溶质在多苯基溶剂中的溶解热力学性质测量

用改装了层析室的国产１０２Ｇ型气相色谱仪，在全部实验范围内水浴控温精度为士０．０１℃，用气液色谱法测量了环烷烃、环烯烃及芳烃分别在二苯甲烷、二苄醚、对苄基联苯、二苯亚矾四个溶剂构成的二十九个二元液系不同温度下的比保留体积值，计算了溶质溶解溶剂的溶解焓△Ｈ°ｓ，溶解吉布斯自由能△Ｇ°ｓ，溶解熵△Ｓ°ｓ的值，并用△Ｈ°ｓ的测量值与文献值［１］［２］对分子间的相互作用作了讨论。     

基于最大熵快速迭代算法和边缘算子的织物疵点分割

将信息熵引入图像处理中,把疵点图像分为背景和目标两部分,分别对两个区域进行处理;通过求最大熵值的快速迭代算法,在满足信息熵最大要求的前提下对织物疵点区域进行分割,然后利用Canny边缘检测算子对分割后的疵点图像进行边缘检测,从而达到识别织物疵点的目的。仿真实验结果表明,将最大熵快速迭代算法与边缘算子结合进行疵点分割识别的方法是有效的。     

Numerical investigation on the mechanism of impeller hub corner separation flow and induced energy loss in the bulb tubular pump

Impeller hub corner separation flow(IHCS)has a significant influence on energy conversion of the bulb tubular pump,and its unsteady characteristics are investigated with CFD-based method.The generation mechanism and power loss characteristics of IHCS are investigated by the entropy production method and pressure fluctuation analysis.The main cause can be attributed to the large transverse pressure gradient near the hub at the trailing edge of the impeller,which is aggravated by the circumferential movement trend and the diffuser reverse flow,while the IHCS is significantly weakened with increased flow rate.The undesirable flow behavior is more likely to cause a significant increase in energy loss near the hub region compared to that in the rim region.The relative vortex stretching induced by the velocity gradient is the main cause of the horn-like vortex(HLV),and its intensity and resulting energy loss tend to decrease along the vortex trajectory.The HLV changes the dominant frequency of the pressure fluctuations in the nearby flow field,the value of which increases from 1 fr(the blade passing frequency)to 2 fr with increased amplitude,mainly due to the lower pressure regions on the impeller suction surface(SS)and HLV vortex core.Due to the effect of rotor-stator interaction(RSI),the HLVs generated between two adjacent impeller blades are cut into several sections by the diffuser vanes and propagate and dissipate along the mainstream direction.     

关于解(eu/et)=a(eu/ex2)的差分格式

对于热传导方程给出了两个高精度差分格式,一个是显格式,稳定条件为0＜r＜1－6.另一个是绝对稳定的隐格式．     

生产资源组织模式结构与运行评价的熵测度法

针对不同生产资源组织模式的结构与运行状态的差异,目前尚缺乏系统的定量评价方法.基于信息熵理论及有序度定义,建立了结构熵模型与运行熵模型来分别评价生产资源组织模式在结构上和运行中的有序度.其中,结构熵模型包括时效熵和质量熵两部分;运行熵模型包括静态运行熵和动态运行熵两部分.对某压缩机制造企业的加工车间做了实例研究,以实施动态单元组织模式前后的结构与运行状态作对比分析,分别求解出2种不同模式下的结构熵与运行熵.结果表明,动态单元组织模式通过合理规划人力、设备资源及生产流程,能够极大减少企业生产中零件的转运与设备空闲时间,具有更优的结构有序度和运行有序度、能获得更好的零件加工效率.     

XZY-73型摇床差动特性的研究

根据实测的振动位移曲线,利用谐和分析及近似积分法,对XZY-73型实验型摇床的差动特性进行了研究,由程序计算获得了综合差动特性参数,为研究和评价该摇床的差动效率提供了一定的依据。     

基于耐久性评定的钢筋混凝土结构的剩余寿命预测

本文着意建立一套钢筋混凝土结构耐久性的评定方法,这一方法提供了一套客观、公正地分析和处理现场检测数据的手段并有助于评定者选择合适的评定指标,从而可以得到结构的性能状况及剩余寿命。这一方法将结构的耐久性分为恶化程度和恶化速度两项评定;利用Ｓａａｔｙ１－９比率标度法将专家根据主观经验所得的判断信息进行客观、科学地量化;采用熵的性质,使多指标评定体系的固有信息与专家经验判断量化的主观信息相结合,解决了各     

基于熵权法—灰色评价法的炼化低温热利用技术评估研究

将熵权法与灰色综合评价法相集成,形成了用于评价炼化低温热利用技术的新方法。该方法在低温热利用技术评价指标体系的基础上,利用熵权法获得指标权重,并通过求取灰色关联度建立了炼化低温热利用技术评价模型,减少了人为主观认识对评价结果的影响,使评价结果更加客观和具有指导性。通过实际案例,给出了该模型的计算流程及评价方法。     

Damage characterization in non-isothermal stretching of acrylics. Part II: Experimental validation

Influence of temperature and strain rate on damage accumulation and large deformation behavior of acrylics was investigated under conditions similar to actual polymer processing. Poly(methyl methacrylate) (PMMA) samples were stretched to large strains at different rates under transient thermal conditions. During testing, specimens were cooled down from temperatures above glass transition temperature (θ_g) to temperatures well-below θ_g inducing a transition from rubbery state to solid state. Contrary to common practice of studying thermo-mechanical coupling in terms of adiabatic heating; in proposed experimental study, temperature effect on mechanical response of material was emphasized by externally intervening temperature variation within specimen. An improved version of dual-mechanism constitutive model presented in Part I [Gunel, E.M., Basaran, C., 2010. Damage characterization in non-isothermal stretching of acrylics. Part I: Theory. Mechanics of Materials] was proposed to predict thermo-mechanical response of amorphous polymer below and above θ_g. Applicability of proposed constitutive model for the specific case of non-isothermal stretching of PMMA at different test conditions was demonstrated by incorporating it into a finite element scheme. Constitutive model was reasonably accurate to capture observed temperature-displacement-force history in experimental study. Damage evolution under different testing conditions was studied in terms of irreversible thermal and mechanical entropy production.