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81.
铝系阻燃剂阻燃PP的力学性能研究 总被引:2,自引:0,他引:2
将用偶联剂处理的碱式碳酸铝镁加入到聚丙烯中,通过对体系阻燃性、力学性能等研究得出:碱式碳酸铝镁能够对聚丙烯起到良好的阻燃效果,碱式碳酸铝镁的加入提高了聚丙烯的冲击强度,当碱式碳酸铝镁质量分数为23%时,体系的冲击强度最高。研究了偶联荆的用量对体系力学性能的影响,结果表明,随偶联荆用量的增加,体系的拉伸强度降低,冲击强度先升高后降低,当偶联荆质量分数为1.0%时,体系的冲击强度最高。 相似文献
82.
83.
Our earlier paper (Jana, S.C.; Prieto, A. J Appl Polym Sci 2002, 86, 2159) on the development of natural fiber composites of high‐performance thermoplastic polymers described a new methodology for the manufacturing of composite materials of a high‐temperature thermoplastic polymer, poly(phenylene ether) (PPE) and wood flour, a cellulosic natural filler. A thermosetting epoxy, used as a reactive solvent, reduced the processing temperature of PPE/epoxy blends to well below the decomposition temperature of natural fillers. In addition, the epoxy component, upon polymerization, formed coating layers around the filler particles to provide resistance against moisture diffusion and attacks by acids and alkali. This article describes the results of an investigation on two outstanding issues: (1) the influence of cellulosic wood particles and coupling agents on the speed of epoxy curing and reaction‐induced phase separation and (2) the effects of coupling agents on the morphology of crosslinked epoxy at the surfaces of natural fillers and mechanical properties of the composites. It was found that wood particles expedited epoxy curing in the composites; the extent of epoxy curing, however, was reduced in the presence of coupling agents. Also, the coupling agents promoted complete coverage of wood flour particles by polymerized epoxy, although the mechanical properties deteriorated over systems without coupling agents. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2168–2173, 2002 相似文献
84.
Isotopic transient techniques were applied to study oxidative coupling of methane over lanthanum oxide and strontium promoted La2O3 catalysts. Results of the18O2/16O2 isotopic exchange experiments indicate that Sr promotion increases oxygen uptake from the lattice of the catalyst. Oxygen self diffusion coefficients, which were determined for the series of lanthana catalysts, reach a maximum for the 1% Sr/La2O3. Steps of18O2 in the presence of a steady flow of methane over Sr/La2O3 catalysts, indicate that surface and bulk oxygen appear in the reaction products before gas-phase18O2. Steps of CO2 over catalysts in which lattice oxygen has been exchanged with18O2, show that gas/solid exchange involves over 50% of the lattice oxygen. Under reaction conditions, methane pulses with no gas-phase oxygen yield negligible amounts of products which indicates that methane interacts with lattice oxygen only in the presence of the gas-phase oxygen. 相似文献
85.
The coupling efficiency of seven coupling agents in wood–polymer composites (WPC) was investigated in this study. The improvement on the interfacial bonding strength, flexural modulus, and other mechanical properties of the resultant wood fiber/high‐density polyethylene (HDPE) composites was mainly related to the coupling agent type, function groups, molecular weight, concentration, and chain structure. As a coupling agent, maleated polyethylene (MAPE) had a better performance in WPC than oxidized polyethylene (OPE) and pure polyethylene (PPE) because of its stronger interfacial bonding. A combination of the acid number, molecular weight, and concentration of coupling agents had a significant effect on the interfacial bonding in WPC. The coupling agents with a high molecular weight, moderate acid number, and low concentration level were preferred to improve interfacial adhesion in WPC. The backbone structure of coupling agents also affected the interfacial bonding strength. Compared with the untreated composites, modified composites improved the interfacial bonding strength by 140% on maximum and the flexural storage modulus by 29%. According to the statistical analysis, 226D and 100D were the best of the seven coupling agents. The coupling agent performance was illustrated with the brush, switch, and amorphous structures. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 93–102, 2005 相似文献
86.
