The pathway of mercury in contaminated waters determined by association with organic carbon (Tagus Estuary,Portugal)

Reactive dissolved Hg (Hg_R), non-reactive dissolved Hg (Hg_NR), particulate Hg (Hg_P), dissolved organic C (DOC), particulate organic C (POC), salinity and other interpretative parameters were determined in water samples collected in the North Channel and in adjacent areas of the Tagus estuary (Portugal). Higher concentrations of both dissolved and particulate Hg in the North Channel indicate a pollution source and raise the possibility of Hg escaping to adjacent areas by tidal action. This transport was confirmed by the increase of Hg_R with salinity and Hg_NR with DOC, along a longitudinal axis paralleling the North Channel. Apparently, Hg leaving this channel is progressively complexed by inorganic and organic ligands. Near the mouth of the estuary, values decreased reflecting dilution with seawater. Moreover the Hg_P:POC ratio also increased seaward, suggesting mixing with Hg enriched particles that escaped the North Channel, or incorporation of dissolved Hg species in river-derived particles. These results suggest that the pathway of anthropogenic Hg in contaminated waters may be identified by their enrichment in organic matter, both in the dissolved and particulate fraction.     

Holocene climate variability in Sicily from a discontinuous stalagmite record and the Mesolithic to Neolithic transition

Fabric and stable isotopic composition of a Holocene stalagmite (CR1) from a cave in northern Sicily record changes in paleorainfall in the early Holocene. High δ¹³C stable isotope values in the calcite deposited from ca. 8500 to ca. 7500 yr ago are interpreted as reflecting periods of high rainfall. The wet phase was interrupted by two periods of multi-century duration characterized by relatively cool and dry winters centered at ca. 8200 and ca. 7500 yr ago, highlighted by low δ¹³C and δ¹⁸O values. A high variability of δ¹³C values is recorded from ca. 7500 to ca. 6500 yr ago and indicates that the transition from a pluvial early Holocene to the present-day climate conditions was punctuated by decadal-scale periods of relatively dry winters. In northern Sicily, the traditional elements of the Neolithic appear at ca. 7700 yr ago. It is possible that changes in rainfall influenced the passage from hunter-gathering to farming and sheep-herding economies.     

Alpujarride attribution of the supposed ‘Almagride Complex’ (Betic Internal Zone,Almerı́a Province,Spain)Appartenance Alpujarride du prétendu « Complexe almagride » (Zones internes bétiques,province d'Almeria,Espagne)

The differentiation of units in the Sierra de Almagro has been a source of controversy. There were defined the Almagride and Ballabona–Cucharón complexes, the former considered by several authors as part of a Subbetic metamorphosed and outcropping in a tectonic window. In this study, the units of Ballabona, Almagro and Cucharón are integrated into a single one, that of Tres Pacos, because they correspond to different parts of the same stratigraphic series. This unit is tectonically over the Nevado–Filabride Complex. The existence of the Almagride and Ballabona–Cucharón complexes is discarded and their units form part of the Alpujarride Complex. To cite this article: C. Sanz de Galdeano, F.J. Garc??a Tortosa, C. R. Geoscience 334 (2002) 355–362.     

An Early-Cambrian UPb apatite cooling age for the high-temperature regional metamorphism in the Piancó area,Borborema Province (NE Brazil): initial conclusions

The Borborema Province (BP) of northeastern Brazil is a complex crustal assemblage, which has undergone a polycyclic evolution during the Proterozoic. In the Piancó-Alto Br??gida belt, a metamorphosed leucosome vein inserted in amphibolites has a trace element pattern suggesting a T-MORB protolith. Apatites yield a REE pattern indicating growth in equilibrium with garnet, thus pointing to its metamorphic origin. UPb analyses yield an age of 540±5 Ma interpreted as a cooling age following amphibolite facies regional metamorphism associated with granitic emplacement at ca. 580 Ma. The resulting slow cooling rates (ranging from ca. 2.5 to 5 °C Ma^?1) are consistent with underplating of mafic magmas, or crustal thickening caused by nappe stacking, as possible processes governing the metamorphic evolution of the BP. To cite this article: B. Dhuime et al., C. R. Geoscience 335 (2003).     

The local structure of Ca-Na pyroxenes. I. XANES study at the Na K-edge

 X-ray absorption Na K-edge spectra have been recorded on synthetic endmember jadeite and on a series of natural Ca-Na pyroxenes compositionally straddling the Jd-Di join. The C2/c members of the series are systematically different from the P2/n members. Differences can be interpreted and explained by comparing the experimental spectra with theoretical spectra. These have been calculated by the multiple-scattering formalism from the atomic positional parameters determined by single-crystal X-ray diffraction structure refinement on the same samples. In the full multiple scattering region of the spectra (1075 to 1090 eV) C-pyroxenes exhibit three features which reflect the 6-2 configuration of the O back-scattering atoms around the Na absorber located at the center of the cluster (site M2 of the jadeite structure). P-pyroxenes show more complicated spectra in which at least four (possibly five) features can be recognized; they reflect the two types of configuration (6-2 and 4-2-2) of O around Na in the two independent M2 and M21 eight-fold coordinated sites of the omphacite structure. A weak, sometimes poorly resolved peak at 1079 eV is diagnostic and discriminates C- from P-pyroxenes. The Garnet Ridge C2/c impure jadeite exhibits a spectrum which is intermediate between those of jadeite and omphacite. The Hedin-Lundqvist potential proves best for these insulating materials and allows multiple-scattering calculations agreeing well with experiments. Received: July 11, 1996/Revised, accepted: October 21, 1996     

