Oil-weathering behavior in Arctic environments

Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup.     

Experimental Melting of Cordierite Gneiss and the Petrogenesis of Syntranscurrent Peraluminous Granites in Southern Brazil

To understand the petrogenesis of peraluminous granites syntectonicto the Dorsal de Canguçu Transcurrent Shear Zone in theSul-rio-grandense Shield, Brazil, melting experiments were performedon one of the potential protoliths, a cordierite-bearing semi-peliticmetasedimentary gneiss (PE-1). Experiments were conducted atpressures of 5, 10 and 15 kbar, at temperatures of 700–900°C,and under fluid-absent and 5% H₂O-present conditions. The experimentsshow that fluid-absent melting begins at near-solidus conditions,around 700°C, promoted by participation of retrogressivephengitic muscovite in the reaction Mus + Kf ± Qz = melt± Fe–Ti oxide ± Als, producing a very smallamount of melt (<9%) with widely ranging composition. Allhypersolidus experiments (>800°C) produced S-type graniticmelts promoted by participation of biotite or cordierite inthe reactions Bio + Pl + Crd + Qz = Px + Fe–Ti oxide +melt at 5 kbar, and Bio + Pl + Crd ± Qz = Grt + Als ±Kf + melt at 10 and 15 kbar, both producing a high amount ofmelt (10–63% by volume). The melt compositions obtainedat 900°C and 15 kbar under fluid-absent conditions, promotedby biotite or cordierite breakdown, are similar to the syntectonicgranites. However, it is unlikely that the granites were formedat this pressure (corresponding to a depth of melting of     

Gravity variations along the Southeast Bohol Ophiolite Complex (SEBOC), Central Philippines: Implications on Ophiolite Emplacement

Abstract The basement complex of Bohol Island consists of the Southeast Bohol Ophiolite Complex (SEBOC), Cansiwang Melange and Alicia Schist. The SEBOC is a complete, but dismembered ophiolite with outcrops generally trending northeast– southwest and dipping north-west. The harzburgite units of the SEBOC are almost always observed to be thrusted onto the Cansiwang Melange, which in turn is thrusted onto the Alicia Schist. Bouguer gravity values on Bohol range from about +60 mGal in the west to +120 mGal in the east, in the region to the north-east of the SEBOC outcrops. Based on the present distribution of the SEBOC units and their thrust fault relationship with the Cansiwang Melange and Alicia Schist, it is proposed that the SEBOC was emplaced by onramping towards the south-eastward direction. However, the orientation of the Bouguer highs suggests that the thrusting direction of the ophiolite units is towards the south-west and not towards the south-east.     

An overview of toxicant identification in sediments and dredged materials

The identification of toxicants affecting aquatic benthic systems is critical to sound assessment and management of our nation's waterways. Identification of toxicants can be useful in designing effective sediment remediation plans and reasonable options for sediment disposal. Knowledge of which contaminants affect benthic systems allows managers to link pollution to specific dischargers and prevent further release of toxicant(s). In addition, identification of major causes of toxicity in sediments may guide programs such as those developing environmental sediment guidelines and registering pesticides, while knowledge of the causes of toxicity which drive ecological changes such as shifts in benthic community structure would be useful in performing ecological risk assessments. To this end, the US Environmental Protection Agency has developed tools (toxicity identification and evaluation (TIE) methods) that allow investigators to characterize and identify chemicals causing acute toxicity in sediments and dredged materials. To date, most sediment TIEs have been performed on interstitial waters. Preliminary evidence from the use of interstitial water TIEs reveals certain patterns in causes of sediment toxicity. First, among all sediments tested, there is no one predominant cause of toxicity; metals, organics, and ammonia play approximately equal roles in causing toxicity. Second, within a single sediment there are multiple causes of toxicity detected; not just one chemical class is active. Third, the role of ammonia is very prominent in these interstitial waters. Finally, if sediments are divided into marine or freshwater, TIEs perforMed on interstitial waters from freshwater sediments indicate a variety of toxicants in fairly equal proportions, while TIEs performed on interstitial waters from marine sediments have identified only ammonia and organics as toxicants, with metals playing a minor role. Preliminary evidence from whole sediment TIEs indicates that organic compounds play a major role in the toxicity of marine sediments, with almost no evidence for either metal or ammonia toxicity. However, interpretation of these results may be skewed because only a small number of interstitial water (n = 13) and whole sediment (n = 5) TIEs have been completed. These trends may change as more data are collected.     

