Preparation of filter aids based on diatomites

Two major deposits of diatomaceous earth (diatomite) in the region of the Balkan Peninsula, the Kolubara basin (Serbia and Montenegro) and the Vesje deposit (Former Yugoslav Republic of Macedonia), were selected for detailed investigation of their possible application in preparation of beer filter aids. Chemical, mineralogical and structural properties of diatomite samples were analyzed with the aim of predicting the filtration efficiency. Results of beer filtering compounds preparation are presented in this paper. The parameters of crushing, drying, calcination and classification are also defined. Beer filtration tests proved diatomites to be satisfactory and not causing any degradation of filtration process or beer quality. Technological flow scheme for obtaining the beer filter aids is proposed in the paper.     

Use of fallout 137Cs for documenting the chronology of overbank sediments from the river Sava, Croatia, and interpreting their geochemical patterns

This paper attempts to determine the impact of former Pb-Zn-Ba mining activities in Slovenian drainage basin on overbank sediments of the Sava river (West Croatia). Among the four studied sequences (S7, S8, S9, S10), the most upstream profile S7 showed the most pronounced impact of ore mining. Mercury was enriched more than 100-fold; Pb and Zn had a strong positive correlation (r > 0.99). Two factor models clearly revealed the Pb-Ba-Hg association in the lower-lying carbonate (CA) population of all four profiles, but only in the overlying silicate (SI) population of profile S7. Factor analysis confirmed this association in the total sediment (90 samples) as well as separately in the CA (33 samples) and SI (57 samples) populations. Based on a comparison with an undisturbed soil profile, the vertical distribution of ¹³⁷Cs in profile S7 was interpreted to be the combination of caesium deposition caused by a flood in 1964 and by post-depositional redistribution.     

Granulometric and chemical composition of the Sava River sediments upstream and downstream of the Krsko nuclear power plant

Total concentrations of 13 elements (K, Ca, Ti, Cr, Mn, Fe, Cu, Zn, Rb, Sr, Y, Zr, Pb) in the size-fractionated Sava River sediments upstream and downstream of the Krsko nuclear power plant together with metal speciation within bulk sediment have been investigated. Trace metals generally increase with decreasing particle size, however, because of entrapment of organic matter in the 0.63–1 mm fraction, concentrations in the coarser sediment fraction are higher than expected. Exchangeable Pb, Zn, Cu, Mn, Cr and Fe are generally found to represent a negligible fraction of the total metal concentration of the bulk sediment. Seasonal variations of the Pb, Zn and Cu concentrations in the <0.5 mm fraction reflect decreased values during the spring period. Heavy metal concentrations in the 2003 waste water discharges from the Krsko nuclear power plant released into the Sava River were much lower than their maximum allowed values. Combined rubidium and organic matter normalization of the Zn, Pb and Cu concentrations, which was applied on the minus 0.063 mm fraction, indicated three potential sources of contaminants.     

Vibration of beams on partial elastic foundations

The natural response of a beam or pile having only a portion of its span supported by an elastic foundation is investigated for the two cases when both ends are either simply supported or free. The derivation of the shape functions and the computed natural frequencies are compared with the extreme cases where the element is either completely supported by, or fully detached from, the elastic foundation.     

The influence of fly and bottom ash deposition on the quality of Kastela Bay sediments

The objective of this study was chemical and radiological characterization of Kastela Bay sediments exposed to numerous anthropogenic sources like deposition of fly and bottom ash enriched in radionuclides and heavy metals, chemical plant, cement plant, iron plant, shipyard, electroplating facility, untreated industrial and domestic waste waters as well as heavy traffic. Totally, 33 samples of the mixture of fly and bottom ash, 12 sediment cores ranging from 0 to 40 cm and nine surface sediment samples were analyzed. Enrichment in heavy metals in the mixture of fly and bottom ash was ranging from 1.5 to 36 times compared to flysch soil while ²²⁶Ra and ²³⁸U were up to 50 times enriched compared to average activities characteristic for surrounding soils developed on the Middle and Upper Eocene flysch. Maximum ²³⁸U activity was approximately 32 times higher and ²²⁶Ra approximately 40 times higher in the Kastela Bay sediment compared to mean value determined for Adriatic sediments. The highest enrichment in sediment cores compared to background values were found for Zn (35.6 times), Pb (16 times), Cr (9.1 times) and Ni (4 times)     

