Thaw modification of frost-fissure wedges,Richards Island,Pleistocene Mackenzie Delta,Western Arctic Canada

Thaw modification is the general process whereby frost-fissure wedges are modified during thaw, and by which frost-fissure pseudomorphs may develop. Specific processes of thaw modification are inferred from ice-wedge pseudomorphs, composite-wedge pseudomorphs and deformed sand wedges in the Pleistocene Mackenzie Delta: i.e. thermal erosion, collapse, subsidence, refreezing, loading, buoyancy, spreading, folding and shearing. Thaw modification is believed to result in selective preservation of pseudomorphs and wedges. Sand wedges are more likely to be preserved than are ice-wedge pseudomorphs or compositewedge pseudomorphs, because only those sand wedges that penetrate massive ice or icy sediments are prone to thaw modification. Furthermore, whereas ice wedges preferentially develop in ice-rich, fine-grained sediments (thaw-sensitive), their pseudomorphs appear to be selectively preserved in ice-poor, coarse-grained sediments (thaw-stable).     

Characterizing Observed Environmental Variability With HF Doppler Radar Surface Current Mappers and Acoustic Doppler Current Profilers: Environmental Variability in the Coastal Ocean

A network of high-frequency (HF) radars is deployed along the New Jersey coast providing synoptic current maps across the entire shelf. These data serve a variety of user groups from scientific research to Coast Guard search and rescue. In addition, model forecasts have been shown to improve with surface current assimilation. In all applications, there is a need for better definitions and assessment of the measurement uncertainty. During a summer coastal predictive skill experiment in 2001, an array of in situ current profilers was deployed near two HF radar sites, one long-range and one standard-range system. Comparison statistics were calculated between different vertical bins on the same current profiler, between different current profilers, and between the current profilers and the different HF radars. The velocity difference in the vertical and horizontal directions were then characterized using the observed root-mean-square (rms) differences. We further focused on two cases, one with relatively high vertical variability, and the second with relatively low vertical variability. Observed differences between the top bin of the current profiler and the HF radar were influenced by both system accuracy and the environment. Using the in situ current profilers, the environmental variability over scales based on the HF radar sampling was quantified. HF radar comparisons with the current profilers were on the same order as the observed environmental difference over the same scales, indicating that the environment has a significant influence on the observed differences. Velocity variability in the vertical and horizontal directions both contribute to these differences. When the potential effects of the vertical variability could be minimized, the remaining difference between the current profiler and the HF radar was similar to the measured horizontal velocity difference (~2.5 cm/s) and below the resolution of the raw radial data at the time of the deployment     

A Yohkoh search for “black-light flares”

Calculations which predict that a phenomenon analogous to stellar negative pre-flares could also exist on the Sun were published by Hénouxet al. (1990), and Aboudarhamet al., (1990), who showed that at the beginning of a solar white-light flare (WLF) event an electron beam can cause a transient darkening before the WLF emission starts, under certain conditions. They named this event a black light flare (BLF). Such a BLF event should appear as diffuse dark patches lasting for about 20 seconds preceding the WLF emission, which would coincide with intense and impulsive hard X-ray bursts. The BLF location would be at (or in the vicinity of) the forthcoming bright patches. Their predicted contrast depends on the position of the flare on the solar disc and on the wavelength band of the observation.TheYohkoh satellite provided white-light data from the aspect camera of the SXT instrument (Tsunetaet al., 1991), at 431 nm and with a typical image interval of 10–12 s. We have studied nine white-light flares observed with this instrument, with X-ray class larger than M6. We have found a few interesting episodes, but no unambiguous example of the predicted BLF event. This study, although the best survey to date, was not ideal from the observational point of view. We therefore encourage further searches. Successful observations of this phenomenon on the Sun would greatly strengthen our knowledge of the lower solar atmosphere and its effects on solar luminosity variations.     

