Appropriate teaching materials for Africa: local is ‘lekker’!

Most of the statistics given in this overview of the history and current status of Geoscience Education in South Africa pertain to the more geologically inclined disciplines; while the report does mention the extent to which earth sciences are taught in mining and geography departments, no detailed information about these activities are given. There are 13 active geoscience departments countrywide (eleven at universities and two at technical institutions) teaching a wide range of geological topics, some at a highly specialised level. There are just over 100 academic staff members engaged in teaching, supported by 65 technical and administrative staff. Of the teaching staff, 89% have Ph.D. degrees, and most are engaged in active research. About 150 three-year B.Sc., slightly fewer B.Sc. (Hons.), graduates, plus 10 geological technicians pass through the system every year, with most finding employment in the mining industry. Approximately 120 M.Sc. and 60 Ph.D. candidates are currently registered at the universities, about 40% of whom graduate in any particular year.     

The Allende multicompound chondrule (ACC)—Chondrule formation in a local super‐dense region of the early solar system

In Allende, a very complex compound chondrule (Allende compound chondrule; ACC) was found consisting of at least 16 subchondrules (14 siblings and 2 independents). Its overall texture can roughly be described as a barred olivine object (BO). The BO texture is similar in all siblings, but does not exist in the two independents, which appear as relatively compact olivine‐rich units. Because of secondary alteration of pristine Allende components and the ACC in particular, only limited predictions can be made concerning the original compositions of the colliding melt droplets. Based on textural and mineralogical characteristics, the siblings must have been formed on a very short time scale in a dense, local environment. This is also supported by oxygen isotope systematics showing similar compositions for all 16 subchondrules. Furthermore, the ACC subchondrules are isotopically distinct from typical Allende chondrules, indicating formation in or reaction with a more ¹⁶O‐poor reservoir. We modeled constraints on the particle density required at the ACC formation location, using textural, mineral‐chemical, and isotopic observations on this multicompound chondrule to define melt droplet collision conditions. In this context, we discuss the possible relationship between the formation of complex chondrules and the formation of macrochondrules and cluster chondrites. While macrochondrules may have formed under similar or related conditions as complex chondrules, cluster chondrites certainly require different formation conditions. Cluster chondrites represent a mixture of viscously deformed, seemingly young chondrules of different chemical and textural types and a population of older chondrules. Concerning the formation of ACC calculations suggest the existence of very local, kilometer‐sized, and super‐dense chondrule‐forming regions with extremely high solid‐to‐gas mass ratios of 1000 or more.     

Surface Geophysical Methods used to Verify the Karst Geological Structure in the Built-up Area: A Case Study of Specific Engineering-Geological Conditions

This article presents a research study of complex limestone karst engineering-geological conditions in the municipality Valaská near Banská Bystrica in Slovakia. The aim of the study is to demonstrate the impossibility of spatial identification of cave spaces using surface geophysical methods due to the specific engineering-geological conditions of a thick surface layer of anthropogenic fill containing highly heterogeneous anthropogenic material. Its maximum thickness is 3 m. Another specificific condition of the study area is its location in the built-up area, due to which the applicability of geophysical methods was limited. The article contains methodological recommendations to be used in analogous geological conditions with karst structures topped with anthropogenic fill, which complicates the identification of cave spaces. The recommended solution herein is the identification of the cave system using underground mapping of the karst and its projection onto the surface for which surface geophysical methods have been combined.     

Evaluation of the Presence of Methane in Złoczew Lignite: Comparison with Other Lignite Deposits in Poland

Natural Resources Research - Catastrophic cases of methane explosion during exploratory drilling within the Be?chatów ortholignite deposit have led to testing for methane in other Polish...     

Copper isotope fractionation during surface adsorption and intracellular incorporation by bacteria

Copper isotopes may prove to be a useful tool for investigating bacteria-metal interactions recorded in natural waters, soils, and rocks. However, experimental data which attempt to constrain Cu isotope fractionation in biologic systems are limited and unclear. In this study, we utilized Cu isotopes (δ⁶⁵Cu) to investigate Cu-bacteria interactions, including surface adsorption and intracellular incorporation. Experiments were conducted with individual representative species of Gram-positive (Bacillus subtilis) and Gram-negative (Escherichia coli) bacteria, as well as with wild-type consortia of microorganisms from several natural environments. Ph-dependent adsorption experiments were conducted with live and dead cells over the pH range 2.5-6. Surface adsorption experiments of Cu onto live bacterial cells resulted in apparent separation factors (Δ⁶⁵Cu_{solution-solid} = δ⁶⁵Cu_solution − δ⁶⁵Cu_solid) ranging from +0.3‰ to +1.4‰ for B. subtilis and +0.2‰ to +2.6‰ for E. coli. However, because heat-killed bacterial cells did not exhibit this behavior, the preference of the lighter Cu isotope by the cells is probably not related to reversible surface adsorption, but instead is a metabolically-driven phenomenon. Adsorption experiments with heat-killed cells yielded apparent separation factors ranging from +0.3‰ to −0.69‰ which likely reflects fractionation from complexation with organic acid surface functional group sites. For intracellular incorporation experiments the lab strains and natural consortia preferentially incorporated the lighter Cu isotope with an apparent Δ⁶⁵Cu_{solution-solid} ranging from ∼+1.0‰ to +4.4‰. Our results indicate that live bacterial cells preferentially sequester the lighter Cu isotope regardless of the experimental conditions. The fractionation mechanisms involved are likely related to active cellular transport and regulation, including the reduction of Cu(II) to Cu(I). Because similar intracellular Cu machinery is shared by fungi, plants, and higher organisms, the influence of biological processes on the δ⁶⁵Cu of natural waters and soils is probably considerable.     

