Thermal expansivities of supercooled haplobasaltic liquids

The thermal expansion of supercooled liquids in the haplobasaltic (anorthite-diopside) system have been determined via methods of container-based dilatometry. The expansivity data obtained in this study agree well with estimates provided by previous dilatometric determinations in the system that have relied on alternative experimental strategies. The data have been combined with high-temperature, superliquidus determinations of melt density to obtain expressions for the volume-temperature (V-T) relationships of liquids in the anorthite-diopside system. The V-T data clearly indicate a nonlinear temperature dependence of volume for all melts investigated. The variation is most striking for diopside, where the coefficient of volume thermal expansion decreases ∼56% from temperatures near the glass transition to superliquidus temperatures. With increasing anorthite content, the degree of variation appears to decrease. An₄₂Di₅₈ exhibits a decrease of 39% of its coefficient of thermal expansion and An₉₈Di₀₂ of 33%, respectively. The expansivities obtained in this study cannot be reproduced by means of published models that are based on linear V-T relationships. They require instead a reanalysis of existing pressure-V-T equations of state models for silicate melts.     

Deflation during caldera unrest: constraints on subsurface processes and hazard prediction from gravity–height data

We have evaluated published gravity-height ((g/(h) data on Campi Flegrei, Kilauea, Askja and Krafla, in order to discriminate between subsurface processes during caldera subsidence. With respect to end member gravity-height correlations, such as the free air gradient (FAG) and the Bouguer corrected free air (BCFAG), (g/(h gradients must be interpreted in terms of subsurface mass redistribution, density changes or some combination of these. (g/(h gradients during subsidence plot (1) along or below the BCFAG, (2) between the BCFAG and the FAG or (3) along or above the FAG. We have evaluated each of these three regions in terms of subsurface processes during volcano subsidence. We have interpreted (g/(h gradients as possible indicators of precursors of volcanic activity and propose that gravity-height surveys may help to detect precursors of caldera collapse caused by magma drainage. In this context, the 1875 eruption of Askja in Iceland has been re-interpreted in terms of the beginning of the eruptive episode being induced by roof collapse of an evacuating magma chamber. Based on other examples of recent volcanic roof collapses, we evaluate the contribution of gravity-height surveys in assessing volcanic risks during caldera subsidence. Caldera-forming eruptions are environmentally and economically the most devastating volcanic events. Inflation is usually considered to be an important precursor to activity. Here, we show that deflation may be associated with the trigger mechanism for caldera-forming explosive eruptions.     

Modelling and forecasting long-term dynamics of Western Baltic macrobenthic fauna in relation to climate signals and environmental change

Long-term macrobenthos data from Kiel Bight in the Western Baltic collected between 1968 and 2000 have been correlated with the winter NAO index (North Atlantic Oscillation Index) and other environmental data such as temperature, salinity and oxygen content in the bottom water in order to detect systematic patterns related to so far unexplained abiotic signals in the dynamics of zoobenthic species assemblages. The benthos data come from a cluster of five stations (Süderfahrt/ Millionenviertel) in Kiel Bay. Our investigations concentrated on the macrobenthic dynamics with a focus on the number of species m^− 2 (species richness). Using logarithms and the time series analysis approach of Box/Jenkins (ARIMA modelling, transfer function modelling) it was shown that species richness was strongly influenced by the winter NAO (adjusted for a linear time trend within the 1968-2000 period) and salinity (with a shift/lag of four years). Bootstrapping experiments (i.e. sampling from the error process) and analysis of prediction power (by means of the one- or more-years leaving-out method) showed that the parameter estimates behaved in a stable way, leading to a relatively robust model.     

Protein carbonyls and antioxidant defenses in corkwing wrasse (Symphodus melops) from a heavy metal polluted and a PAH polluted site

The use of fish in environmental monitoring has become increasingly important in recent years as anthropogenic substances, many of which function as prooxidants, are accumulating in aquatic environments. We have measured a battery of antioxidant defenses as a measure of oxidative status, as well as protein carbonylation as a measure of oxidative damage, in corkwing wrasse (Symphodus melops) captured near a disused copper mine, where water and sediment are contaminated with heavy metals, and an aluminum smelter, a site contaminated with PAHs. Results were compared to two different reference sites. Fish at the heavy metal site had lower glucose-6-phosphate dehydrogenase activity and elevated protein carbonyls (1.8 times) compared to fish from the reference site. At the PAH site, EROD was increased 2-fold, while total glutathione and methemoglobin reductase concentration, were decreased. No differences were seen in protein carbonyl levels at the PAH site. Measures of both antioxidant defenses and oxidative damage should be used when assessing effects of xenobiotics on oxidative stress in fish species.