Thermodynamic data from redox reactions at high temperatures. II. The MnO-0Mn3O4 oxygen buffer,and implications for the thermodynamic properties of MnO and Mn3O4

The \(\mu _{O_2 } \) defined by the reaction 6 MnO+O₂ =2 Mn₃O₄ has been determined from 917 to 1,433 K using electrochemical cells (with calcia-stabilized zirconta, CSZ) of the type: Steady emfs were achieved rapidly at all temperatures on both increasing and decreasing temperature, indicating that the MnO-Mn₃O₄ oxygen buffer equilibrates relatively easily. It therefore makes a useful alternative choice in experimental petrology to Fe₂O₃-Fe₃O₄ for buffering oxygen potentials at oxidized values. The results are (in J/mol, temperature in K, reference pressure 1 bar); \(\mu _{O_2 } \) (±200)=-563,241+1,761.758T-220.490T inT+0.101819T ² with an uncertainty of ±200 J/mol. Third law analysis of these data, including a correction for the deviations in stoichiometry of MnO, impliesS _298.15 for Mn₃O₄ of 166.6 J/K · mol, which is 2.5 J/K · mol higher than the calorimetric determination of Robie and Hemingway (1985). The low value of the calorimetric entropy may be due to incomplete ordering of the magnetic spins. The third law value of Δ _r H _298.15 ⁰ is-450.09 kJ/mol, which is significantly different from the calorimetric value of-457.5±3.4 kJ/mol, calculated from Δ _f H _298.15 ⁰ of MnO and Mn₃O₄, implying a small error in one or both of these latter.     

Inferring erosional resistance of bedrock units in the east Tennessee mountains from digital elevation data

Measures of local relief, regional relief, and slope were calculated from digital elevation models (DEMs) for 50 bedrock units in the Ridge and Valley and Blue Ridge provinces of Tennessee. Each of these measures was normalized and the three were then averaged to produce the erosional resistance index (ERI). Bedrock units with higher ERI values include coarse clastics, intermediate clastics, and metaplutonics. Units with lower values include shales, limestones, limestones plus dolostones, and carbonates plus fine clastics. Dolostones tend to have intermediate values. The calculated ERI values were compared with subjective ratings by a geologist with decades of field experience in east Tennessee. Generally, the agreement between the two ratings was good, the most glaring exception being several shales with improbably high ERI values. These turned out to be thin units cropping out beneath very hard sandstones, allowing them to stand higher and steeper than would otherwise be possible. A systematic method for detecting such erroneously high ERI values is suggested. Inspection of a drainage map superimposed on the geology map shows that in a given area, streams tend to flow on rock units with the lowest ERI values. In addition, statistical analysis shows that bedrock units with the lowest ERI values are, on average, almost three times closer to the nearest stream and six times as likely to have streams flowing on them than are units with highest values. Further, the effect of ERI on stream location is strongest for streams with drainage areas between 1 and 30 km². Thus, small streams appear to be subject to greater lithologic control than are larger streams.     

Experimental calibration of vanadium partitioning and stable isotope fractionation between hydrous granitic melt and magnetite at 800 °C and 0.5 GPa

Vanadium has multiple oxidation states in silicate melts and minerals, a property that also promotes fractionation of its isotopes. As a result, vanadium isotopes vary during magmatic differentiation, and can be powerful indicators of redox processes at high temperatures if their partitioning behaviour can be determined. To quantify the partitioning and isotope fractionation factor of V between magnetite and melt, piston cylinder experiments were performed in which magnetite and a hydrous, haplogranitic melt were equilibrated at 800 °C and 0.5 GPa over a range of oxygen fugacities (\({f_{{{\text{O}}_{\text{2}}}}}\)), bracketing those of terrestrial magmas. Magnetite is isotopically light with respect to the coexisting melt, a tendency ascribed to the VI-fold V³⁺ and V⁴⁺ in magnetite, and a mixture of IV- and VI-fold V⁵⁺ and V⁴⁺ in the melt. The magnitude of the fractionation factor systematically increases with increasing log\({f_{{{\text{O}}_{\text{2}}}}}\) relative to the Fayalite–Magnetite–Quartz buffer (FMQ), from ?⁵¹V_mag-gl = ? 0.63?±?0.09‰ at FMQ ? 1 to ? 0.92?±?0.11‰ (SD) at ≈?FMQ?+?5, reflecting constant V³⁺/V⁴⁺ in magnetite but increasing V⁵⁺/V⁴⁺ in the melt with increasing log\({f_{{{\text{O}}_{\text{2}}}}}\). These first mineral-melt measurements of V isotope fractionation factors underline the importance of both oxidation state and co-ordination environment in controlling isotopic fractionation. The fractionation factors determined experimentally are in excellent agreement with those needed to explain natural isotope variations in magmatic suites. Furthermore, these experiments provide a useful framework in which to interpret vanadium isotope variations in natural rocks and magnetites, and may be used as a potential fingerprint the redox state of the magma from which they crystallise.     

