Lead isotope systematics of Late Cretaceous – Tertiary Andean arc magmas and associated ores between 8°N and 40°S: evidence for latitudinal mantle heterogeneity beneath the Andes

ABSTRACT Lead isotope variability of magmatic arc rocks and associated mineralization of the Central Andes is usually considered to be the result of mixing between a homogeneous mantle and heterogeneous continental crust. About 230 new lead isotope data on the Northern and Central Andes allow us to compare for the first time lead isotope systematics of the Late Cretaceous – Tertiary arc magmatism and associated mineralization along the Andean chain between 8°N and 40°S. Lead isotope compositions indicate mixing between mantle and upper crustal rocks along the whole Andean chain. Additionally, we have found that mantle end-members of the Late Cretaceous – Tertiary magmatism are heterogeneous and systematically shifted towards less radiogenic ²⁰⁶Pb/²⁰⁴Pb compositions from north to south along the Andes. This heterogeneity most likely results from mixing between a low radiogenic mantle, possibly carrying a DMM or EM I component, and a more radiogenic mantle, possibly carrying an HIMU component. Thus, our results imply that lead isotope variability of Andean magmas at the continental scale is caused not only by crustal but also by mantle heterogeneity.     

Mechanisms of riverbank failure along the Arno River,central Italy

Riverbanks along the Arno River have been investigated with the aims of de?ning the main mechanisms of failure and retreat, their spatial distribution, and their causes. Geomorphological aspects were investigated by a reconnaissance of riverbank processes, for a number (26) of representative sites. Laboratory and in situ tests were then performed on a selected number of riverbanks (15). Based on the material characteristics, six main typologies of riverbanks have been de?ned, with homogeneous ?ne‐grained and composite banks representing the most frequent types. Slab‐type failures are the most frequent mechanism observed on ?ne‐grained banks, while cantilever failures prevail on composite banks. The role of river stage and related pore water pressure distributions in triggering the main observed mechanisms of failure has been investigated using two different types of stability analysis. The ?rst was conducted for 15 riverbanks, using the limit equilibrium method and considering simpli?ed hypotheses for pore water pressure distribution (annulment of negative pore pressures in the portion of the bank between low water stage and peak stage). Stability conditions and predicted mechanisms of failure are shown to be in reasonably good agreement with ?eld observations. Three riverbanks, representative of the main alluvial reaches of the river, were then selected for a more detailed bank stability analysis, consisting of: (a) de?nition of characteristic hydrographs of the reach with different return periods; (b) modelling of saturated and unsaturated ?ow using ?nite element seepage analysis; and (c) stability analysis with the limit equilibrium method, by adopting pore water pressure values derived from the seepage analysis. The results are compared to those obtained from the previous simpli?ed analysis, and are used to investigate the different responses, in terms of stability, to different hydrological and riverbank conditions. Copyright © 2003 John Wiley & Sons, Ltd.     

Monitoring and modelling of pore water pressure changes and riverbank stability during flow events

Pore water pressures (positive and negative) were monitored for four years (1996–1999) using a series of tensiometer‐piezometers at increasing depths in a riverbank of the Sieve River, Tuscany (central Italy), with the overall objective of investigating pore pressure changes in response to ?ow events and their effects on bank stability. The saturated/unsaturated ?ow was modelled using a ?nite element seepage analysis, for the main ?ow events occurring during the four‐year monitoring period. Modelling results were validated by comparing measured with computed pore water pressure values for a series of representative events. Riverbank stability analysis was conducted by applying the limit equilibrium method (Morgenstern‐Price), using pore water pressure distributions obtained by the seepage analysis. The simulation of the 14 December 1996 event, during which a bank failure occurred, is reported in detail to illustrate the relations between the water table and river stage during the various phases of the hydrograph and their effects on bank stability. The simulation, according to monitored data, shows that the failure occurred three hours after the peak stage, during the inversion of ?ow (from the bank towards the river). A relatively limited development of positive pore pressures, reducing the effective stress and annulling the shear strength term due to the matric suction, and the sudden loss of the con?ning pressure of the river during the initial drawdown were responsible for triggering the mass failure. Results deriving from the seepage and stability analysis of nine selected ?ow events were then used to investigate the role of the ?ow event characteristics (in terms of peak stages and hydrograph characteristics) and of changes in bank geometry. Besides the peak river stage, which mainly controls the occurrence of conditions of instability, an important role is played by the hydrograph characteristics, in particular by the presence of one or more minor peaks in the river stage preceding the main one. Copyright © 2004 John Wiley & Sons, Ltd.     

