The composition and crystallinity of the near-surface regions of weathered alkali feldspars

Our ability to identify thin non-stoichiometric and amorphous layers beneath mineral surfaces has been tested by undertaking X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) work on alkali feldspars from pH 1 dissolution experiments. The outcomes of this work were used to help interpret XPS and TEM results from alkali feldspars weathered for <10,000 years in soils overlying the Shap Granite (north-west England). The chemistry of effluent solutions indicates that silica-rich layers a few nanometers in thickness formed during the pH 1 experiments. These layers can be successfully identified by XPS and have lower Al/Si, Na/Si, K/Si and Ca/Si values than the outermost ∼9 nm of unweathered controls. Development of Al-Si non-stoichiometry is coupled with loss of crystal structure to produce amorphous layers that are identifiable by TEM where >∼2.5 nm thick, whereas the crystallinity of albite is retained despite leaching of Na to depths of tens to hundreds on nanometers. Integration of XPS data over the outermost 6-9 nm of naturally weathered Shap feldspars shows that they have stoichiometric Al/Si and K/Si ratios, which is consistent with findings of previous TEM work on the same material that they lack amorphous layers. There is some XPS evidence for loss of K from the outermost couple of nanometers of Shap orthoclase, and the possibility of leaching of Na from albite to greater depths cannot be excluded using the XPS or TEM results. This study demonstrates that the leached layer model, as formulated from laboratory experiments, is inapplicable to the weathering of alkali feldspars within acidic soils, which is an essentially stoichiometric reaction.     

Abundance versus rates of accumulation in fine-grained strata of the Miocene Santa Barbara Basin,California

Although best known as a deposit rich in silica and organic matter, the Miocene Monterey Formation actually had long-term rates of silica and organic Matter accumulation equal to or lower than values in the underlying and overlying detritus-rich formations in the Santa Barbara coastal area. The factor Mainly influencing the composition of the Monterey Formation in this area was the slow accumulation of terrigenous debris. In contrast, with greater than average silica abundance within the Monterey Formation probably resulted from rapid short-term silica accumulation (of hundreds to tens of thousands years duration) rather than from especially slow accumulation of diluting debris.     

Permeability development in vesiculating magmas: implications for fragmentation

 Fragmentation, or the "coming apart" of magma during a plinian eruption, remains one of the least understood processes in volcanology, although assumptions about the timing and mechanisms of fragmentation are key parameters in all existing eruption models. Despite evidence to the contrary, most models assume that fragmentation occurs at a critical vesicularity (volume percent vesicles) of 75–83%. We propose instead that the degree to which magma is fragmented is determined by factors controlling bubble coalescence: magma viscosity, temperature, bubble size distribution, bubble shapes, and time. Bubble coalescence in vesiculating magmas creates permeability which serves to connect the dispersed gas phase. When sufficiently developed, permeability allows subsequent exsolved and expanded gas to escape, thus preserving a sufficiently interconnected region of vesicular magma as a pumice clast, rather than fully fragmenting it to ash. For this reason pumice is likely to preserve information about (a) how permeability develops and (b) the critical permeability needed to insure clast preservation. We present measurements and calculations that constrain the conditions (vesicularity, bubble size distribution, time, pressure difference, viscosity) necessary for adequate permeability to develop. We suggest that magma fragments explosively to ash when and where, in a heterogeneously vesiculating magma, these conditions are not met. Both the development of permeability by bubble wall thinning and rupture and the loss of gas through a permeable network of bubbles require time, consistent with the observation that degree of fragmentation (i.e., amount of ash) increases with increasing eruption rate. Received: 5 July 1995 / Accepted: 27 December 1995     

A Long Way to Go: Collective Paths to Racial Justice in Geography

Despite decades of recognition and worry about diversity, our discipline remains persistently white. That is, it is dominated by white bodies and it continues to conform to norms, practices, and ideologies of whiteness. This is a loss. At best, it limits the possibilities and impact of our work as geographers. At worst, it perpetuates harmful exclusions in our discipline: its working environments, its institutions, and its knowledge production. This remains deeply concerning for many geographers, and there has been important research, commentary, and institutional activity over the years. Yet, research shows us that little meaningful progress has been made. We know that mentoring is one vital part of the journey toward change. As such, we reflect here on our experience developing a research collective built on a transformative mentoring practice. We outline the key challenges, strategies, and tentative successes of the collective in supporting women of color undergraduate, graduate, and faculty geographers, arguing that such feminist formations are a vital part of the path to intellectual racial justice in our field. Key Words: diversity, feminist geography, higher education, mentoring, race.     