建立了双旋转偏重激振的惯性往复振动机械的状态方程,将该状态方程与两驱动电机的状态方程一起组成机电耦合系统的数学模型,对不同阻尼的机电耦合数学模型进行数值求解,得到不同阻尼时系统的瞬态和稳态解.通过综合分析系统阻尼对最大共振振幅、启动时间、稳态功率消耗及阻尼力的影响,提出了惯性往复振动机械阻尼率的合理设计值为0.1左右. 相似文献
87.
讨论了两个自旋为h/2的电子的能级,本征波函数的求解及粒子处于z轴上的概率问题.通过两种不同的的方法得到了粒子处于z轴负方向上的概率,加深了对耦合表象下两个电子自旋性质的掌握,拓宽了量子力学的理论计算的思路. 相似文献
88.
In order to consider the influence of temperature and stress fields on the migration of radioactive nuclide with underground water movement, an elastoplastic model and a 2D FEM code for analysis of coupled thermo-hydro-mechanical (THM) processes in saturated and unsaturated porous media were extended and improved through introducing the percolation and migration equation, so that the code can be used for solving the temperature field, flow field, stress field and nuclide concentration field simultaneously. The states of temperatures, pore pressures and nuclide concentrations in the near field of a hypothetical nuclear waste repository were investigated. The influence of the half life of the radioactive nuclide on the temporal change of nuclide concentration was analyzed considering the thermo-hydro-mechanical-migratory coupling. The results show that, at the boundary of the vitrified waste, the concentration of radioactive nuclide with a half life of 10 a falls after a period of rising, with the maximum value of 0.182 mol/m3 and the minimum value of 0.181 mol/m3 at the end of computation. For a half life of 1 000 a, the concentration of radioactive nuclide always increases with the increase of the time during the computation period; and the maximum value is 1.686 mol/m3 at the end of the computation. Therefore, under the condition of THM coupling, the concentration of radioactive nuclide with a shorter half life will decrease more quickly with water flow; but for the radioactive nuclide with a longer half life, its concentration will keep at a higher level for a longer time in the migration process. 相似文献
89.
Xiao-xia Li~) Gang Han~) ) Experimental Center College of Science Yanshan University Qinhuangdao China ) School of Materials Science Engineering University of Science Technology Beijing Beijing China 《北京科技大学学报(英文版)》2010,17(2):229-233
The magnetic force microscopy and a sample vibrating magnetometer have been used to investigate the domain structure in two antiferromagnetically coupled Co/Pt multilayers.In the antiferromagnetic coupled[Pt(0.5 nm)/Co(0.4 nm)]_n/NiO(1.1 nm)/[Co(0.4 nm)/Pt(0.5 nm)]_n multilayers with perpendicular anisotropy,the antiferromagnetic interlayer coupling strength increases linearly with the repetition number n in Co/Pt multilayers.In demagnetized states,relatively shifted domain walls in the two Co/Pt multila... 相似文献
90.
首先采用弹性理论对立井井壁进行了分析,建立了井壁破坏的理论模型,进而采用通用有限元软件ANSYS,建立了立井井壁的大型三维分离式有限元数值模型。运用这两种模型详细研究了多种荷载耦合作用对立井井壁的影响,多种荷载包括:随深度变化的土压力、随时间变化的疏水附加力以及井壁自身重量。确定了立井井壁在这三种荷载综合作用下的应力、应变集中区,论证了井壁破坏理论中疏水附加力理论的正确性,对井壁设计理论以及加固区域的确定提供了一定的理论指导。本文有限元模型的建立方法以及得到的结论,在一定程度上丰富了立井井壁理论的内容,增加了立井井壁理论研究的方法,促进了井壁附加应力说的发展。 相似文献