A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.     

A field comparison of two methods for the determination of copper complexation: Bacterial bioassay and fixed-potential amperometry

Complexation of copper added to seawater was determined by bacterial bioassay and fixedpotential amperometry. Consistent results were obtained by these two fundamentally different methods. The results of this study support the validity of both techniques and the field applicability of fixed-potential amperometry.The intercomparison studies were performed on samples collected at the N.Y.C. sewage sludge dumpsite and in relatively unpolluted coastal waters. In this limited study, the calculated free cupric ion concentrations at ambient total copper concentrations were similar at both sites.     

An experimental study on the shallow-level migmatization of ferrogabbros from the Fuerteventura Basal Complex, Canary Islands

Spectacular shallow-level migmatization of ferrogabbroic rocks occurs in a metamorphic contact aureole of a gabbroic pluton of the Tierra Mala massif (TM) on Fuerteventura (Canary Islands). In order to improve our knowledge of the low pressure melting behavior of gabbroic rocks and to constrain the conditions of migmatization of the TM gabbros, we performed partial melting experiments on a natural ferrogabbro, which is assumed as protolith of the migmatites. The experiments were performed in an internally heated pressure vessel (IHPV) at 200 MPa, 930–1150 °C at relatively oxidizing conditions. Distinct amounts of water were added to the charge.

From 930 to 1000 °C, the observed experimental phases are plagioclase (An_60–70), clinopyroxene, amphibole (titanian magnesiohastingsites), two Fe–Ti oxides, and a basaltic, K-poor melt. Above 1000 °C, amphibole is no longer stable. The first melts are very rich in normative plagioclase (>70 wt.%). This indicates that at the beginning of partial melting plagioclase is the major phase which is consumed to produce melt. In the experiments, plagioclase is stable up to high temperatures (1060 °C) showing increasing An content with temperature. This is not compatible with the natural migmatites, in which An-rich plagioclase is absent in the melanosomes, while amphibole is stable. Our results show that the partial melting of the natural rocks cannot be regarded as an “in-situ” process that occurred in a closed system. Considerable amounts of alkalis probably transported by water-rich fluids, derived from the mafic pluton underplating the TM gabbro, were necessary to drive the melting reaction out of the stability range of plagioclase. A partial melting experiment with a migmatite gabbro showing typical “in-situ” textures as starting material supports this assumption.

Crystallization experiments performed at 1000 °C on a glass of the fused ferrogabbro with different water contents added to the charge show that generally high water activities could be achieved (crystallization of amphibole), independently of the bulk water content, even in a system with very low initial bulk water content (0.3 wt.%). Increasing water contents produce plagioclase richer in An, reduces the modal proportion of plagioclase in the crystallizing assemblage and extends the melt fraction. High melt fractions of >30 wt.% could only be observed in systems with high bulk water contents (>2 wt.%). This indicates that the migmatites were generated under water-rich conditions (probably water-saturated), since those migmatites, which are characterized as “in-situ” formations, show generally high amounts of leucosomes (>30 wt.%).     

小型激光天文动力学空间计划概念

小型激光天文动力学空间计划是 :使用在太阳轨道上无拖曳航天器和地面站以激光干涉和脉冲测距的方法 ,精确地探讨天文动力学 ,检测相对论与时空基本定律 ,改进探测引力波的灵敏度以及更准确地测定太阳、行星和小行星的参数。 1 969年开始的月球激光 (反射 )测距 ,对地球物理、参考坐标的选定、相对论的检验均有重要的贡献。 3 0年来 ,激光技术的长足进步 ,使现在正是适合于开始进行研究空间有源 (主动 )测距和光波空间通讯的时候。激光天文动力学的兴起是必然的趋势 ,其精确度将比现在提高 3到 6个数量级 ,将是天文动力学革命性的发展。小型激光天文动力学空间计划可以起到带头作用。它的关键技术有三 ,即 :弱光锁相、极精确无拖曳航天和高衰减日冕仪。弱光锁相已有长足的进步。对高衰减日冕仪的研究 ,也有了初步的方案。LISA空间计划将于 2 0 0 6年 8月发射SMART -2 ,研究测试极精确无拖曳航天。小型激光天文动力学空间计划的关键技术已日趋成熟。在第一届国际激光天文动力学研讨会 ( 2 0 0 1 ,9.1 3 -2 3 )中介绍了各相关学科背景及前沿研究 ,讨论了激光天文动力学空间计划科学目标及相关技术 ,并召开了两次小型激光天文动力学空间计划预研究筹备会 ,建立了和欧洲的合作关系。会后着手进行此项对基础     

