The Kabanga Ni sulfide deposit, Tanzania: I. Geology, petrography, silicate rock geochemistry, and sulfur and oxygen isotopes

The Kabanga Ni sulfide deposit represents one of the most significant Ni sulfide discoveries of the last two decades, with current indicated mineral resources of 23.23 Mt at 2.64% Ni and inferred mineral resources of 28.5 Mt at 2.7% Ni (Nov. 2008). The sulfides are hosted by a suite of ∼1.4 Ga ultramafic–mafic, sill-like, and chonolithic intrusions that form part of the approximately 500 km long Kabanga–Musongati–Kapalagulu igneous belt in Tanzania and Burundi. The igneous bodies are up to about 1 km thick and 4 km long. They crystallized from several compositionally distinct magma pulses emplaced into sulfide-bearing pelitic schists. The first magma was a siliceous high-magnesium basalt (approximately 13.3% MgO) that formed a network of fine-grained acicular-textured gabbronoritic and orthopyroxenitic sills (Mg# opx 78–88, An plag 45–88). The magma was highly enriched in incompatible trace elements (LILE, LREE) and had pronounced negative Nb and Ta anomalies and heavy O isotopic signatures (δ¹⁸O +6 to +8). These compositional features are consistent with about 20% contamination of primitive picrite with the sulfidic pelitic schists. Subsequent magma pulses were more magnesian (approximately 14–15% MgO) and less contaminated (e.g., δ¹⁸O +5.1 to +6.6). They injected into the earlier sills, resulting in the formation of medium-grained harzburgites, olivine orthopyroxenites and orthopyroxenites (Fo 83–89, Mg# _opx 86–89), and magmatic breccias consisting of gabbronorite–orthopyroxenite fragments within an olivine-rich matrix. All intrusions in the Kabanga area contain abundant sulfides (pyrrhotite, pentlandite, and minor chalcopyrite and pyrite). In the lower portions and the immediate footwall of two of the intrusions, namely Kabanga North and Kabanga Main, there occur numerous layers, lenses, and veins of massive Ni sulfides reaching a thickness of several meters. The largest amount of high grade, massive sulfide occurs in the smallest intrusion (Kabanga North). The sulfides have heavy S isotopic signatures (δ³⁴S wr = +10 to +24) that broadly overlap with those of the country rock sulfides, consistent with significant assimilation of external sulfur from the Karagwe–Ankolean sedimentary sequence. However, based partly on the relatively homogenous distribution of disseminated sulfides in many of the intrusive rocks, we propose that the Kabanga magmas reached sulfide saturation prior to final emplacement, in staging chambers or feeder conduits, followed by entrainment of the sulfides during continued magma ascent. Oxygen isotope data indicate that the mode of sulfide assimilation changed with time. The heavy δ¹⁸O ratios of the early magmas are consistent with ingestion of the sedimentary country rocks in bulk. The relatively light δ¹⁸O ratios of the later magmas indicate less bulk assimilation of the country rocks, but in addition the magmas selectively assimilated additional S, possibly through devolatization of the country rocks or through cannibalization of magmatic sulfides deposited in the conduits by preceding magma surges. The intrusions were tilted at ca. 1.37 Ga, during the Kibaran orogeny and associated synkinematic granite plutonism. This caused solid-state mobilization of ductile sulfides into shear zones, notably along the base of the intrusions where sulfide-hornfels breccias and lenses and layers of massive sulfides may reach a thickness of >10 m and can extend for several 10 s to >100 m away from the intrusions. These horizons represent an important exploration target for additional nickel sulfide deposits.     

Precambrian–Cambrian boundary interval deposition and the marginal platform of the Avalon microcontinent

Thick terminal Proterozoic–lowest Cambrian successions allow reference of the Saint John, New Brunswick, and MacCodrum Brook, southern Cape Breton Island, areas to the marginal platform of the Avalon microcontinent. Marginal-platform siliciclastic-dominated sequences form a cover on Late Precambrian arc successions from southern New Brunswick to North Wales. Their deposition in fault-bounded basins began with the origin of the Avalon microcontinent and development of a persistent transtensional regime in the latest Precambrian. The terminal Proterozoic–lowest Cambrian on the Avalonian marginal platform consists of three successive lithofacies associations: lower subaerial rift to marginal-marine facies; overlying cool-water, wave-influenced, marine platform sandstones and shales; and higher macrotidal quartz arenites (=Avalonian depositional sequences 1–2). Only the Lower Cambrian macrotidal quartz arenites onlap southeast, where they form the oldest Cambrian unit on the inner platform. These major lithofacies are the Rencontre, Chapel Island, and Random formations, respectively, in Avalonian North America. Southwest thinning of the Rencontre–Chapel Island–Random interval in southern New Brunswick reflects slower subsidence of a fault-bounded area in the city of Saint John. The depositional sequence 1–2 unconformity, which falls in the sub-trilobitic Lower Cambrian Watsonella crosbyi Zone of the Chapel Island Formation, persists for 650 km along the marginal platform from southeastern Newfoundland to southern New Brunswick and, potentially, appears in Cape Breton Island. Latest Precambrian-earliest Cambrian epeirogenic and depositional history was very uniform along the marginal platform, and a unified lithostratigraphic nomenclature is appropriate.     

