Trace element mobility during sub-seafloor alteration of basaltic glass from Ocean Drilling Program site 953 (off Gran Canaria)

Trace element concentrations of altered basaltic glass shards (layer silicates) and zeolites in volcaniclastic sediments drilled in the volcanic apron northeast of Gran Canaria during Ocean Drilling Program (ODP) leg 157 document variable element mobilities during low-temperature alteration processes in a marine environment. Clay minerals (saponite, montmorillonite, smectite) replacing volcanic glass particles are enriched in transition metals and rare earth elements (REE). The degree of retention of REE within the alteration products of the basaltic glass is correlated with the field strength of the cations. The high field-strength elements are preferentially retained or enriched in the alteration products by sorption through clay minerals. Most trace elements are enriched in a boundary layer close to the interface mineral-altered glass. This boundary layer has a key function for the physico-chemical conditions of the subsequent alteration process by providing a large reactive surface and by lowering the fluid permeability. The release of most elements is buffered by incorporation into secondary precipitates (sodium-rich zeolites, phillipsite, Fe- and Mn-oxides) as shown by calculated distribution coefficients between altered glasses and authigenic minerals. Chemical fluxes change from an open to a closed system behavior during prograde low-temperature alteration of volcaniclastic sediments with no significant trace metal flux from the sediment to the water column.     

The channel between Gran Canaria and Tenerife: constructive processes and destructive events during the evolution of volcanic islands

Seismic, sidescan sonar, bathymetric multibeam and ODP (Ocean Drilling Program) data obtained in the submarine channel between the volcanic islands of Gran Canaria and Tenerife allow to identify constructive features and destructive events during the evolution of both islands. The most prominent constructive features are the submarine island flanks being the acoustic basement of the seismic images. The build-up of Tenerife started following the submarine stage of Gran Canaria because the submarine island flank of Tenerife onlaps the steeper flank of Gran Canaria. The overlying sediments in the channel between Gran Canaria and Tenerife are chaotic, consisting of slumps, debris flow deposits, syn-ignimbrite turbidites, ash layers, and other volcaniclastic rocks generated by eruptions, erosion, and flank collapse of the volcanoes. Volcanic cones on the submarine island flanks reflect ongoing submarine volcanic activity. The construction of the islands is interrupted by large destructive events, especially by flank collapses resulting in giant landslides. Several Miocene flank collapses (e.g., the formation of the Horgazales basin) were identified by combining seismic and drilling data whereas young giant landslides (e.g., the Güimar debris avalanche) are documented by sidescan, bathymetric and drilling data. Sediments are also transported through numerous submarine canyons from the islands into the volcaniclastic apron. Seismic profiles across the channel do not show a major offset of reflectors. The existence of a repeatedly postulated major NE-SW-trending fault zone between Gran Canaria and Tenerife is thus in doubt. The sporadic earthquake activity in this area may be related to the regional stress field or the submarine volcanic activity in this area. Seismic reflectors cannot be correlated through the channel between the sedimentary basins north and south of Gran Canaria because the channel acts as sediment barrier. The sedimentary basins to the north and south evolved differently following the submarine growth of Gran Canaria and Tenerife in the Miocene.     

Englacial vs lacustrine origin of volcanic table mountains: evidence from iceland

Detailed facies analysis of hyaloclastites and associated lavas from eight table mountains and similar "hyaloclastite volcanoes" in the Icelandic rift zone contradict a rapid and continuous, "monogenetic", entirely subglacial evolution of most volcanoes studied. The majority of the exposed hyaloclastite deposits formed in large, stable lakes as indicated by widespread, up to 300-m-thick, continuous sections of deep water, shallow water and emergent facies. Salient features include extensively layered or bedded successions comprising mainly debris flow deposits, turbidites, base surge and fallout deposits consisting of texturally and compositionally variable, slightly altered hyaloclastites, as well as sheet and pillow lavas. In contrast, chaotic assemblages of coarser-grained, more poorly sorted and more strongly palagonitized hyaloclastite tuffs and breccias, as well as scoria and lava are interpreted to have formed under sub- or englacial conditions in small, chimney-like ice cavities or ice-bound lakes. Irregularly shaped and erratically arranged hyaloclastite bodies produced at variable water levels appear to have resulted mainly from rapid changes of the eruptive environment due to repeated build-up and drainage of ice-bound lakes as well as the restricted space between the ice walls. We distinguish a "deep water" facies formed during high water levels of the lake, a hydroclastic shallow water and emergent facies (leakage of the lake or growth of the volcano above the water surface). Our model implies the temporary existence of large, stable lakes in Iceland probably formed by climatically induced ice melting. The highly complex edifices of many table mountains and similar volcanoes were constructed during several eruptive periods in changing environments characterized by contrasting volcanic and sedimentary processes. Received: 10 June 1997 / Accepted: 28 July 1998     

