Arsenic incorporation in a salt marsh ecosystem

Replicate portions of a Delaware salt marsh were enclosed in cylindrical microcosms and exposed to elevated levels of inorganic arsenic (arsenate). All biotic and abiotic components in dosed cylinders rapidly incorporated arsenic. Spartina blades showed the greatest arsenic enrichment, with dosed plants incorporating arsenic concentrations an order of magnitude higher than controls. Spartina detritus and sediments also exhibited greatly elevated arsenic concentrations. Virtually all of the arsenic was incorporated into plant tissue or strongly sorbed to cell surfaces. Thus, elevated arsenic concentrations in estuarine waters will be reflected in living and non-living components of a salt marsh ecosystem, implying that increased arsenic will be available to organisms within the marsh ecosystem.     

Fourier analysis of the light curves of eclipsing variables. XIII

New expressions for the fractional loss of light _l ⁰ have been derived in the simple forms of rapidly converging expansions to the series of Chebyshev polynomials, Jacobi polynomials, and Kopal'sJ-integrals. In these expansions, which are a supplement to those given by Kopal (1977b), variablesk andh occur in different products that simplify the numerical computation. The treatment follows the new definition of _l ⁰ which has been recently developed by Kopal (1977a).     

Geodynamic significance of granitoid magmatism in the southeast Anatolian orogen: geochemical and geochronogical evidence from Göksun–Afşin (Kahramanmaraş, Turkey) region

In southeast Anatolia, there are number of tectonomagmatic units in the Kahramanmaraş–Malatya–Elazığ region that are important in understanding the geological evolution of the southeast Anatolian orogenic belt during the Late Cretaceous. These are (a) metamorphic massifs, (b) ophiolites, (c) ophiolite-related metamorphics and (d) granitoids. The granitoids (i.e. Göksun–Afşin in Kahramanmaraş, Doğanşehir in Malatya and Baskil in Elazığ) intrude all the former units in a NE–SW trending direction. The granitoid in Göksun–Afşin (Kahramanmaraş) region is mainly composed of granodioritic and granitic in composition. The granodiorite contains a number of amphibole-bearing mafic microgranular enclaves of different sizes, whereas the granite is intruded by numerous aplitic dikes. The granitoid rocks have typical calcalkaline geochemical features. The REE- and Ocean ridge granite-normalized multi-element patterns and tectonomagmatic discrimination diagrams, as well as biotite geochemistry suggest that the granitoids were formed in a volcanic arc setting. The K–Ar geochronology of the granitoid rocks yielded ages ranging from 85.76±3.17 to 77.49±1.91 Ma. The field, geochemical and geochronological data suggest the following Late Cretaceous tectonomagmatic scenario for southeast Anatolia. The ophiolites were formed in a suprasubduction zone tectonic setting whereas the ophiolite-related metamorphic rocks formed either during the initiation of intraoceanic subduction or late-thrusting (∼90 Ma). These units were then overthrust by the Malatya–Keban platform during the progressive elimination of the southern Neotethys. Thrusting of the Malatya–Keban platform over the ophiolites and related metamorphic rocks was followed by the intrusion of the granitoids (88–85 Ma) along the Tauride active continental margin in the southern Neotethys.     

EXPERIMENTAL AND FIELD STUDY ON MINING-PIT MIGRATION

1 INTRODUCTION Because of the large quantity of sand and gravel in their beds, rivers have always been considered as a major source of sand and gravel for civil works. Acceptable quality, ease of extraction and economy are some of the reasons could be mentioned. Unfortunately, specific laws and regulations regarding the safe in-stream mining have not been provided for users and officials. What should be taken into account are the effects of over-mining of sand and gravel, which can cause …     

铀在近代海洋生物中的积聚

本文研究的目的是确定软体动物对于铀在海洋生态系统中的分布所起的地球化学作用。对取自里海、日本海、马尔马拉海、爱琴海、黑海、地中海、波罗的海和印度洋的近代软体动物贝壳进行了生物地球化学研究,这些贝壳的物理、化学、地理和地球化学特征各不相同。本次研究中,分析了9个腹足类和54个双壳类不同种的贝壳以记录铀在不同季节层中的变化。季节层是由软体动物在整个生命过程中季节性的碳酸盐—有机相生成的。研究中使用的贝壳主要分3层:上(外)棱柱层,中棱柱层,内(珠母)层。此外,条件许可时,将贝壳性的头部、中部和下部分别进行分析,并且还计算出相对     

Analysis of parameters of ground vibration produced from bench blasting at a limestone quarry

The aim of this study is to predict peak particle velocity level at a limestone quarry located in Istanbul, Turkey. The ground vibration components were measured for 73 blast events during the bench blast optimization studies during a long period. In blasting operations; ANFO (blasting agent), gelatine dynamite (priming) and NONEL detonators (firing) were used as explosives at this site. Parameters of scaled distance (charge quantity per delay and the distance between the source and the station) were recorded carefully and the ground vibration components were measured by means of vibration monitors for every event. Then, the data pairs of scaled distance and particle velocity were analyzed. The equation of scaled distance extensively used in the literature was taken into consideration for the prediction of peak particle velocity. At the end of statistical evaluations, an empirical relationship with good correlation was established between peak particle velocity and scale distance for this site. The established relationship and the results of the study are presented.     

