苯部分加氢催化剂失活原因的研究

探讨了环己醇装置苯部分加氢催化剂失活的原因，分析了失活机理，并结合实例——母液置换法解决催化剂的氮化物中毒。     

卤素置换反应用氯化锌催化剂的再生

研究了用于催化卤素置换反应后的氯化锌催化剂的再生方法。其过程包括：用石灰乳中和，沉淀出氢氧化锌，用氢氧化锌中和氯化锌废液至pH值为5—6，通入氯气氧化氯化锌废液中的有机物，蒸发至必要的浓度。     

Water‐soluble/dispersible cationic pressure‐sensitive adhesives. I. Adhesives from solution polymerization

Pressure‐sensitive adhesives (PSAs) have long been a problem as sticky contaminants for paper recycling mills. The main problem associated with such stickies is that the PSAs in the waste papers deposit on the felts, press rolls, and drying cylinders of paper machines, and this creates problems with paper formation, reducing the paper quality and paper machine runnability. The annual cost of stickies to the U.S. paper industry is estimated to be about $600,000,000–650,000,000. To solve this problem, a series of cationic water‐soluble/dispersible PSAs have been synthesized by the free‐radical solution polymerization of butyl acrylate and [3‐(methacryloylamino)propyl]trimethylammonium chloride in ethanol. The PSA end‐use properties, repulpability in paper recycling, and the effects on the properties of recycled paper products have been studied. The cationic PSAs can be dissolved or dispersed in water if the cationic charge density in the PSA backbone is controlled, and so they do not deposit as stickies during recycling and papermaking processes. Because the PSAs are cationically charged, they can easily be removed from the papermaking system by adsorption onto the negatively charged fibers and fine surfaces. Furthermore, the adsorbed colloidal or dissolved PSAs have little effect on the final paper properties. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1624–1630, 2003     

Phase equilibria of quasi-binary systems consisting of multicomponent polymers 1 and 2. IV: Poly(ethylene oxide)/poly(propylene oxide) systems

To confirm the reliability of the theory of phase equibria of multicomponent polymer 1/multicomponent polymer 2 systems (i.e. quasi-binary systems) and the method of computer experiment based on this theory (Brit. Polym. J., 23 (1990)285; 23 (1990)299; Polym. Int., 29 (1992)219), could point curves (CPC), two-phase volume ratios ( R ) and critical solution points (CSP) have been determined experimentally for the quasi-binary mixtures of poly(ethylene oxide) (M¯_w = 647, M¯_w/M¯_n = 1.15; M¯_w and M¯_n, the weight-average and numberaverage molecular weights, respectively) and poly(propylene oxide) (M¯_w = 2028, M¯_w/M¯_n = 1.08; and M_w = 2987, M_w/M_n = 1.13). The hydroxyl end groups of both polymers were methoxylated in advance by the Cooper & Booth method (Polymer, 18 (1977)164). The thermodynamic interaction parameter between both polymers, χ₁₂, and the concentration dependence parameters for the above quasi-binary systems were determined by the method proposed in a previous paper (Brit. Polym. J., 23 (1990)299). CPC, R and CSP values calculated on the basis of the theory are in good agreement with the values determined experimentally.     

TRVs and fault clearing stresses in extra-high-voltage radial networks

To cope with the high rate of increase of power demand in the main industrialized districts in Japan, 550-kV transmission systems covering the districts have been reinforced, with most of the main power plants connected directly to these systems. Through 550-/300-kV substations, the majority of power to the districts is supplied by 300-kV systems. To limit the excess short-circuit capacity in the 300-kV systems, they tend to be reconstructed as so-called radial networks. In radial networks with high short-circuit capacity and relatively small number of transmission lines connected to the substation busbars, the rate of rise of TRV can be far higher than standard value. This paper analyzes the transient recovery voltages (TRV) in such extra-high-voltage radial networks in Japan, together with the relevant stresses to circuit-breakers during fault clearings. Future system conditions have also been introduced. As the typical rate of rise of the TRV values, more than twice that of today's standard ones are probable.     

Synthesizing plans that contain actions with context-dependent effects1

This paper presents a method of solving planning problems that involve actions whose effects change according to the situations in which they are performed. The approach is an extension of the conventional planning methodology in which plans are constructed through an iterative process of scanning for goals that are not yet satisfied, inserting actions to achieve them, and introducing subgoals to these actions. This methodology was originally developed under the assumption that one would be dealing exclusively with actions that produce the same effects in every situation. The extension involves introducing additional subgoals to actions above and beyond the preconditions of execution normally introduced. These additional subgoals, called secondary preconditions, ensure that the actions are performed in contexts conducive to producing the effects we desire. This paper defines and analyzes secondary preconditions from a mathematically rigorous standpoint and demonstrates how they can be derived from regression operators.     

基于AutoCAD2000的图解法确定工艺转角

提出了基于AutoCAD2 0 0 0的图解法求解机械加工过程中工艺转角的问题 ,并针对具体的应用实例给出了圆满的解答 ,并验证了其精度。     

Boussinesq方程的永形波的级数解

对于用层平均速度势(或速度)与波高给出的非线性等水深Boussinesq方程,与KdV方程一样,存在两类永形波—孤立波和周期波。不同的是,对于Boussinesq方程,孤立波和周期波一样,是以反函数的积分形式给出的,这在使用上是不方便的。本文对这两类波,分别给出了相应的级数形式的正函数解。对于孤立波,级数的收敛速度是十分快的,且文中还给出了一个具有高精度的十分简单的近似解,对于周期波,只要有关参数选得合适,解的收敛速度也是相当快的。这就有效地克服了反函数形式解在使用上的不方便。     

痕量分析中金溶液的稳定性

评述了痕量分析中,金标准溶液和天然水试样中痕量金贮存的稳定性及影响贮存的重要因素,提出了标准溶液配制和贮存的方法。     

发电机同轴励磁机电刷火花过大的原因及处理方法

本文对发电机同轴励磁机电刷火花过大的原因进行了分析．并针对这些原因提出了相应的处理办法。对规范励磁机的运行维护有很大的帮助。