Astrometric investigation with the Tautenburg Schmidt telescope

The observations and the plate reduction technique for the determination of positions and absolute proper motions which is used in Potsdam are described. Recent results have shown that an accuracy of about 0 _. 1 for positions and 0 _. ⁷ cent _. ^–1 for proper motions can be achieved both for bright (8^m–12^m) and faint (16^m–18^m) stars. Three astrometric programmes using the Tautenburg plates are presented.     

Investigation of the stable isotope fractionation in speleothems with laboratory experiments

Many speleothems show evidence for calcite precipitation under disequilibrium conditions. To improve the understanding of these kinetic processes, several laboratory experiments were performed to study the fractionation of stable oxygen and carbon isotopes during the precipitation of calcite. Carbonate was precipitated under controlled conditions from both a body of standing water (beaker experiments) and a solution flowing along a channel (channel experiments) at a relative humidity of 100%. Slow degassing of CO₂, simulated by the beaker experiments, results in δ¹⁸O values in equilibrium with the solution. In contrast, the δ¹³C values show a significant enrichment, inversely proportional to the height of the solution in the beakers. Fast degassing of CO₂, simulated by the channel experiments, showed an enrichment of both δ¹³C and δ¹⁸O and a slope of Δδ¹³C/Δδ¹⁸O of 1.4±0.6. These results represent experimental evidence for the Hendy effect, which is manifested in (i) a progressive increase in δ¹⁸O and δ¹³C away from the growth axis and (ii) a positive correlation between δ¹⁸O and δ¹³C along a single growth layer of a stalagmite.     

Crustal structure of the Eastern Alps along the TRANSALP profile from wide-angle seismic tomography

The objective of the TRANSALP project is an investigation of the Eastern Alps with regard to their deep structure and dynamic evolution. The core of the project is a 340-km-long seismic profile at 12°E between Munich and Venice. This paper deals with the P-wave velocity distribution as derived from active source travel time tomography. Our database consists of Vibroseis and explosion seismic travel times recorded at up to 100 seismological stations distributed in a 30-km-wide corridor along the profile. In order to derive a velocity and reflector model, we simultaneously inverted refractions and reflections using a derivative of a damped least squares approach for local earthquake tomography. 8000 travel time picks from dense Vibroseis recordings provide the basis for high resolution in the upper crust. Explosion seismic wide-angle reflection travel times constrain both deeper crustal velocities and structure of the crust–mantle boundary with low resolution. In the resulting model, the Adriatic crust shows significantly higher P-wave velocities than the European crust. The European Moho is dipping south at an angle of 7°. The Adriatic Moho dips north with a gentle inclination at shallower depths. This geometry suggests S-directed subduction. Azimuthal variations of the first-break velocities as well as observations of shear wave splitting reveal strong anisotropy in the Tauern Window. We explain this finding by foliations and laminations generated by lateral extrusion. Based on the P-wave model we also localized almost 100 local earthquakes recorded during the 2-month acquisition campaign in 1999. Seismicity patterns in the North seem related to the Inn valley shear zone, and to thrusting of Austroalpine units over European basement. The alignment of deep seismicity in the Trento-Vicenza region with the top of the Adriatic lower crust corroborates the suggestion of a deep thrust fault in the Southern Alps.     

Permanent Scatterers for landslide investigations: outcomes from the ESA-SLAM project

Within the SLAM project (Service for Landslide Monitoring), launched in 2003 by the European Space Agency (ESA) the Permanent Scatterers (PS) technique, a multi-image interferometric approach, coupled with the interpretation of aerial-photos and optical satellite images, was carried out for landslide investigations. The PS analysis was applied at a regional scale as support for landslide inventory mapping and at local scale for the monitoring of single well-known slope movements. For the integration of the PS measurements within a landslide inventory the Arno river basin (Italy) was chosen as test site for the presence of a high number of mass movements (to date about 300 areas at high landslide risk and more than 27,000 individual landslides mapped by the institutional authorities). About 350 SAR images have been interferometrically processed by means of the PS technique, with the detection of about 600,000 PS. The use of optical images contributed spatial meaning to the point-wise information provided by the PS, making it easier to identify terrain features related to slope instability and the landslide boundaries. Here we describe the employed methodology and its impact in the updating of a preexisting landslide inventory. 6.8% of the total number of landslides were characterized by ground displacement measurements from the PS: 6.1% of already mapped landslides and 0.8% of new unstable areas detected through the PS analysis. Moreover, most of the PS are located in urban areas, showing that the proposed methodology is suitable for landslide mapping in areas with a quite high density of urbanization, but that over vegetated areas it still suffers from the limitations induced by the current space-borne SAR missions (e.g. temporal de-correlation). On the other hand, the use of InSAR for the monitoring of single slow landslides threatening built-up areas has provided satisfactory results, allowing the measurement of superficial deformations with high accuracy on the landslide sectors characterized by a good radar reflectivity and coherence.     