Green synthesis of magnetic mesoporous silica nanocomposite and its adsorptive performance against organochlorine pesticides

Green synthesis of nanomaterials has received increasing attention as an eco-friendly technology in materials science. Here, we have used two types of extractions from green tea leaf (i.e., total extraction and tannin extraction) as reducing agents for a rapid, simple and one-step synthesis method of mesoporous silica nanoparticles/iron oxide nanocomposite based on deposition of iron oxide onto mesoporous silica nanoparticles. Mesoporous silica nanoparticles/iron oxide nanocomposite were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray, vibrating sample magnetometer, N₂ adsorption and high-resolution transmission electron microscopy. Mesoporous silica nanoparticles/iron oxide nanocomposite was used as a solid adsorbent for removal of lindane pesticide from aqueous solutions. The developed system possesses the advantages of silica as core that include large surface area and advantages of iron oxide (shell) that include the capability to interact with chlorinated compounds and ability to release by using external magnetic field. UV-Vis technique was used as a simple and easy method for monitoring the removal of lindane. Effects of pH and temperature on the removal efficiency of the developed mesoporous silica nanoparticles/iron oxide nanocomposite toward lindane pesticide were also investigated. Fourier transform infrared spectroscopy, high-performance liquid chromatography and gas chromatography techniques were used to confirm the high ability of mesoporous silica nanoparticles/iron oxide nanocomposite for sensing and the capture of lindane molecules with high sorption capacity (about 99%) that could develop a new eco-friendly strategy for detection and removal of pesticide and as a promising material for water treatment.     

Chemical composition of rock-forming minerals and crystallization physicochemical conditions of the Middle Eocene I-type Haji Abad pluton,SW Buin-Zahra,Iran

The Haji Abad intrusion is a well-exposed Middle Eocene I-type granodioritc pluton in the Urumieh–Dokhtar magmatic assemblage (UDMA). The major constituents of the investigated rocks are K-feldspar, quartz, plagioclase, pyroxene, and minor Fe–Ti oxide and hornblende. The plagioclase compositions fall in the labradorite, andesine, and oligoclase fields. The amphiboles range in composition from magnesio-hornblende to tremolite–hornblende of the calcic-amphibole group. Most pyroxenes principally plot in the field of diopside. The calculated average pressure of emplacement is 1.9 kbar for the granodioritic rocks, crystallizing at depths of about 6.7 km. The highest pressure estimated from clinopyroxene geobarometry (5 kbar) reflects initial pyroxene crystallization pressure, indicating initial crystallization depth (17.5 km) in the Haji Abad granodiorite. The estimated temperatures using two-feldspar thermometry give an average 724 °C. The calculated average temperature for clinopyroxene crystallization is 1090 °C. The pyroxene temperatures are higher than the estimated temperature by feldspar thermometry, indicating that the pyroxene and feldspar temperatures represent the first and late stages of magmatic crystallization of Haji Abad granodiorite, respectively. Most pyroxenes plot above the line of Fe³⁺?=?0, indicating they crystallized under relatively high oxygen fugacity or oxidized conditions. Furthermore, the results show that the Middle Eocene granitoids crystallized from magmas with H₂O content about 3.2 wt%. The relatively high water content is consistent with the generation environment of HAG rocks in an active continental margin and has allowed the magma to reach shallower crustal levels. The MMEs with ellipsoidal and spherical shapes show igneous microgranular textures and chilled margins, probably indicating the presence of magma mixing. Besides, core to rim compositional oscillations (An and FeO) for the plagioclase crystals serve as robust evidence to support magma mixing. The studied amphiboles and pyroxenes are grouped in the subalkaline fields that are consistent with crystallization from I-type calc-alkaine magma in the subduction environment related to active continental margin. Mineral chemistry data indicate that Haji Abad granodiorites were generated in an orogenic belt related to the volcanic arc setting consistent with the subduction of Neo-Tethyan oceanic crust beneath the central Iranian microcontinent.     

A study of aerosol properties over Lahore (Pakistan) by using AERONET data

It is well established that aerosols affect the climate in a variety of ways. In order to understand these effects, we require an insight into the properties of aerosols. In this paper we present a study of aerosol properties such as aerosol optical depth (AOD), single scattering albedo (SSA) and aerosol radiative forcing (ARF) over mega city of Lahore (Pakistan). The data from Aerosol Robotic Network (AERONET) have been used for the period December 2009 to October 2011. The seasonal average values of AOD, asymmetry parameter (ASY) and volume size distribution in coarse mode were observed to be highest in summer. On the other hand, the average values of Angstrom exponent (AE) and imaginary part of refractive index (RI) were found to be maximum in winter. The average value of real part of RI was found to be higher in spring than in all other seasons. The SSA exhibited an increasing trend with wavelength in the range 440 nm–1020 nm in spring, summer and fall indicating the dominance of coarse particles (usually dust). However, a decreasing trend was found in winter in the range 675 nm–1020 nm pointing towards the dominance of biomass and urban/industrial aerosols. As far as aerosol radiative forcing (ARF) is concerned, we have found that during the spring season ARF was lowest at the surface of Earth and highest at top of the atmosphere (TOA). This indicates that the atmosphere was warmer in spring than in all the remaining seasons.