Detection of radical species formed by the ozonolysis of α-pinene

Highly reactive free radical species have been subject of many toxicological in vivo and in vitro studies because of the oxidative cell damage they cause. Similar species have been postulated to be the key intermediates formed during many environmental chamber reactions and atmospheric oxidation of organic species present in the troposphere. Thus, detection and characterization of these transient radical species are important steps in understanding the atmospheric chemistry and confirming the reaction pathways involved in secondary organic aerosol formation. Study of these species is particularly difficult because of their short life-times. To facilitate such studies, 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) and diethyl-(2-methyl-1-oxido-3,4-dihydro-2H-pyrrol-2-yl) phosphonate (DEPMPO) nitrone spin traps were used to capture radicals formed from the α-pinene/ozone reaction. Electrospray ionization/tandem mass spectrometry (ESI/MSⁿ) was applied to elucidate their structures. Characteristic fragments with m/z 114, m/z 130 and m/z 148 with the DMPO trap, and m/z 236, m/z 252, and m/z 270 with the DEPMPO trap indicated the existence of alkyl, alkoxyl and peroxyl radicals, respectively.     

Pyrite Formation in Organic-rich Clay, Calcitic and Coal-Forming Environments

The early diagenetic characteristics of pyrite formation processes in a Miocene freshwater sequence of mixed sediments （coal fragments in clays, sandstones or shales） alternating with continuous brown coal layers was investigated. Based on abundant minerals, the following main sedimentary environments were distinguished： the illite-montmorillonitic （I-M）, calcitic （Ct） and coal-forming environment （CL）. For these hydrogeochemically differing environments the effects of limiting factors on the pyrite formation process （availability of sulphate and Fe, amount of organic matter and participation of organic sulphur） were assessed by correlation analysis. Significant differences in the effects of these limiting factors in the particular environments were observed. These differences were explained taking in account the different oxidative activity, Fe-complex and surface complex forming properties of humic substances in dependence of pH of environment and the abundance of sorptionally active clay minerals. In environments having a relatively low pH and containing clay minerals （I-M- and CL-environments） the oxidative activity of humic substances （Hs） on pyrite precursors was greatly prevented however pyrite formation depended on reactive Fe availability as the consequence of complex formation. On the contrary, in environments with a relatively high pH, as it was the calcitic, the oxidative activity of Hs was greatly enhanced, thus oxidizing the sulfur precursors of pyrite. The oxidation degree of organic matter was probably also a consequence of the differing activity of the humic electron-acceptors.     

Shear-wave splitting and reservoir crack characterization: the Coso geothermal field

This paper aims to improve current understanding of the subsurface fracture system in the Coso geothermal field, located in east-central California. The Coso reservoir is in active economic development, so that knowledge of the subsurface fracture system is of vital importance for an accurate evaluation of its geothermal potential and day-to-day production. To detect the geometry and density of fracture systems we applied the shear-wave splitting technique to a large number of high-quality seismograms from local microearthquakes recorded by a permanent, 16-station, down-hole, 3-component seismic array running at 480 samples/s. The analysis of shear-wave splitting (seismic birefringence) provides parameters directly related to the strike of the subsurface fractures and their density (number of cracks per unit volume), and, consequently, is an important technique to outline zones of high permeability. Three major fracture directions N10–30W, N0–20E, and N40–50E, of which the first and the second are the most prominent, were identified from the seismograms recorded by the 16-station down-hole array. All orientations are consistent with the known strike of local sets of faults and fractures in local wells and at the surface, as well as with previous analyses of seismic anisotropy in the region. The high quality of the recordings has allowed us to launch an unprecedented investigation into the characteristics of the temporal variations in crack polarization and crack density in a producing geothermal environment. Preliminary results point to significant temporal changes in shear-wave time delays, probably influenced by temporal changes in crack density within a period of 5 years (1996–2000). They are tentatively interpreted as due to a local 3% increase in shear-wave velocity in the southwestern part of the field during 1999.