C8芳烃异构体+叔丁醇体系在12.666kPa下的汽液平衡

采用CP-I型汽液平衡双循环釜，测定了12．666kPa压力下叔丁醇 乙苯、叔丁醇 o-二甲苯、叔丁醇 m-二甲苯、叔丁醇 p-二甲苯4个体系的汽液平衡数据，计算了该压力下4个体系中各组分的活度系数。并对所测数据进行了恒压下热力学一致性检验。用Wilson方程关联了实验数据，拟合精度令人满意。     

The Rule of Interfacial Equilibrium

The detailed analysis of the well-known relation γ₁₂ = γ₁ -γ₂ has been done (γ₁₂, γ₁ and γ₂ are interfacial and surface tensions of phases 1 and 2). The analysis of equilibrium of a liquid drop at the interface with another liquid allowed us to prove that this relation should be modified by including in it the value γ₂* which is considered as the result of all interactions at the interface and is accepted depending on γ₁. The value γ₂* represents the surface tension of a phase in the ternary point solid-liquid-gas, i.e. in the zone of interfacial nonuniformity. The modified form of the relation, called the rule of interfacial equilibrium, allows us to show that thermodynamic work of adhesion is equal to the cohesion energy of the interphase formed by phase 2.     

Interpolymer‐specific interactions and miscibility in poly(styrene‐co‐acrylic acid)/poly(styrene‐co‐N,N‐dimethylacrylamide) blends

The miscibility or complexation of poly(styrene‐co‐acrylic acid) containing 27 mol % of acrylic acid (SAA‐27) and poly(styrene‐co‐N,N‐dimethylacrylamide) containing 17 or 32 mol % of N,N‐dimethylacrylamide (SAD‐17, SAD‐32) or poly(N,N‐dimethylacrylamide) (PDMA) were investigated by different techniques. The differential scanning calorimetry (DSC) analysis showed that a single glass‐transition temperature was observed for all the mixtures prepared from tetrahydrofuran (THF) or butan‐2‐one. This is an evidence of their miscibility or complexation over the entire composition range. As the content of the basic constituent increases as within SAA‐27/SAD‐32 and SAA‐27/PDMA, higher number of specific interpolymer interactins occurred and led to the formation of interpolymer complexes in butan‐2‐one. The qualitative Fourier transform infrared (FTIR) spectroscopy study carried out for SAA‐27/SAD‐17 blends revealed that hydrogen bonding occurred between the hydroxyl groups of SAA‐27 and the carbonyl amide of SAD‐17. Quantitative analysis carried out in the 160–210°C temperature range for the SAA‐27 copolymer and its blends of different ratios using the Painter–Coleman association model led to the estimation of the equilibrium constants K₂, K_A and the enthalpies of hydrogen bond formation. These blends are miscible even at 180°C as confirmed from the negative values of the total free energy of mixing ΔG_M over the entire blend composition. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 1011–1024, 2007     

无线传感器网络中能耗问题的探讨

无线传感器网络中传感节点能量消耗不均衡将导致整个网络过早地失效。文章在LEACH层次路由算法的基础上,提出了自动退避的簇头竞争选择机制、设定阀值的数据融合和基于能量感知的多路径策略,并在网络均衡、能量消耗方面做了优化,极大地提高了传感节点的服务寿命,延长了整个网络的生存周期。     

On Dynamics and Nash Equilibriums of Networked Games

Networked noncooperative games are investigated, where each player (or agent) plays with all other players in its neighborhood. Assume the evolution is based on the fact that each player uses its neighbors' current information to decide its next strategy. By using sub-neighborhood, the dynamics of the evolution is obtained. Then a method for calculating Nash equilibriums from mixed strategies of multi-players is proposed. The relationship between local Nash equilibriums based on individual neighborhoods and global Nash equilibriums of overall network is revealed. Then a technique is proposed to construct Nash equilibriums of an evolutionary game from its one step static Nash equilibriums. The basic tool of this approach is the semi-tensor product of matrices, which converts strategies into logical matrices and payoffs into pseudo-Boolean functions, then networked evolutionary games become discrete time dynamic systems.      

EFFECTS OF ENTRAINERS ON THE PHASE EQUILIBRIUM OF SUPERCRITICAL FLUID EXTRACTION PROCESS

A flow apparatus was set up for measuring the solubility of a solid solute in a supercritical fluid withthe presence of a small amount of entrainer.The solubilities of biphenyl,diphenylamine and benzoic acid insupercritical carbon dioxide with one of the selected entrainers which were ethanol,acetone and n-hexanerespectively,were obtained in the pressure range of 10—32 MPa and the temperature range of 308—318K.Asolvolytic association theory has been proposed to explain the mechanism of entrainer effect,and theexperimental results were reasonably analysed.According to the solvolytic association theory,the association equa-tion of state was adopted to correlate the experimental data with good accuracy.     

基于一般相位结构的区域信号配时二层规划模型与算法

基于城市道路交叉口的一般信号相位结构,根据各相位车流在交叉口遭遇不同信号延误的特点,建立了一个新的区域信号配时二层规划模型.该模型的上层问题,是一个明确考虑了交叉口信号延误的区域信号配时优化模型,而下层是随机用户平衡交通分配模型.针对这类问题的特点,应用灵敏度分析方法、信赖域方法和作者提出的仿射尺度内点算法,构建了一类新算法的基本框架.由于仿射尺度内点算法收敛速度快,而信赖域算法可以避免相当耗费的一维搜索,使得该算法具有较为优越的整体计算性能.     

考虑交叉口信号延误的平衡交通分配模型

针对具有一般信号相位结构的道路交通网络,通过对交叉口处道路交通流按相位分解,将车辆的信号延误耦合到交通分配问题中,相继建立了带有交叉口延误的确定性用户平衡分配和随机用户平衡分配问题的数学规划模型.通过对两个模型的一阶最优性条件的分析,证明了它们的最优解分别满足广义交通平衡分配问题(即同时考虑交叉口信号延误和路段拥挤延误)的Wardrop用户平衡条件和Logit分配准则.     

回归分析在地源热泵系统地温场研究中的应用

利用地下水地源热泵系统运行期间监测到的地温数据,通过多元回归分析方法拟合出取水井附近、回灌井附近、中间过渡区域平均地温变化曲线,初步查明该系统冷热源在制冷期、采暖期及运行停歇期的地温变化特征,并对地温场年度热平衡情况进行了初步分析,为系统节能运行和改进提供了理论根据。     

一类SARS传染病模型的稳定性分析

在现有模型的基础上,进一步将人群分为六个仓室并考虑易感人群的密度制约以及患病者类的死亡率与治愈率等因素,建立了描述SARS传染病的一个新的动力学模型．证明了该模型的疾病消除平衡点在一定条件下是全局渐近稳定的,而地方病平衡点不是渐近稳定的,同时得到了该模型在适当的条件下为永久持续生存的结果．