Redetermination of the transformation enthalpies of the xanthoconite–proustite, pyrostilpnite–pyrargyrite and trechmannite–smithite phase transitions

 We report here refined values of the transformation enthalpy for xanthoconite to proustite (54.81 kJ/mol) and pyrostilpnite to pyrargyrite (40.32 kJ/mol). Additionally, the enthalpy for the transformation of trechmannite to smithite (5.82 kJ/mol) has been determined. The refinement was possible by taking into account a previously unknown dependence of electrochemical signals on the amount of substance undergoing the reduction process. Received December 21, 1995/Revised, accepted June 29, 1996     

Hotspots and a clumpy disc: variability of brown dwarfs and stars in the young σ Ori cluster

The properties of accretion discs around stars and brown dwarfs in the σ Ori cluster (age 3 Myr) are studied based on near-infrared (IR) time series photometry supported by mid-IR spectral energy distributions (SEDs). We monitor ∼30 young low-mass sources over eight nights in the J and K band using the duPont telescope at Las Campanas. We find three objects showing variability with J -band amplitudes  ≥0.5 mag  ; five additional objects exhibit low-level variations. All three highly variable sources have been previously identified as highly variable; thus, we establish the long-term nature of their flux changes. The light curves contain periodic components with time-scales of  ∼0.5–8 d  , but have additional irregular variations superimposed – the characteristic behaviour for classical T Tauri stars. Based on the colour variability, we conclude that hotspots are the dominant cause of variations in two objects (#19 and #33), including one likely brown dwarf, with spot temperatures in the range of 6000–7000 K. For the third one (#2), a brown dwarf or very low-mass star, inhomogeneities at the inner edge of the disc are the likely origin of variability. Based on mid-IR data from Spitzer , we confirm that the three highly variable sources are surrounded by circum-(sub)-stellar discs. They show typical SEDs for T Tauri-like objects. Using SED models, we infer an enhanced scaleheight in the disc for the object #2, which favours the detection of disc inhomogeneities in light curves and is thus consistent with the information from variability. In the σ Ori cluster, about every fifth accreting low-mass object shows persistent high-level photometric variability. We demonstrate that estimates for fundamental parameters in such objects can be significantly improved by determining the extent and origin of the variations.     

The mesoscale variability in the Caribbean Sea. Part I: Simulations and characteristics with an embedded model

The variability in the Caribbean Sea is investigated using high resolution (1/15°) general circulation model experiments. For the first time in this region, simulations were carried out with a 2-way nested configuration of the NEMO primitive equation model. A coarse North Atlantic grid (1/3°) reproduces the main features of the North Atlantic and Equatorial circulation capable of influencing ocean dynamics in the Caribbean Sea. This numerical study highlights strong dynamical differences among basins and modifies the view that dynamics are homogeneous over the whole Caribbean Basin. The Caribbean mean flow is shown to organize in two intense jets flowing westward along the northern and southern boundaries of the Venezuela Basin, which merge in the center of the Colombia Basin. Diagnostics of model outputs show that width, depth and strength of baroclinic eddies increase westward from the Lesser Antilles to the Colombia Basin. The widening and strengthening to the west is consistent with altimetry data and drifter observations. Although influenced by the circulation in the Colombia Basin, the variability in the Cayman Basin (which also presents a westward growth from the Chibcha Channel) is deeper and less energetic than the variability in the Colombia/Venezuela Basins. Main frequency peaks for the mesoscale variability present a westward shift, from roughly 50 days near the Lesser Antilles to 100 days in the Cayman Basin, which is associated with growth and merging of eddies.     

