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1.
Jens Fiebig Giovanni Chiodini Andrea Rizzo Johannes C. Hunziker 《Geochimica et cosmochimica acta》2004,68(10):2321-2334
The chemical and isotopic composition of fumarolic gases emitted from Nisyros Volcano, Greece, and of a single gas sample from Vesuvio, Italy, was investigated in order to determine the origin of methane (CH4) within two subduction-related magmatic-hydrothermal environments.Apparent temperatures derived from carbon isotope partitioning between CH4 and CO2 of around 340°C for Nisyros and 470°C for Vesuvio correlate well with aquifer temperatures as measured directly and/or inferred from compositional data using the H2O-H2-CO2-CO-CH4 geothermometer. Thermodynamic modeling reveals chemical equilibrium between CH4, CO2 and H2O implying that carbon isotope partitioning between CO2 and CH4 in both systems is controlled by aquifer temperature.N2/3He and CH4/3He ratios of Nisyros fumarolic gases are unusually low for subduction zone gases and correspond to those of midoceanic ridge environments. Accordingly, CH4 may have been primarily generated through the reduction of CO2 by H2 in the absence of any organic matter following a Fischer-Tropsch-type reaction. However, primary occurrence of minor amounts of thermogenic CH4 and subsequent re-equilibration with co-existing CO2 cannot be ruled out entirely. CO2/3He ratios and δ13CCO2 values imply that the evolved CO2 either derives from a metasomatized mantle or is a mixture between two components, one outgassing from an unaltered mantle and the other released by thermal breakdown of marine carbonates. The latter may contain traces of organic matter possibly decomposing to CH4 during thermometamorphism. 相似文献
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To achieve environmental sustainability and reduce their vulnerability to oil shocks, countries can develop new energy technologies. Technological advances reduce the cost of structural changes in the energy economy, and thus also increase the political feasibility of such changes. But what explains international variation in the form and quality of energy technology innovation? We build on previous theories and offer an integrated account: increasing oil prices reinforce existing sectoral innovation systems, both politically and economically, thus allowing public policymakers and private entrepreneurs to profitably invest in new energy technologies. We test this theoretical argument against data on public R&D expenditures and patents in the domain of renewable energy technology for industrialized countries from 1989 to 2007. We find strong support for the interactive hypothesis. Thus, we contribute to literatures on (i) domestic responses to international shocks, (ii) environmental sustainability and energy security, and (iii) the political economy of technology innovation. 相似文献
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Joana F.M.F. Cardoso Johannes IJ. Witte Henk W. van der Veer 《Estuarine, Coastal and Shelf Science》2009
Cerastoderma edule and Mya arenaria are two common bivalve species in European waters. Longevity and maximum size are much greater in the latter species. Because comparison of species life-history strategies states that a long life span (i.e. high annual survival) generally goes with lower fecundity, we hypothesise that reproductive output would be lower in M. arenaria than in C. edule. In the present paper, we studied the reproductive strategies of these two species in an intertidal and a subtidal area of the western Dutch Wadden Sea, by following seasonal changes in absolute and relative weights of somatic and gonadal tissues in these bivalves. Starting of spawning was similar in the two species, around May, except for intertidal M. arenaria, which initiated spawning in August. Individual energy investment in reproduction was similar for the two species but, unlike M. arenaria, C. edule spawned completely, releasing all energy of gonadal mass in the form of gametes. Mya arenaria used the gonad not only for reproduction but also for storage. In the intertidal area, we found a trade-off between longevity and reproduction, i.e. maximum reproductive output (expressed as a proportion of body mass) was higher in C. edule than in M. arenaria. However, since body size is larger and life span longer in M. arenaria than in C. edule, mean lifetime reproductive output per individual must be higher in the first than in the latter. Based on the differences in reproductive strategies of these two species, we hypothesise that the negative effects of warming climate on bivalve population dynamics in the Wadden Sea will be stronger in C. edule than in M. arenaria. 相似文献
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Alicja Wudarska Ewa Saby Michael Wiedenbeck Jaime D. Barnes Magali Bonifacie Neil C. Sturchio Grard Bardoux Frdric Couffignal Johannes Glodny Linnea Heraty Timm John Christof Kusebauch Sathish Mayanna Franziska D. H. Wilke Ewa Deput 《Geostandards and Geoanalytical Research》2021,45(1):121-142
Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca10(PO4)6(F,Cl,OH)2 solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for 37Cl/35Cl homogeneity using SIMS followed by δ37Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean 37Cl/35Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ37ClSMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 103δ37ClSMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25. 相似文献
9.
Second-order wave maker theory has long been established; the most extensive and detailed approach given by Schäffer [1996. Second-order wave maker theory for irregular waves. Ocean Engineering 23, 47–88]. However, all existing theories assume the wave paddle is driven by a position-feedback motion controller. Early research in the wave power field led to the design of a force-controlled absorbing wave machine [Salter, S., 1982. Absorbing wave-makers and wide tanks. In: Directional Wave Spectra Applications, pp. 185–200]. In addition to operating as an excellent absorber, this machine seemed to introduce very little spurious harmonic content when driven with a first-order command signal. The present paper provides a mathematical model for the operation of wave makers using force-feedback control and seeks to explain this apparent advantage. The model is developed to second-order so that a command signal compensating for the remaining spurious wave is also provided. Due to the complexity of the problem, the model has been limited to flap-type wave machines and the generation of regular waves. A variety of numerical tests in force-control mode have been conducted, indicating that the spurious wave content is greatly reduced when compared to the position-control mode. A separate experimental study validating the theory is presented in a part II paper by the same authors. 相似文献
10.
Johannes Dambach Michael J. Raupach Florian Leese Julia Schwarzer Jan O. Engler 《Marine Ecology》2016,37(6):1336-1344
The coherency among larval stages of marine taxa, ocean currents and population connectivity is still subject to discussion. A common view is that organisms with pelagic larval stages have higher dispersal abilities and therefore show a relatively homogeneous population genetic structure. Contrary to this, local genetic differentiation is assumed for many benthic direct developers. Specific larval or adult migratory behavior and hydrographic effects may significantly influence distribution patterns, rather than passive drifting abilities alone. The Southern Ocean is an ideal environment to test for the effects of ocean currents on population connectivity as it is characterized by several well‐defined and strong isolating current systems. In this study we studied the genetic structure of the decapod deep‐sea shrimp Nematocarcinus lanceopes, which has planktotrophic larval stages. We analysed 194 individuals from different sample localities around the Antarctic continent using nine microsatellite markers. Consistent with a previous study based on mitochondrial DNA markers, primarily weak genetic patterns among N. lanceopes populations around the continent were found. Using ocean resistance modeling approaches we were able to show that subtle genetic differences among populations are more likely explained by ocean currents rather than by geographic distance for the Atlantic Sector of the Southern Ocean. 相似文献