Vegetation dynamics during the late Pleistocene in the Barreirinhas region, Maranhão State, northeastern Brazil, based on carbon isotopes in soil organic matter

The study place is in the Barreirinhas region, Maranhão State, northeastern Brazil. A vegetation transect of 78 km was studied among four vegetation types: Restinga (coastal vegetation), Cerrado (woody savanna), Cerradão (dense woody savanna), and Forest, as well as three forested sites around Lagoa do Caçó, located approximately 10 km of the transect. Soil profiles in this transect were sampled for δ¹³C analysis, as well as buried charcoal fragments were used for ¹⁴C dating. The data interpretation indicated that approximately between 15,000 and ∼9000 ¹⁴C yr B.P., arboreal vegetation prevailed in the whole transect, probably due to the presence of a humid climate. Approximately between ∼9000 and 4000-3000 ¹⁴C yr B.P., there was the expansion of the savanna, probably related to the presence of drier climate. From ∼4000-3000 ¹⁴C yr B.P. to the present, the results indicated an increase in the arboreal density in the area, due to the return to a more humid and probably similar climate to the present. The presence of buried charcoal fragments in several soil depths suggested the occurrence of palaeofires during the Holocene. The vegetation dynamic inferred in this study for northeastern Brazil is in agreement with the results obtained in areas of Amazon region, based on pollen analysis of lake sediments and carbon isotope analysis of soil organic matter (SOM), implying than similar climatic conditions have affected these areas during the late Pleistocene until the present.     

Crustal and mantle strengths in continental lithosphere: is the jelly sandwich model obsolete?

The relative importance of the contribution of the lower crust and of the lithospheric mantle to the total strength of the continental lithosphere is assessed systematically for realistic ranges of layer thickness, composition, and temperature. Results are presented as relative strength maps, giving the ratio of the lower crust to upper mantle contribution in terms of crustal thickness and surface heat flow. The lithosphere shows a “jelly sandwich” rheological layering for low surface heat flow, thin to average crustal thickness, and felsic or wet mafic lower crustal compositions. On the other hand, most of the total strength resides in the seismogenic crust in regions of high surface heat flow, crust of any thickness, and dry mafic lower crustal composition.     

The holstein interglaciation: Time-stratigraphic position and correlation to stable-isotope stratigraphy of deep-sea sediments

Marine molluscan shells from para-type and other loclities of the Holsteinian interglaciation were dated by Th/U and the electron spin resonance (ESR) method to more than 350,000 and 370,000 yr B.P., beyond the limit of Th/U dating. The high age estimate is corroborated by a K/Ar age of 420,000 yr B.P. determined from volcanic ash near the base of the Ariendorf paleosol in the Middle Rhine valley believed to be a pedostratigraphic equivalent of the Holsteinian. Shells from the Herzeele marine unit III, an equivalent of the Wacken (Dömnitz) warm stage in northern France and subsequent to the Holsteinian, revealed ages between 300,000 and 350,000 yr B.P. A correlation of these two warm stages with marine oxygen-isotope stages 11 and 9 on the SPECMAP and CARTUNE time scales is suggested. From the benthic oxygen-isotope record one may infer that no exceptionally high global sea-level rise corresponds to the large transgressions of the Holstein Sea in northern Germany. Therefore, a significant proportion of the transgression was probably the result of an unusually large local glacial-isostatic depression caused by the extreme buildup of ice during the preceding Elster glaciation (stage 12). According to the deep-sea record, it lasted approximately 50% longer than the subsequent cold stage 10. The outstanding soil formation with Braunlehm and the well-developed thermal optimum of the Holsteinian are tentatively related to a phase of minimum sea-ice cover in the Norwegian-Greenland Sea, as deduced from long benthic carbon-isotope records from the central Atlantic.     

Comparison of statistically downscaled precipitation in terms of future climate indices and daily variability for southern Ontario and Quebec,Canada

Given the coarse resolution of global climate models, downscaling techniques are often needed to generate finer scale projections of variables affected by local-scale processes such as precipitation. However, classical statistical downscaling experiments for future climate rely on the time-invariance assumption as one cannot know the true change in the variable of interest, nor validate the models with data not yet observed. Our experimental setup involves using the Canadian regional climate model (CRCM) outputs as pseudo-observations to estimate model performance in the context of future climate projections by replacing historical and future observations with model simulations from the CRCM, nested within the domain of the Canadian global climate model (CGCM). In particular, we evaluated statistically downscaled daily precipitation time series in terms of the Peirce skill score, mean absolute errors, and climate indices. Specifically, we used a variety of linear and nonlinear methods such as artificial neural networks (ANN), decision trees and ensembles, multiple linear regression, and k-nearest neighbors to generate present and future daily precipitation occurrences and amounts. We obtained the predictors from the CGCM 3.1 20C3M (1971–2000) and A2 (2041–2070) simulations, and precipitation outputs from the CRCM 4.2 (forced with the CGCM 3.1 boundary conditions) as predictands. Overall, ANN models and tree ensembles outscored the linear models and simple nonlinear models in terms of precipitation occurrences, without performance deteriorating in future climate. In contrast, for the precipitation amounts and related climate indices, the performance of downscaling models deteriorated in future climate.