The right to say: the development of youth councils/forums within the UK

Summary Article 12 of the United Nations Convention on the Rights of the Child makes explicit reference to children's right to say what they think about matters relating to the quality of their lives, and to have those opinions taken into account in accordance with their levels of competence and maturity. Despite the commitment of the UK Government to this and other similar initiatives designed to empower young people, a culture of non-participation is endemic within the UK in the context of environmental planning. Young people are seemingly invisible on the landscape. This paper reviews the case for children's active involvement in their environmental future and considers attempts to engage young people through an incipient structure of youth councils and forums.     

The inception and early evolution of the North Alpine Foreland Basin, Switzerland

The stratigraphy of the Eocene-Miocene peripheral foreland basin in Switzerland consists of basal deposits of Nummulitic Limestones and Globigerina Marls representing a phase of deepening, followed by two shallowing-up megacycles culminating in fully continental sedimentation. The onset of sedimentation was diachronous and took place on an unconformity surface with increasing stratigraphic gap to the north and west. In the Ultrahelvetic units, which were derived from the south and have a provenance between the Helvetic shelf and the Penninic ocean, the stratigraphic gap is minimal. This restricts the initiation of erosion of the southern European margin due to emersion to post-Maastrichtian and pre-late Palaeocene. This coincides with the final closing of the Valais trough and may therefore be interpreted as the point at which continental flexure s. s. started. In the autochthon, the subcrop map of the unconformity surface shows that the regional pattern of subcropping units is oblique to both neo-Alpine tectonic structures and Helvetic (Mesozoic) passive margin structures. There are local zones of disruption to the broad regional pattern suggesting that the basal unconformity was corrugated. Both the paliaspastic restoration of the autochthon relative to the thrust front during the Palaeocene, and the regional pattern of erosion indicate that the basal unconformity may be due to erosion of a flexural forebulge. Following deposition of the shallow water Nummulitic Limestones and the deeper water Globigerina Marls, clastic sediments were shed from the orogenic wedge in the south. These turbidites, the Taveyannaz Sandstones, filled both ponded basins at the contemporaneous thrust front and the frontal trench or foredeep. Evidently, early thrusts drove at a shallow level into the embryonic basin as ‘front-runners’, whereas most shortening and uplift continued to take place within the main part of the orogenic wedge further to the south. Eventually, the frontal palaeohighs, together with the turbidite basins, were buried by the northward emplacement of surface mud-slides, and sediment depocentres were translated northwards onto the foreland. The most likely cause of the underfilled ‘Flysch’ stage is the rapid advance of a submarine thrust wedge over the flexed European plate which resulted in (i) low sediment fluxes and (ii) high subsidence rates associated with the rapid migration of the load and depocentre. Later, as the rate of advance slowed and the wedge became subaerially exposed, the basin rapidly filled with coarse-grained detritus representing the ‘Molasse’ stage.     

Microphytobenthos: The ecological role of the “secret garden” of unvegetated,shallow-water marine habitats. II. role in sediment stability and shallow-water food webs

The microphytobenthos form an important component of all shallow-water ecosystems where enough light reaches the sediment surface to support appreciable primary production. Although less conspicuous than macroalgae or vascular plants, the microphytobenthos can contribute significantly to primary production and can modify habitat characteristics. The microphytobenthos alter sediment properties (e.g., erodibility) both directly, in the extreme forming a mat or scum on the sediment surface, and indirectly by modifying the activities of benthic infauna (e.g., pelletization, burrowing, tube building, and sediment tracking). Carbon dioxide fixed by the microphytobenthos supports higher, grazing trophic levels. These include deposit-feeding and suspension-feeding macrofauna as well as meiofauna and microfauna. Quantitative relations between the feeding and growth rates of macrofauna and the abundance of microphytobenthos and suspended organic matter (i.e., functional responses) are reviewed. Given the current state of knowledge of the direct and indirect interactions involving trophic dynamics, sediment properties, and benthic microalgae, we argue for reductionist studies of particular interactions as distinct entities. This is a prerequisite for the emergence of a comprehensive picture of unvegetated ecosystems and the ability to predict their responses to man’s activities. *** DIRECT SUPPORT *** A01BY074 00005