Scattered ground‐roll attenuation using model‐driven interferometry

Scattered ground roll is a type of noise observed in land seismic data that can be particularly difficult to suppress. Typically, this type of noise cannot be removed using conventional velocity‐based filters. In this paper, we discuss a model‐driven form of seismic interferometry that allows suppression of scattered ground‐roll noise in land seismic data. The conventional cross‐correlate and stack interferometry approach results in scattered noise estimates between two receiver locations (i.e. as if one of the receivers had been replaced by a source). For noise suppression, this requires that each source we wish to attenuate the noise from is co‐located with a receiver. The model‐driven form differs, as the use of a simple model in place of one of the inputs for interferometry allows the scattered noise estimate to be made between a source and a receiver. This allows the method to be more flexible, as co‐location of sources and receivers is not required, and the method can be applied to data sets with a variety of different acquisition geometries. A simple plane‐wave model is used, allowing the method to remain relatively data driven, with weighting factors for the plane waves determined using a least‐squares solution. Using a number of both synthetic and real two‐dimensional (2D) and three‐dimensional (3D) land seismic data sets, we show that this model‐driven approach provides effective results, allowing suppression of scattered ground‐roll noise without having an adverse effect on the underlying signal.     

THE KRAMER CREEK,COLORADO METEORITE: A NEW L4 CHONDRITE

The Kramer Creek, Colorado, chondrite was found in 1966 and identified as a meteorite in 1972. Bulk chemical analysis, particularly the total iron content (20.36%) and the ratio of Fe_total/SiO₂ (0.52), as well as the compositions of olivine (Fa_21.7) and orthopyroxene (Fs_18.3) place the meteorite into the L-group of chondrites. The well-defined chondritic texture of the meteorite, the presence of igneous glass in the chondrules and of low-Ca clinopyroxene, as well as the slight variations in FeO contents of olivine (2.4% MD) and orthopyroxene (5.6% MD) indicate that the chondrite belongs to the type 4 petrologic class.     

Climatic implications of correlated Upper Pleistocene glacial and fluvial deposits on the Cinca and Gállego Rivers (NE Spain) based on OSL dating and soil stratigraphy

We correlate Upper Pleistocene glacial and fluvial deposits of the Cinca and Gállego River valleys (south central Pyrenees and Ebro basin, Spain) using geomorphic position, luminescence dates, and time-related trends in soil development. The ages obtained from glacial deposits indicate glacial periods at 85 ± 5 ka, 64 ± 11 ka, and 36 ± 3 ka (from glacial till) and 20 ± 3 ka (from loess). The fluvial drainage system, fed by glaciers in the headwaters, developed extensive terrace systems in the Cinca River valley at 178 ± 21 ka, 97 ± 16 ka, 61 ± 4 ka, 47 ± 4 ka, and 11 ± 1 ka, and in the Gállego River valley at 151 ± 11 ka, 68 ± 7 ka, and 45 ± 3 ka. The times of maximum geomorphic activity related to cold phases coincide with Late Pleistocene marine isotope stages and Heinrich events. The maximum extent of glaciers during the last glacial occurred at 64 ± 11 ka, and the terraces correlated with this glacial phase are the most extensive in both the Cinca (61 ± 4 ka) and Gállego (68 ± 7 ka) valleys, indicating a strong increase in fluvial discharge and availability of sediments related to the transition to deglaciation. The global Last Glacial Maximum is scarcely represented in the south central Pyrenees owing to dominantly dry conditions at that time. Precipitation must be controlled by the position of the Iberian Peninsula with respect to the North Atlantic atmospheric circulation system. The glacial systems and the associated fluvial dynamic seem sensitive to 1) global climate changes controlled by insolation, 2) North Atlantic thermohaline circulation influenced by freshwater pulses into the North Atlantic, and 3) anomalies in atmospheric circulation in the North Atlantic controlling precipitation on the Iberian Peninsula. Our scenario of glacial and fluvial evolution during the Late Pleistocene in northern Spain could be extrapolated to other glaciated mountainous areas in southern Europe.     

Pfiesteria shumwayae (Pfiesteriaceae) in New Zealand

Pfiesteria shumwayae Steidinger et Burkholder is now known to be present in New Zealand and occurs in estuaries around the country. The presence of Pfiesteria was initially determined by a polymerase chain reaction (PCR)‐based detection assay, using oligonucleotide primers targeted at ribosomal DNA extracted from estuarine water and sediments. Presence was confirmed by isolation from fresh sediments in the presence offish (Oreochromis mossambicus), followed by identification by scanning electron microscopy. The New Zealand isolates of P. shumwayae were ichthyotoxic in bioassays, but there is no historic evidence offish kills in New Zealand associated with the dinoflagellate.