Rothenberg scoria cone,East Eifel: a complex Strombolian and phreatomagmatic volcano

Rothenberg scoria cone Eifel formed by an alternation of three Strombolian and three phreatomagmatic eruptive phases. Eruptions took place from up to six vents on a 600 m-long fissure, building an early tuff ring and then two coalescing scoria cones. Strombolian volcanism dominated volumetrically, as the supply of external water was severely limited. Magma/water interaction only occurred during the opening stages of eruption at any vent, when discharge rates were low and the fragmentation surface was below the water table. The phreatomagmatic deposits consist of relatively well-sorted fall beds and only minor surge deposits. They contain juvenile clasts with a wide range of vesicularity and grain size, implying considerable heterogeneity in the assemblage of material ejected by the phreatomagmatic explosions. the transition from phreatomagmatic to Strombolian eruption at any vent was rapid and irreversible, and Strombolian volcanism persisted even when eruption rates are inferred to have waned at the close of each eruptive phase as, by then, the fragmentation surfaces were high in the growing cones and water was denied access to the magma. The Strombolian deposits are relatively homogenous, consisting of alternating coarser- and finer-grained, well-sorted fall beds erupted during periods of open-vent eruption and partial blockage of the vent respectively. The intervals of Strombolian eruption were always a delicate balance between discharge of freely degassing magma and processes such as ponding of degassed magma in the vent, collapse of the growing cones, and repeated recycling of clasts through the vent. Clear evidence of the instability of the Rothenberg cones is preserved in numerous unconformities within deposits of the inner walls of the cones. The close of Strombolian phases was probably marked by a decreasing supply of magma to the vents accompanied by ponding and stagnation of lava in the craters.     

Geochronology of Gran Canaria,Canary Islands: Age of shield building volcanism and other magmatic phases

Forty-six new K-Ar age determinations are presented on whole rock samples and mineral separates from volcanic and subvolcanic rocks of Gran Canaria. The main subaerial shield building basaltic volcanism with estimated volume of about 1000 km³ was confined to the interval about 13.7 m.y. to 13.5 m.y. ago in the middle Miocene. Substantial volume (～100 km³) of silicic volcanics (trachyte and peralkaline rhyolite) were erupted with no detectable time break following the basaltic volcanism, essentially contemporaneous with formation of a large collapse caldera at 13.4±0.3 m.y. ago. Trachytic to phonolitic volcanism continued intermittently in the waning states of activity until about 9 m.y. ago. Following a long hiatus there was resurgence of volcanism with eruption of about 100 km³ of basanitic to hauyne phonolitic rocks of the Roque Nublo Group between about 4.4 m.y. and 3.4 m.y. ago in the Pliocene. After a hiatus of less than 1.0 m.y., olivine nephelinite magmas were erupted and this activity continued intermittently until relatively recent times, the younger eruptives being mainly basanitic in composition. The volume of volcanic products in this phase probably does not exceed 10 km³. Thus the volume of all the resurgent volcanism comprises less than 10 percent of the subaerially exposed part of Gran Canaria. The results show that the subaerial main shield building phase of volcanism in Gran Canaria, consisting of mildly alkali to transitional basalts, occurred over a time interval that was less than 0.5 m.y. Magmatic evolution on Gran Canaria appears to be similar to that found on other basaltic volcanoes in oceanic regions. Thus volcanoes in the Hawaiian, Marquesas and Society Islands all were built by basaltic lavas in similar short-lived episodes of volcanism. In some Hawaiian volcanoes, a resurgent phase of volcanism of strongly undersaturated basalts of small volume is recognized following a long hiatus, again similar to that found on Gran Canaria. The relatively large volume of silicic lavas erupted in Gran Canaria immediately following the main basaltic shield building phase is, however, not matched in the Pacific volcanoes mentioned.     

Walking through volcanic mud: the 2,100-year-old Acahualinca footprints (Nicaragua)