Can marine fisheries and aquaculture meet fish demand from a growing human population in a changing climate?

Expansion in the world's human population and economic development will increase future demand for fish products. As global fisheries yield is constrained by ecosystems productivity and management effectiveness, per capita fish consumption can only be maintained or increased if aquaculture makes an increasing contribution to the volume and stability of global fish supplies. Here, we use predictions of changes in global and regional climate (according to IPCC emissions scenario A1B), marine ecosystem and fisheries production estimates from high resolution regional models, human population size estimates from United Nations prospects, fishmeal and oil price estimations, and projections of the technological development in aquaculture feed technology, to investigate the feasibility of sustaining current and increased per capita fish consumption rates in 2050. We conclude that meeting current and larger consumption rates is feasible, despite a growing population and the impacts of climate change on potential fisheries production, but only if fish resources are managed sustainably and the animal feeds industry reduces its reliance on wild fish. Ineffective fisheries management and rising fishmeal prices driven by greater demand could, however, compromise future aquaculture production and the availability of fish products.     

Europe adapts to climate change: Comparing National Adaptation Strategies

For the last two decades, European climate policy has focused almost exclusively on mitigation of climate change. It was only well after the turn of the century, with impacts of climate change increasingly being observed, that adaptation was added to the policy agenda and EU Member States started to develop National Adaptation Strategies (NASs). This paper reviews seven National Adaptation Strategies that were either formally adopted or under development by Member States at the end of 2008. The strategies are analysed under the following six themes. Firstly, the factors motivating and facilitating the development of a national adaptation strategy. Secondly, the scientific and technical support needed for the development and implementation of such a strategy. Thirdly, the role of the strategy in information, communication and awareness-raising of the adaptation issue. Fourthly, new or existing forms of multi-level governance to implement the proposed actions. Fifthly, how the strategy addresses integration and coordination with other policy domains. Finally, how the strategy suggests the implementation and how the strategy is evaluated. The paper notes that the role of National Adaptation Strategies in the wider governance of adaptation differs between countries but clearly benchmarks a new political commitment to adaptation at national policy levels. However, we also find that in most cases approaches for implementing and evaluating the strategies are yet to be defined. The paper concludes that even though the strategies show great resemblance in terms of topics, methods and approaches, there are many institutional challenges, including multi-level governance and policy integration issues, which can act as considerable barriers in future policy implementation.     

Modèles géostatistiques de concentrations ou de débits le long des cours d'eau

Estimating concentrations or flow rates along a stream network requires specific models. Two classes of models, recently proposed in the literature, are generalized, to the intrinsic case in particular. We present a global construction by ‘streams’, i.e. on the whole set of paths between sources and outlet. Combining stationary or intrinsic one-dimensional random functions leads to stationary or intrinsic models on segments, with discontinuities at the forks. A construction from outlet to sources, leads to stationary or intrinsic models on each stream, without any discontinuity at the forks. The linear variogram is found as a particular case. The extension to the linear model of coregionalization is immediate, allowing a multivariate modelling of concentrations. To cite this article: C. de Fouquet, C. Bernard-Michel, C. R. Geoscience 338 (2006).     

An evaluation of temperature scales for silica diagenesis in diatomaceous sequences including a new approach based on the Miocene Monterey Formation,California

Geologic relations indicate that silica phases transformed in the Monterey Formation in two zones that persist over a narrow depth/temperature range and do not stratigraphically overlap. The wide and overlapping range of reported temperatures of these transformations is mainly a result of the many uncertainties inherent in the different methods used to estimate temperature and does not indicate that phases transform throughout these ranges. Our approach to a reliable temperature scale for silica diagenesis combines as empirical zonation of silica phases with temperature calibration from a sequence at maximum temperature and depth of burial.