Radiation pressure and dust particle dynamics

The dynamics of small dust grains orbiting a planet are investigated when solar radiation pressure forces are added to the planet's gravitational central field. In the first part a set of differential equations is derived in a reference frame linked to the solar motion. The complete solution of these equations is given for particles lying in the planet's orbital plane, and we show that the orbital eccentricity may undergo considerable variation. At the same time the pericenter longitude librates or circulates according to initial conditions. With this result we establish a criterion for any orbiting particle (because of its highly eccentric orbit) to collide with its planet's atmosphere. The case of inclined orbit is studied through a numerical integration and allows us to draw conclusions related to the stability of the orbital plane. All solutions are periodic, with the period being independent of the initial conditions. This last point permits us to investigate the different time scales involved in that problem. Finally, the Poynting-Robertson drag is included, along with the radial radiation pressure forces, and the secular trend is considered. A coupling effect between the two components is ascertained, yielding a systematic behavior in the eccentricity and thus in the pericenter distance. Our solutions generalize the results of S. J. Peale (1966, J. Geophys. Res.71, 911–933) and J. A. Burns, P. Lamy, and S. Soter (1979, Icarus40, 1–48) by allowing eccentricities to be large (of order 1) and inclinations to be nonzero and by considering Poynting-Robertson drag.     

Seeing Conditions at Sutherland. Results of the 1992/93 seeing campaign

In order to decide whether the seeing conditions at SAAO/Sutherland justify the erection of a 3.5 m telescope and also to compare Sutherland with the Gamsberg/Namibia site, a seeing campaign covering 15 months has been carried out. For direct comparison with the results of the seeing campaign at Gamsberg twenty years before the same QUESTAR telescope was employed. The seeing is determined by the scattering of the star-trail exposed on a film in the focal plane of the telescope. The campaign commenced in February 1992. Up to May 1993, data for 204 nights, that is 47.3% of the total number of nights, were collected. Due to wind speeds above 30 km h^-1, 25 out of the 204 nights were not considered in the final reduction. The useful 179 nights are evenly distributed over the campaign period. The median seeing value for the whole period is = 0.52. There are differences during the year: the best season gives = 0.42, the worst = 0.67. Each night was divided into three intervals, although data for each of the three intervals were not always available. Generally, there is an improvement in the seeing during the course of a night. The results are compared to the seeing values of Gamsberg/Namibia and ESO/La Silla.     

Intermittent generation of mafic enclaves in the 1991–1995 dacite of Unzen Volcano recorded in mineral chemistry

Mafic enclaves in the 1991–1995 dacite of Unzen volcano show chemical and textural variability, such as bulk SiO₂ contents ranging from 52 to 62 wt% and fine- to coarse-grained microlite textures. In this paper, we investigated the mineral chemistry of plagioclase and hornblende microlites and distinguished three enclave types. Type-I mafic enclaves contain high-Mg plagioclase and low-Cl hornblende as microlites, whereas type-III enclaves include low-Mg plagioclase and high-Cl hornblende. Type-II enclaves have an intermediate mineral chemistry. Type-I mafic enclaves tend to show a finer-grained matrix, have slightly higher bulk rock SiO₂ contents (56–60 wt%) when compared with the type-III mafic enclaves (SiO₂?=?53–59 wt%), but the overall bulk enclave compositions are within the trend of the basalt–dacite eruptive products of Quaternary monogenetic volcanoes around Unzen volcano. The origin of the variation of mineral chemistry in mafic enclaves is interpreted to reflect different degree of diffusion-controlled re-equilibration of minerals in a low-temperature mushy dacitic magma reservoir. Mafic enclaves with a long residence time in the dacitic magma reservoir, whose constituent minerals were annealed at low-temperature to be in equililbrium with the rhyolitic melt, represent type-III enclaves. In contrast, type-I mafic enclaves result from recent mafic injections with a mineral assemblage that still retains the high-temperature mineral chemistry. Taking temperature, Ca/(Ca?+?Na) ratio of plagioclase, and water activity of the hydrous Unzen magma into account, the Mg contents of plagioclase indicate that plagioclase microlites in type-III enclaves initially crystallized at high temperature and were subsequently re-equilibrated at low-temperature conditions. Compositional profiles of Mg in plagioclase suggest that older mafic enclaves (Type-III) had a residence time of ~100 years at 800 °C in a stagnant magma reservoir before their incorporation into the mixed dacite of the 1991–1995 Unzen eruption. Presence of different types of mafic enclaves suggests that the 1991–1995 dacite of Unzen volcano tapped mushy magma reservoir intermittently replenished by high-temperature mafic magmas.     

Etude des Déformations et Inclinaisons du Sous-sol: Développements Instrumentaux et Applications dans la Région Sismique d’Arette,France

We present a modified version of a tilt and strain meter conceived to have great sensibility and good stability. These instruments were deployed in a cave at the seismic Pyrenean region of Arette (France). We set in evidence several types of phenomena, of which deformations brought about by water recharge filling up fissures on the massif are of importance. Owing to the redundance in the data, the study of the co-seismic deformations allows one to separate instrumental displacements and local readjustments from regional motions.