Geochemistry of meteoric calcite cements in some Pleistocene limestones

In this study, the stable isotope and trace element geochemistries of meteoric cements in Pleistocene limestones from Enewetak Atoll (western Pacific Ocean), Cat Island (Bahamas), and Yucatan were characterized to help interpret similar cements in ancient rocks. Meteoric calcite cements have a narrow range of δ¹⁸O values and a broad range of δ¹³C values in each geographical province. These Pleistocene cements were precipitated from water with stable oxygen isotopic compositions similar to modern rainwater in each location. Enewetak calcite cements have a mean δ¹⁸O composition of ?6.5%₀ (PDB) and δ¹³C values ranging from ?9.6 to +0.4%0 (PDB). Sparry calcite cements from Cat Island have a mean δ¹⁸O composition of ?4.1%₀ and δ¹³C values ranging from ?6.3 to + 1.1%₀. Sparry cements from Yucatan have a mean δ¹⁸O composition of ?5.7%₀ and δ¹³C values of ?8.0 to ?2.7%₀. The mean δ¹⁸O values of these Pleistocene meteoric calcite cements vary by 2.4%₀ due to climatic variations not related directly to latitude. The δ¹³C compositions of meteoric cements are distinctly lower than those of the depositional sediments. Variations in δ¹³C are not simply a function of distance below an exposure surface. Meteoric phreatic cements often have δ¹³C compositions of less than —4.0%₀, which suggests that soil-derived CO₂ and organic material were washed into the water table penecontemporaneous with precipitation of phreatic cements. Concentrations of strontium and magnesium are quite variable within and between the three geographical provinces. Mean strontium concentrations for sparry calcite cements are, for Enewetak Atoll, 620 ppm (σ= 510 ppm); for Cat Island, 1200 ppm (σ= 980 ppm); and for Yucatan, 700 ppm (σ= 390 ppm). Equant cements, intraskeletal cements, and Bahamian cements have higher mean strontium concentrations than other cements. Equant and intraskeletal cements probably precipitated in more closed or stagnant aqueous environments. Bahamian depositional sediments had higher strontium concentrations which probably caused high strontium concentrations in their cements. Magnesium concentrations in Pleistocene meteoric cements are similar in samples from Enewetak Atoll (mean =1.00 mol% MgCO₃; σ= 0.60 mol% MgCO₃) and Cat Island (mean = 0.84 mol% MgCO₃; σ= 0.52mol% MgCO₃) but Yucatan samples have higher magnesium concentrations (mean = 2.20 mol% MgCO₃: σ= 0.84mol% MgCO₃). Higher magnesium concentrations in some Yucatan cements probably reflect precipitation in environments where sea water mixed with fresh water.     

Effects of winter atmospheric circulation on temporal and spatial variability in annual streamflow in the western United States

Abstract

Winter mean 700-hectoPascal (hPa) height anomalies, representing the average atmospheric circulation during the snow season, are compared with annual streamflow measured at 140 streamgauges in the western United States. Correlation and anomaly pattern analyses are used to identify relationships between winter mean atmospheric circulation and temporal and spatial variability in annual streamflow. Results indicate that variability in winter mean 700-Hpa height anomalies accounts for a statistically significant portion of the temporal variability in annual streamflow in the western United States. In general, above-average annual streamflow is associated with negative winter mean 700-Hpa height anomalies over the eastern North Pacific Ocean and/or the western United States. The anomalies produce an anomalous flow of moist air from the eastern North Pacific Ocean into the western United States that increases winter precipitation and snowpack accumulations, and subsequently streamflow. Winter mean 700-hPa height anomalies also account for statistically significant differences in spatial distributions of annual streamflow. As part of this study, winter mean atmospheric circulation patterns for the 40 years analysed were classified into five winter mean 700-hPa height anomaly patterns. These patterns are related to statistically significant and physically meaningful differences in spatial distributions of annual streamflow.     

Lake Hoare, Antarctica: sedimentation through a thick perennial ice cover

Lake Hoare in the Dry Valleys of Antarctica is covered with a perennial ice cover more than 3 m thick, yet there is a complex record of sedimentation and of growth of microbial mats on the lake bottom. Rough topography on the ice covering the lake surface traps sand that is transported by the wind. In late summer, vertical conduits form by melting and fracturing, making the ice permeable to both liquid water and gases. Cross-sections of the ice cover show that sand is able to penetrate into and apparently through it by descending through these conduits. This is the primary sedimentation mechanism in the lake. Sediment traps retrieved from the lake bottom indicate that rates of deposition can vary by large amounts over lateral scales as small as 1 m. This conclusion is supported by cores taken in a 3 × 3 grid with a spacing of 1.5 m. Despite the close spacing of the cores, the poor stratigraphic correlation that is observed indicates substantial lateral variability in sedimentation rate. Apparently, sand descends into the lake from discrete, highly localized sources in the ice that may in some cases deposit a large amount of sand into the lake in a very short time. In some locations on the lake bottom, distinctive sand mounds have been formed by this process. They are primary sedimentary structures and appear unique to the perennially ice-covered lacustrine environment. In some locations they are tens of centimetres high and gently rounded with stable slopes; in others they reach ～ 1 m in height and have a conical shape with slopes at angle of repose. A simple formation model suggests that these differences can be explained by local variations in water depth and sedimentation rate. Rapid colonization and stabilization of fresh sand surfaces by microbial mats composed of cyanobacteria, eukaryotic algae, and heterotrophic bacteria produces a complex intercalation of organic and sandy layers that are a distinctive form of modern stromatolites.     

