尿素设备腐蚀的影响因素及防腐措施

从温度、氨碳比、水碳比、甲铵液浓度、氧含量、硫含量、氯离子含量、介质流速等方面论述了尿素设备腐蚀的影响因素;提出了在正常生产和停车封塔情况下的防腐控制措施。     

Foliar fertilization of high-yielding peanuts during the pod-filling period

A 2-year field experiment was carried out in a sandy soil (Xeropsament-Torripsament) at Nir Yizhaq, Israel, where commercially grown peanut plants were sprayed with different NPKS solutions during the pod-filling period. All foliar sprays were applied in addition to the fertilizer which had been added to the soil before planting. The differences in yield between the treatments were not significant in either year. In the first year, there was a tendency toward increased yields of pods (up to 13%) and of hay (up to 16%) when four foliar fertilizer applications (10 kg N, 1 kg P, 3 kg K and 0.5 kg S/ha/application) were given, at one-week intervals. N was added mainly as urea, P and K as potassium polyphosphate, and S as ammonium sulphate. In the second year, the highest yield was obtained in the control plots and the differences between the treatments were not significant. Utilization of foliar nutrient application seems to be dependent upon availability of these nutrients in the soil.Contribution from the Agricultural Research Organization, The Volcani Center, Bet Dagan, Israel. No. 1976-E. 1087 series.     

锐钛型TiO2对尿素热解过程的影响

通过实验的方法收集了不同温度下纯尿素和尿素/TiO₂混合物热解后的固体残留物，使用红外光谱（IR）及气相色谱质谱联机（GC-MS）方法对这些热解残留物进行成分分析；使用热重-红外联机（TG-FTIR）技术研究尿素及三聚氰酸在有无催化剂TiO₂的情况下的热解特性及气体产物的生成规律；根据Coats-Renfern方法对尿素热解第一阶段的非等温热失重率曲线的数据进行动力学研究，建立动力学方程。结果表明，100~250℃的尿素热解残留物中主要为尿素和缩二脲，300~400℃的尿素热解残留物中主要为三聚氰酸等含氮杂环有机化合物；锐钛型TiO₂能促进尿素和三聚氰酸的热解反应，缩短其反应进程，HNCO与水蒸气在TiO₂表面易发生反应；尿素第一阶段热解的反应级数为2，单独热解时活化能为113.25kJ/mol，指前因子A为2.01×10¹¹min^-1，在催化剂TiO₂的作用下，活化能E为77.42kJ/mol，指前因子A为4.82×10⁷min^-1。     

新型包膜尿素的制备及其特性的研究

以桐油为主要成膜物质制备新型包膜尿素。研究结果表明，包膜后尿素颗粒的粒径分布更加均匀，有外密封层时可在包膜尿素表面形成连续致密的包膜，包膜尿素因之获得逐步释放特性。使用溶解率和无土柱淋溶率可以评价包膜尿素的养份释放特性。     

Eicosapentaenoic acid (20∶5n-3) from the marine microalgaPhaeodactylum tricornutum

Eicosapentaenoic acid (EPA, 20∶5n-3) was obtained from the marine microalgaePhaeodactylum tricornutum by a three-step process: fatty acid extraction by direct saponification of biomass, polyunsaturated fatty acid (PUFA) concentration by formation of urea inclusion compounds, and EPA isolation by semipreparative high-performance liquid chromatography (HPLC). Alternatively, EPA was obtained by a similar two-step process without the PUFA concentration step by the urea method. Direct saponification of biomass was carried out with two solvents that contained KOH for lipid saponification. An increase in yield was obtained because the problems associated with emulsion formation were avoided by separating the biomass from the soap solution before adding hexane for extraction of insaponifiables. The most efficient solvent, ethanol (96%) at 60°C for 1 h, extracted 98.3% of EPA. PUFA were concentrated by the urea method with a urea/fatty acid ratio of 4∶1 at a crystallization temperature of 28°C and by using methanol and ethanol as urea solvents. An EPA concentration ratio of 1.73 (55.2∶31.9) and a recover yield of 78.6% were obtained with methanol as the urea solvent. This PUFA concentrate was used to obtain 93.4% pure EPA by semipreparative HPLC with a reverse-phase, C₁₈, 10 mm i.d.×25-cm column and methanol/water (1% acetic acid), 80∶20 w/w, as the mobile phase. Eighty-five percent of EPA loaded was recovered, and 65.7% of EPA present inP. tricornutum biomass was recovered in highly pure form by this three-step downstream process. Alternatively, 93.6% pure EPA was isolated from the fatty acid extract (without the PUFA concentration step) with 100% EPA recovery yield. This two-step process increases the overall EPA yield to 98.3%, but it is only possible to obtain 20% as much EPA as that obtained by three-step downstream processing.     

尿素生产中尿液的不稳定流动对尿素一分塔的影响

介绍了水溶液全循环法尿素生产系统中,一分塔的精馏段由泡罩塔盘改为规整填料后出现的一系列问题,针对尿液的不稳定流动造成一分塔规整填料严重腐蚀的原因,进行分析并提出整改和预防措施。     

尿素嵌入法制备纤维素氨基甲酸酯的研究

探讨了尿素嵌入法制备纤维素氨基甲酸酯(CC)的生产工艺。指出:选用聚合度为450~625、α-纤维素含量大于90/的纤维素浆粕,用14/~16/的氢氧化钠溶液,于40~50℃条件下活化处理30~40min后,与尿素以1∶2~3的比例混合,在137℃的二甲苯体系中反应2~3h,便可得到含氮量为2.4/~3.5/的纤维素氨基甲酸酯产物。该产物在氢氧化钠溶液中可形成良好的稳定溶液,过滤性好,可直接用于纺丝。     

尿素合成塔腐蚀在线监测

简要介绍了尿素合成塔腐蚀在线监测技术、监测仪及其安装、使用情况。     

D.s.c. investigation of the states of water in poly(vinyl alcohol-co-itaconic acid) membranes

The state of water in water-swollen poly(vinyl alcohol-co-itaconic acid) membranes, having various water contents from 0.31 to 0.83, was investigated by d.s.c. measurements and compared with those in water-swollen poly(vinyl alcohol) membranes. The amount of freezing water in the membranes was estimated by use of a relationship between the phase transition temperature and the enthalpy of the crystallization of supercooled water. The melting temperature of the water in the membranes immersed in urea and NaCl 0–2 mol l^?1 aqueous solutions was also determined by d.s.c. analysis. The present study proposes a method for estimating the solubilities of urea and NaCl in both of the freezing and the non-freezing water using the melting point depression of the freezing water in the membranes immersed in the solute solution.     

氨汽提合成塔腐蚀控制探讨

分析尿素合成塔腐蚀机理、类型,并提出防腐蚀的控制方法。