Determination of Lithium, Beryllium and Boron at Trace Levels by Laser Ablation-Inductively Coupled Plasma-Sector Field Mass Spectrometry

The analytical capabilities of laser ablation (LA)-ICP-MS in determining Li, Be and B at trace levels in geological samples have been tested on a series of glass reference materials and natural samples. The LA-ICP-MS instrument used consisted of a sector-field ICP-MS coupled with a laser ablation microprobe operating at either 266 or 213 nm wavelength. Reference glasses from NIST (SRM 612, 614 and 616) and MPI-DING (KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, T1-G and ATHO-G) were selected to develop the analytical method and to assess the best instrumental configuration. A series of calcic amphiboles with different Li, Be and B concentrations were also analysed using both LA-ICP-MS and SIMS to test the applicability of the method to natural minerals. Results indicated that with a spot size of 40 μm the agreement between measured and reference values of Li, Be and B is generally better than 10% for NIST SRM 612 and 20% for NIST SRM 614. Average reproducibility at the 2s level was 10% for Li, 20% for Be and 15% for B. Limits of detection were approximately 100 ng g^-1 for Be and B and 200 ng g^-1 for Li. These results were confirmed by analyses carried out on natural amphiboles and compared well in terms of precision and accuracy with those commonly achieved by SIMS.     

Turbulent Transfer Between Street Canyons and the Overlying Atmospheric Boundary Layer

The turbulent exchange of momentum between a two-dimensional cavity and the overlying boundary layer has been studied experimentally, using hot-wire anemometry and particle image velocimetry (PIV). Conditions within the boundary layer were varied by changing the width of the canyons upstream of the test canyon, whilst maintaining the square geometry of the test canyon. The results show that turbulent transfer is due to the coupling between the instabilities generated in the shear layer above the canyons and the turbulent structures in the oncoming boundary layer. As a result, there is no single, unique velocity scale that correctly characterizes all the processes involved in the turbulent exchange of momentum across the boundary layer. Similarly, there is no single velocity scale that can characterize the different properties of the turbulent flow within the canyon, which depends strongly on the way in which turbulence from the outer flow is entrained into the cavity and carried round by the mean flow. The results from this study will be useful in developing simple parametrizations for momentum exchange in the urban canopy, in situations where the street geometry consists principally of relatively long, uniform streets arranged in grid-like patterns; they are unlikely to be applicable to sparse geometries composed of isolated three-dimensional obstacles.     

Bioremediation of petroleum hydrocarbons in anoxic marine sediments: Consequences on the speciation of heavy metals

We investigated the effects of biostimulation and bioagumentation strategies applied to harbor sediments displaying reducing conditions and high concentrations of petroleum hydrocarbons and heavy metals. We compared the microbial efficiency of hydrocarbon removal from sediments maintained for 60 days in anoxic conditions and inoculated with acetate, sulfate-reducing bacterial strains and acetate and sulfate-reducing bacteria. All treatments determined a significant increase in the microbial growth and significant decreases of hydrocarbon contents and of redox potential values. The addition of sulfate-reducing bacterial strains to the sediment was the most efficient treatment for the hydrocarbon removal. In all experiments, significant changes of the heavy metals’ phase repartition were observed. The results reported here suggest that the biodegradation of petroleum hydrocarbons in anoxic marine sediments may be enhanced by stimulating microbial anaerobic metabolism, but care should be applied to monitor the potential changes in the mobility and bioavailability of heavy metals induced by bio-treatments.     