Quantitative Simulation of the Hydrothermal Systems of Crystallizing Magmas on the Basis of Transport Theory and Oxygen Isotope Data: An analysis of the Skaergaard Intrusion

Application of the principles of transport theory to studiesof magma-hydrothermal systems permits quantitative predictionsto be made of the consequences of magma intruding into permeablerocks. Transport processes which redistribute energy, mass,and momentum in these environments can be represented by a setof partial differential equations involving the rate of changeof extensive properties in the system. Numerical approximationand computer evaluation of the transport equations effectivelysimulates the crystallization of magma, cooling of the igneousrocks, advection of chemical components, and chemical and isotopicmass transfer between minerals and aqueous solution. Numerical modeling of the deep portions of the Skaergaard magma-hydrothermalsystem has produced detailed maps of the temperature, pressure,fluid velocity, integrated fluid flux, ¹⁸O-values in rock andfluid, and extent of nonequilibrium exchange reactions betweenfluid and rock as a function of time for a two-dimensional cross-sectionthrough the pluton. An excellent match was made between calculated¹⁸O-values and the measured ¹⁸O-values in the three principalrock units, basalt, gabbro, and gneiss, as well as in xenolithsof roof rocks that are now embedded in Layered Series; the latterwere evidently depleted in ¹⁸O early in the system's coolinghistory, prior to falling to the bottom of the magma chamber.The best match was realized for a system in which the bulk rockpermeabilities were 10^–13 cm² for the intrusion, 10^–11cm² for basalt, and 10^–16 cm² for gneiss; reaction domainsizes were 0.2 cm in the intrusion and gneiss and 0.01 cm inthe basalts, and activation energy for the isotope exchangereaction between fluid and plagioclase was 30 kcal/mole. The calculated thermal history of the Skaergaard system wascharacterized by extensive fluid circulation that was largelyrestricted to the permeable basalts and to regions of the plutonstratigraphically above the basalt-gneiss unconformity. Althoughfluids circulated all around the crystallizing magma, fluidflow paths were deflected around the magma sheet during theinitial 130,000 years. At that time, crystallization of thefinal sheet of magma and fracture of the rock shifted the circulationsystem toward the center of the intrusion, thereby minimizingthe extent of isotope exchange between rocks near the marginof the intrusion at this level. For comparison, similar calculationswere also made for pure conductive cooling; it was found thatthe rate of crystallization of the magma body was not changed.The solidified pluton cooled by a factor of about 2 faster inthe presence of a hydrothermal system. Transport rates of thermal energy out of the intrusion and oflow-¹⁸O fluids into the intrusion controlled the overall isotopeexchange process. During the initial 150,000 years, temperatureswere high and reaction rates were fast; thus, fluids flowinginto the intrusion quickly equilibrated with plagioclase. However,the temperature decreased between 120,000 and 175,000 yearsand caused a decrease in reaction rates and an increase in theequilibrium fractionation factor between plagioclase and fluid.Consequently, during this time period fluids in the intrusiontended to be out of equilibrium with plagioclase. After 175,000years temperatures had decreased sufficiently that reactionrates became insignificant, but convection rates were largeenough to redistribute fluid and enlarge the regions where fluidand plagioclase were out of equilibrium. By 400,000 years, thepluton had cooled to approximately ambient temperatures, andthe final ¹⁸O values were ‘frozen in’. Reactionsbetween hydrothermal fluid and the intrusion occurred over abroad range in temperature, 1000-200 °C, but 75 per centof the fluid circulated through the intrusion while its averagetemperature was >480 °C. This relatively high temperatureis consistent with the observation that only minor amounts ofhydrothermal alteration products were formed in the naturalsystem, even where several per mil shifts in ¹⁸O were detected. The relative quantities of fluid to rock integrated over theentire cooling history were 0.52 for the upper part of intrusion,0.88 for the basalt, 0.003 for the gneiss, and 0.41 for theentire domain. Almost all of the fluid flowed into the intrusionfrom the basalt host rocks that occur adjacent to the side contactsof the intrusion. Convection transferred about 20 per cent ofthe total heat contained in the gabbro upward into the overlyingbasalts; the remaining 80 per cent of the heat was transferredby conduction.