No major thermal event on the mid-Cretaceous Côte d'Ivoire–Ghana Transform Margin

Transient mid-Cretaceous thermal uplift induced by lateral heating from passing oceanic lithosphere is often invoked as a mechanism for the formation of the Côte d'Ivoire–Ghana basement ridge in the Equatorial Atlantic. This heating event should have affected mid-Cretaceous sedimentary rocks along the ridge. However, organic maturity and clay mineral data on the thermal evolution of these rocks suggest that burial temperatures did not exceed 80 °C and that palaeo–geothermal gradients are not anomalous. Optical petrography and the stratigraphic pattern of temperature-sensitive parameters indicate that higher palaeotemperature estimates are related to admixtures of preheated, detrital organic and inorganic matter. Erosion brought the sediments to their present shallow burial depths. Lack of evidence for significant thermal alteration implies that either thermal exchange between oceanic and continental lithosphere along the Côte d'Ivoire–Ghana Transform Margin was negligible, or that lateral heating by oceanic lithosphere was not strong enough to affect the sedimentary cover of the basement ridge.     

An experimental study of the solubility and speciation of the Rare Earth Elements (III) in fluoride- and chloride-bearing aqueous solutions at temperatures up to 300 °C

The solubility of REE(III) fluoride solids was determined in fluoride- and chloride-bearing solutions at 150, 200 and 250 °C and saturated water vapor pressure. These experimental data, together with experimental data from previously published studies, were used to evaluate formation constants for chloride- and fluoride-bearing aqueous species of the entire REE(III) group at temperatures up to 300 °C. The data show that the stability of these species differs significantly from that predicted theoretically. For example, contrary to the theoretical predictions, LREEF²⁺ species are more stable than HREEF²⁺ species at elevated temperature. The behavior of the chloride-bearing species is similar. Parameters for the Helgeson–Kirkham–Flowers (HKF) equation of state were determined for REEF²⁺, REECl²⁺ and REECl₂⁺ complexes using these experimental data and permit calculation of formation constants of these species at conditions not investigated experimentally. These data now permit the mobility of all REE in fluoride- and chloride-bearing hydrothermal systems to be reliably evaluated at intermediate temperatures and pressures.     

Development of preferred orientation in plane strain deformed limestone: Experiment and theory

Carbonate rocks deform preferentially by twin gliding on e={01ˉ18} and slip on r ={10ˉ14} and f={02ˉ21}. In polycrystalline aggregates strong textures develop. We report on experimentally produced textures in triaxial plane strain geometry with orthorhombic symmetry at 200° C and 400° C. Pole figure of the experimentally deformed specimens are compared quantitatively with theoretical simulations based on the Taylor theory using both slip and mechanical twinning as mechanisms. Agreement at low and high temperature is satisfactory and documents that models developed for f.c.c. metals can be applied to low symmetry minerals provided that deformation mechanisms are known and that mechanical twinning is properly accounted for. Comparison with experimental results indicates that strain was nearly homogeneous at the conditions considered and the same may apply to many geological textures. Three texture types are described which are differentiated mainly by the relative importance of e twinning.     

Absorption of nuclear γ-rays on the starlight radiation in FR I sources: the case of Centaurus A

Several BL Lac objects are confirmed sources of variable and strongly Doppler-boosted TeV emission produced in the nuclear portions of their relativistic jets. It is more than probable that also many of the Fanaroff–Riley type I (FR I) radio galaxies, believed to be the parent population of BL Lacs, are TeV sources, for which Doppler-hidden nuclear γ-ray radiation may be only too weak to be directly observed. Here we show, however, that about 1 per cent of the total time-averaged TeV radiation produced by the active nuclei of low-power FR I radio sources is inevitably absorbed and re-processed by photon–photon annihilation on the starlight photon field, and the following emission of the created and quickly isotropized electron–positron pairs. In the case of the radio galaxy Centaurus A, we found that the discussed mechanism can give a distinctive observable feature in the form of an isotropic γ-ray halo. It results from the electron–positron pairs injected to the interstellar medium of the inner parts of the elliptical host by the absorption process, and upscattering starlight radiation via the inverse-Compton process mainly to the GeV–TeV photon energy range. Such a galactic γ-ray halo is expected to possess a characteristic spectrum peaking at ∼0.1 TeV photon energies, and the photon flux strong enough to be detected by modern Cherenkov Telescopes and, in the future, by GLAST. These findings should apply as well to the other nearby FR I sources.