We present the stratigraphy, lithology, volcanology, and age of the Acahualinca section in Managua, including a famous footprint layer exposed in two museum pits. The ca. 4-m-high walls of the main northern pit (Pit I) expose excellent cross sections of Late Holocene volcaniclastic deposits in northern Managua. We have subdivided the section into six lithostratigraphic units, some of which we correlate to Late Holocene eruptions. Unit I (1.2 m thick), chiefly of hydroclastic origin, begins with the footprint layer. The bulk is dominated by mostly massive basaltic-andesitic tephra layers, interpreted to represent separate pulses of a basically phreatomagmatic eruptive episode. We correlate these deposits based on compositional and stratigraphic evidence to the Masaya Triple Layer erupted at Masaya volcano ca. 2,120 ± 120 a B.P.. The eruption occurred during the dry season. A major erosional channel unconformity up to 1 m deep in the western half of Pit I separates Units II and I. Unit II begins with basal dacitic pumice lapilli up to 10 cm thick overlain by a massive to bedded fine-grained dacitic tuff including a layer of accretionary lapilli and pockets of well-rounded pumice lapilli. Angular nonvesicular glass shards are interpreted to represent hydroclastic fragmentation. The dacitic tephra is correlated unequivocally with the ca. 1.9-ka-Plinian dacitic Chiltepe eruption. Unit III, a lithified basaltic-andesitic deposit up to 50 cm thick and extremely rich in branch molds and excellent leaf impressions, is correlated with the Masaya Tuff erupted ca. 1.8 ka ago. Unit IV, a reworked massive basaltic-andesitic deposit, rich in brown tuff clasts and well bedded and cross bedded in the northwestern corner of Pit I, cuts erosionally down as far as Unit I. A poorly defined, pale brown mass flow deposit up to 1 m thick (Unit V) is overlain by 1–1.5 m of dominantly reworked, chiefly basaltic tephra topped by soil (Unit VI). A major erosional channel carved chiefly between deposition of Units II and I may have existed as a shallow drainage channel even prior to deposition of the footprint layer. The swath of the footprints is oriented NNW, roughly parallel to, and just east of, the axis of the channel. The interpretation of the footprint layer as the initial product of a powerful eruption at Masaya volcano followed without erosional breaks by additional layers of the same eruptive phase is strong evidence that the group of 15 or 16 people tried to escape from an eruption.     

A Mid Cretaceous origin for the Galápagos hotspot: volcanological, petrological and geochemical evidence from Costa Rican oceanic crustal segments

The Quepos, Nicoya and Herradura oceanic igneous terranes in Costa Rica are conspicuous features of a Mid to Late Cretaceous regional magmatic event that encompasses similar terranes in Central America, Colombia, Ecuador and the Caribbean. The Quepos terrane (66?Ma), which consists of ol-cpx phyric, tholeiitic pillow lavas overlain by highly vesicular hyaloclastites, breccias and conglomerates, is interpreted as an uplifted seamount/ocean island complex. The Nicoya (～90?Ma) and Herradura terranes consist of fault-bounded sequences of sediments, tholeiitic volcanics (pillow lavas and massive sheet flows) and plutonic rocks. The volcanic rocks were emplaced at relatively high eruption rates in moderate to deep water, possibly forming part of an oceanic plateau. Major and trace element data from Nicoya/Herradura tholeiites indicate higher melting temperatures than inferred for normal mid-ocean-ridge basalts (MORB) and/or a different source composition. Sr–Nd–Pb isotopic ratios from all three terranes are distinct from MORB but resemble those from the Galápagos hotspot. The volcanological, petrological and geochemical data from Costa Rican volcanic terranes, combined with published age data, paleomagnetic results and plate tectonic reconstructions of this region, provide strong evidence for a Mid Cretaceous (～90Ma) age for the Galápagos hotspot, making it one of the oldest known, active hotspots on Earth. Our results also support an origin of the Caribbean Plate through melting of the head of the Galápagos starting plume.     

Magma fractionation systems beneath the mid-Atlantic ridge at 36–37 ° N

Variation of major and trace elements in drilled basalts from the Mid-Atlantic Ridge (DSDP Leg 37) reflects distinct cycles of low pressure fractionation operating independently within a complex network of magma storage reservoirs beneath the crustal spreading axis. Low pressure phase relations are determined by parental magma composition, which varies from An-rich (An/Di > ca. 1.4) to Di-rich (An/Di < ca. 1.4). High An/Di magmas probably formed under slightly hydrous conditions in the mantle. They have low LIL element contents, low P/Y and high Mg/(Mg + Fe) ratios. Zr, P and Y abundance and inter-element ratios are highly diagnostic of primary magma type, and are used to quantify fractional crystallization models.Low pressure fractionation hypotheses were tested by least-squares modelling of whole-rock and phenocryst chemistry, which indicated removal or addition of phenocryst assemblages: ol; pl; ol + pl; ol + pl + cpx; pl + cpx, (± sp). Accumulation of plagioclase or olivine is an important mechanism for generating highly porphyritic rocks. A rare 3-phase (ol + pl + cpx) cumulate resulted from cotectic fractionation of a low An/Di magma type. Olivine and plagioclase cumulates appear to be related to high An/Di magmas. Olivine accumulation has been monitored by comparison of olivine/bulk rock partitioning of Fe and Mg to experimental measurements of the equilibrium K_D value. A single extensive sub-axial magma chamber could not account for the observed chemical variation and would probably be dynamically unstable.