The REMIND-R model: the role of renewables in the low-carbon transformation—first-best vs. second-best worlds

Can near-term public support of renewable energy technologies contain the increase of mitigation costs due to delays of implementing emission caps at the global level? To answer this question we design a set of first and second best scenarios to analyze the impact of early deployment of renewable energy technologies on welfare and emission timing to achieve atmospheric carbon stabilization by 2100. We use the global multiregional energy?Ceconomy?Cclimate hybrid model REMIND-R as a tool for this analysis. An important design feature of the policy scenarios is the timing of climate policy. Immediate climate policy contains the mitigation costs at less than 1% even if the CO₂ concentration target is 410?ppm by 2100. Delayed climate policy increases the costs significantly because the absence of a strong carbon price signal continues the carbon intensive growth path. The additional costs can be decreased by early technology policies supporting renewable energy technologies because emissions grow less, alternative energy technologies are increased in capacity and their costs are reduced through learning by doing. The effects of early technology policy are different in scenarios with immediate carbon pricing. In the case of delayed climate policy, the emission path can be brought closer to the first-best solution, whereas in the case of immediate climate policy additional technology policy would lead to deviations from the optimal emission path. Hence, technology policy in the delayed climate policy case reduces costs, but in the case of immediate climate policy they increase. However, the near-term emission reductions are smaller in the case of delayed climate policies. At the regional level the effects on mitigation costs are heterogeneously distributed. For the USA and Europe early technology policy has a positive welfare effect for immediate and delayed climate policies. In contrast, India looses in both cases. China loses in the case of immediate climate policy, but profits in the delayed case. Early support of renewable energy technologies devalues the stock of emission allowances, and this effect is considerable for delayed climate policies. In combination with the initial allocation rule of contraction and convergence a relatively well-endowed country like India loses and potential importers like the EU gain from early renewable deployment.     

Economic Development and Emission Control over the Long Term: The ICLIPS Aggregated Economic Model

In integrated assessments of climate change, greenhouse-gasemissions and climate change impacts provide the linkages betweenthe world economy and the climate system. Key climatic processesoperate at the scales of centuries. This requires highlyaggregated models for portraying the dynamics of the economicsystem. An extended Ramsey-type optimal growth model is presentedas the appropriate tool to be integrated with a reduced-formclimate model in the ICLIPS integrated assessment. Theeleven-region model of the world economy involves exogenouspopulation and endogenous investment dynamics with productivityprogress based on a technological diffusion model. World regionsare linked via intertemporal trade flows of the compositeconsumption/investment good, capital mobility, and emission permittrading. Coupled with the ICLIPS Climate Model, the AggregatedEconomic Model can determine corridors of permitted long-termcarbon emission paths or, as primarily discussed in this paper,specific cost-effective emission trajectories. The sensitivity ofmitigation costs to externally specified climate change/impactconstraints and to assumptions about non-CO₂ greenhouse-gasemissions is also discussed.     

The Gaojiacun Mafic-Ultramafic Complex （Sichuan, SW China）：Neoproterozoic Magmatic Activity at the Western Margin of the Yangtze Craton

1 Introduction The Gaojiacun intrusive complex is one of the numerous ultramafic-mafic intrusions in Sichuan Province of China. It was mapped during the 1970s and studied mainly by Chinese scientists (e.g. Geological Team 106, 1975; Shen et al., 1986, 1989; CGGJC, 1986; Yang et al., 1993; Li et al., 1995; Shen et al., 2003; Zhu et al., 2004a). Since the year 2000, China has become one of the largest PGE consumers. While the country can produce only less than 1 ton PGE/year, the Chin…     

Sustainable Chemical Technologies in Production of Clean Fuels from Fossil Fuels

Some aspects of the present and the possible future role of sustainable chemical technologies in the production of clean liquid and gaseous fuels from fossil fuels are discussed. The state‐of‐the‐art and the vision of possible sources and alternative routes which may lead to clean fuels from fossil fuels due to the progress in crude oil, natural gas and coal processing are briefly presented. The possible future role of the Fischer‐Tropsch synthesis, methanol synthesis, dimethylether synthesis, and a group of methanol transformation processes is also discussed.