The meteoritic origin of Tutankhamun's iron dagger blade

Scholars have long discussed the introduction and spread of iron metallurgy in different civilizations. The sporadic use of iron has been reported in the Eastern Mediterranean area from the late Neolithic period to the Bronze Age. Despite the rare existence of smelted iron, it is generally assumed that early iron objects were produced from meteoritic iron. Nevertheless, the methods of working the metal, its use, and diffusion are contentious issues compromised by lack of detailed analysis. Since its discovery in 1925, the meteoritic origin of the iron dagger blade from the sarcophagus of the ancient Egyptian King Tutankhamun (14th C. BCE) has been the subject of debate and previous analyses yielded controversial results. We show that the composition of the blade (Fe plus 10.8 wt% Ni and 0.58 wt% Co), accurately determined through portable x‐ray fluorescence spectrometry, strongly supports its meteoritic origin. In agreement with recent results of metallographic analysis of ancient iron artifacts from Gerzeh, our study confirms that ancient Egyptians attributed great value to meteoritic iron for the production of precious objects. Moreover, the high manufacturing quality of Tutankhamun's dagger blade, in comparison with other simple‐shaped meteoritic iron artifacts, suggests a significant mastery of ironworking in Tutankhamun's time.     

The Atacama Large Millimeter/Submillimeter Array: overview & status

The Atacama Large Millimeter/Submillimeter Array (ALMA) is an international millimeter-wavelength radio telescope under construction in the Atacama Desert of northern Chile. ALMA will be situated on a high-altitude site at 5000 m elevation which provides excellent atmospheric transmission over the instrument wavelength range of 0.3 to 3 mm. ALMA will be comprised of two key observing components—a main array of up to sixty-four 12-m diameter antennas arranged in a multiple configurations ranging in size from 0.15 to ∼18 km, and a set of four 12-m and twelve 7-m antennas operating in a compact array ∼50 m in diameter (known as the Atacama Compact Array, or ACA), providing both interferometric and total-power astronomical information. High-sensitivity dual-polarization 8 GHz-bandwidth spectral-line and continuum measurements between all antennas will be available from two flexible digital correlators. At the shortest planned wavelength and largest configuration, the angular resolution of ALMA will be 0.005″. The instrument will use superconducting (SIS) mixers to provide the lowest possible receiver noise contribution, and special-purpose water vapor radiometers to assist in calibration of atmospheric phase distortions. A complex optical fiber network will transmit the digitized astronomical signals from the antennas to the correlators in the Array Operations Site Technical Building, and post-correlation to the lower-altitude Operations Support Facility where the array will be controlled, and initial construction and maintenance of the instrument will occur. ALMA Regional Centers in the US, Europe, Japan and Chile will provide the scientific portals for the use of ALMA; early science observations are expected in 2010, with full operations in 2012.     

Landscape response to tectonic and climatic forcing in the foredeep of the southern Apennines,Italy: insights from Quaternary stratigraphy,quantitative geomorphic analysis,and denudation rate proxies

We present new data about the morphological and stratigraphic evolution and the rates of fluvial denudation of the Tavoliere di Puglia plain, a low‐relief landscape representing the northernmost sector of the Pliocene‐Pleistocene foredeep of the southern Apennines. The study area is located between the easternmost part of the southern Apennine chain and the Gargano promontory and it is characterized by several orders of terraced fluvial deposits, disconformably overlying lower Pleistocene marine clay and organized in a staircase geometry, which recorded the emersion and the long‐term incision history of this sector since mid‐Pleistocene times. We used the spatial and altimetric distribution of several orders of middle to late Pleistocene fluvial terraces in order to perform paleotopographic reconstruction and GIS‐aided eroded volumes estimates. Then, we estimated denudation rates on the basis of the terraces chronostratigraphy, supported by published OSL and AAR dating. Middle to upper Pleistocene denudation rates estimated by means of such an approach are slightly lower than 0.1 mm yr^‐1, in good agreement with short‐term data from direct and indirect evaluation of suspended sediment yield. The analysis of longitudinal river profiles using the stream power erosion model provided additional information on the incision rates of the studied area. Middle to late Quaternary uplift rates (about 0.15 mm yr^‐1), calculated on the basis of the elevation above sea level of marine deposits outcropping in the easternmost sector of the study area, are quite similar to the erosion rates average value, thus suggesting a steady‐state fluvial incision. The approach adopted in this work has demonstrated that erosion rates traditionally obtained by quantitative geomorphic analysis and k_sn estimations can be successfully integrated to quantify rates of tectonic or geomorphological processes of a landscape approaching steady‐state equilibrium. Copyright © 2014 John Wiley & Sons, Ltd.