Trace element diagenesis in pyrite-rich sediments of the Achterwasser lagoon, SW Baltic Sea

The early diagenesis of trace elements (V, Cr, Co, Cu, Zn, As, Cd, Ba, U) in anoxic sediments of the Achterwasser, a shallow lagoon in the non-tidal Oder estuary in the Baltic Sea, was investigated in the context of pyrite formation. The dissolved major redox parameters show a two-tier distribution with transient signals in the occasionally re-suspended fluid mud layer (FM) and a permanently established diagenetic sequence in the sediment below. Intense microbial respiration leads to rapid depletion of O₂ within the uppermost mm of the FM. The reduction zones of Mn, Fe and sulfate overlap in the FM and in the permanently anoxic sediment section which appears to be a typical feature of estuarine sediments, under low-sulfate conditions. Degrees of pyritization (DOP) range from 50% in the FM to remarkably high values > 90% at 50 cm depth. Pyrite formation at the sediment surface is attributed to the reaction of Fe-monosulfides with intermediate sulfur species via the polysulfide pathway. By contrast, intense pyritization in the permanently anoxic sediment below is attributed to mineral growth via adsorption of aqueous Fe-sulfide complexes onto pyrite crystals which had originally formed in the surface layer.The studied trace elements show differential behavior patterns which are closely coupled to the diagenetic processes described above: (i) Zn, Cu and Cd are liberated from organic matter in the thin oxic layer of the sediment and diffuse both upwards across the sediment/water boundary and downwards to be trapped as monosulfides, (ii) V, Cr, Co and As are released during reductive dissolution of Mn- and Fe-oxyhydroxides, (iii) U removal from pore water occurs concomitantly to Fe reduction in the FM and is attributed to reduction of U(VI) to U(IV), (iv) the Ba distribution is controlled by reductive dissolution of authigenic barite in the sulfate reduction zone coupled with upward diffusion and re-precipitation. The incorporation of trace elements into pyrite is most intense for Co, Mn and As, intermediate for Cu and Cr and little to negligible for U, Zn, Cd, V and Ba. The observed trend is largely in agreement with previous studies and may be explained with differing rates for ligand exchange. Slow and fast ligand exchange and thus precipitation kinetics are also displayed by downcore increasing (Mn, Cr, Co and As) or constantly low (Zn, Cu, Cd) pore water concentrations. The downward increasing degrees of trace metal pyritization (DTMP) for Co, Cu, Zn and As are, in analogy to pyrite growth, assigned to adsorption of sulfide complexes or As oxyanions onto preexisting pyrite minerals.     

Ocean currents determine functional connectivity in an Antarctic deep‐sea shrimp

The coherency among larval stages of marine taxa, ocean currents and population connectivity is still subject to discussion. A common view is that organisms with pelagic larval stages have higher dispersal abilities and therefore show a relatively homogeneous population genetic structure. Contrary to this, local genetic differentiation is assumed for many benthic direct developers. Specific larval or adult migratory behavior and hydrographic effects may significantly influence distribution patterns, rather than passive drifting abilities alone. The Southern Ocean is an ideal environment to test for the effects of ocean currents on population connectivity as it is characterized by several well‐defined and strong isolating current systems. In this study we studied the genetic structure of the decapod deep‐sea shrimp Nematocarcinus lanceopes, which has planktotrophic larval stages. We analysed 194 individuals from different sample localities around the Antarctic continent using nine microsatellite markers. Consistent with a previous study based on mitochondrial DNA markers, primarily weak genetic patterns among N. lanceopes populations around the continent were found. Using ocean resistance modeling approaches we were able to show that subtle genetic differences among populations are more likely explained by ocean currents rather than by geographic distance for the Atlantic Sector of the Southern Ocean.     

Abundances in intermediate-mass AGB stars undergoing third dredge-up and hot-bottom burning

High-dispersion near-infrared spectra have been taken of seven highly evolved, variable, intermediate-mass (4–6 M_⊙) asymptotic giant branch (AGB) stars in the Large Magellanic Cloud and Small Magellanic Cloud in order to look for C, N and O variations that are expected to arise from third dredge-up and hot-bottom burning. The pulsation of the objects has been modelled, yielding stellar masses, and spectral synthesis calculations have been performed in order to derive abundances from the observed spectra. For two stars, abundances of C, N, O, Na, Al, Ti, Sc and Fe were derived and compared with the abundances predicted by detailed AGB models. Both stars show very large N enhancements and C deficiencies. These results provide the first observational confirmation of the long-predicted production of primary nitrogen by the combination of third dredge-up and hot-bottom burning in intermediate-mass AGB stars. It was not possible to derive abundances for the remaining five stars: three were too cool to model, while another two had strong shocks in their atmospheres which caused strong emission to fill the line cores and made abundance determination impossible. The latter occurrence allows us to predict the pulsation phase interval during which observations should be made if successful abundance analysis is to be possible.