。(3)不论是日、月尺度下的比较,还是在探测率及错报率上,GSMap-Gauge产品性能表现总是更优。月降雨量估测结果的准确性明显高于日降雨量估测结果。     

杭州地铁储气砂土的渗气性试验研究

浅层气地质灾害对工程的影响日益受到重视,认清储气土层的气渗透特性是采取积极有效工程措施防治灾害影响的基础。以杭州地铁所遇的储气砂为研究对象,利用自制的渗气性量测装置对其进行了系统的试验研究。结果表明：地铁工程所遇的浅层气储气砂层属渗透性极好储层,渗透率达2 960×10-3 ?m2;砂土中气渗透规律符合达西定律;饱和度较低时,含水率的增加对砂土的渗气性影响很小;随着饱和度的增加,气渗透性逐渐减弱,在饱和度大于80 %后,渗气系数急剧减小直至完全不透气;饱和度的变化相对于干密度对储气砂土的渗气性影响更为显著。     

耒宜高速公路路堑边坡变形破坏特征及其综合治理

耒宜高速公路修建于山岭重丘区 ,沿线地形、地质条件差异较大 ,路堑开挖边坡类型较多 ,特征不一。本文介绍了路堑边坡的主要特征、边坡失稳的主要原因及治理对策。     

太阳活动上升期源表面太阳风质量流量的速度关系分析

以ＩＰＳ速度、光球磁场、Ｋ─日冕偏振亮度和卫星实地观测数据为基础,综合生成处于太阳活动上升期的１９７６年１０个太阳周（１６４３─１６５２卡林顿周）的源表面高度（Ｒ＝２．５Ｒｓ,Ｒｓ为太阳半径）和日球空间中（ＩＡＵ）太阳同质量流量速度谱。结果表明,速度谱存在与太阳活动上升期一致的＂三段＂结构,且各段分别与不同的磁结构区相对应。     

乐亭发生特大渔业污染案渔民获赔1300多万元

2002年4月12日,天津海事法院对河北省乐亭特大渔业污染案做出一审判决,责令被告迁安第一造纸厂等9家单位连带赔偿原告乐亭18户渔民经济损失总计人民币1 365.97万元,立即停止侵害,不得再排放污水入海,消除继续污染原告养殖区域的危险。 接到判决书,原告对笔者表示说,他们“对     

浅地层剖面仪在港池探测中的应用

介绍了3200XS型浅地层剖面仪工作原理及其数据处理过程,在港池开挖前进行浅地层剖面测量可以详细了解港池内各地层单元的分布和埋深,并对区内的灾害地质体或者障碍物进行有效识别,以保障施工安全和节约工程支出;结合海南某港池的浅剖探测实例,分析了该港池的地层单元划分及地层内物质识别,针对浅地层剖面测量前发射参数的选择和测量中的多次回波、调头区变形等问题等进行了探讨。