间氟苯基荧光酮—溴化十六烷基吡啶荧光熄灭法测定微量钼（Ⅵ）的研究

研究了间氟苯基荧光酮（m-FPF)与钼（Ⅵ）的反应条件。在0.02-0.10mol/L盐酸溶液中,于表面活性剂溴化十六烷基吡啶（CPB）存在下,MO（Ⅵ）与m-FPF生成络合物使m-FPF荧光熄灭,建立了MO（Ⅵ）-m-FPF-CPB体系测定微量MO（Ⅵ）的荧光分析新方法。荧光熄灭程度与MO（Ⅵ）的含量在0-4.0μg/25mL范围内呈线性关系。应用本法于钢样及水样中微量钼的测定,结果满意。     

Study on l uidity of squeeze cast AZ91D magnesium alloy with dif erent wall thicknesses

Rectangular cross-section specimens with different section thicknesses were prepared to study the infl uences of pouring temperature, mould temperature and squeeze velocity on the fl uidity of squeeze cast AZ91D magnesium alloy by means of orthogonal test design method. The results show that pouring temperature, mould temperature and squeeze velocity can significantly affect the fluidity of magnesium alloy specimens with wall thickness no more than 4 mm, and the pouring temperature is the most infl uential factor on the fl uidity of specimens with wall thickness of 1, 2 and 3 mm, while mould temperature is the one for specimens with wall thickness of 4 mm. Increasing pouring temperature between 700 °C and 750 °C is benefi cial to the fl uidity of AZ91D magnesium alloy, and increasing mould temperature signifi cantly enhances the fi lling ability of thick(3 and 4 mm) section castings. The fl uidity of squeeze cast magnesium alloy increases with the increase of wall thickness. It is not recommended to produce magnesium alloy casting with wall thickness of smaller than 3 mm by squeeze cast process due to the poor fl uidity. The software DPS was used to generate the regression model, and linear regression equations of the fl uidity of squeeze cast AZ91D with different wall thicknesses are obtained using the test results.     

Flow of a micropolar fluid in a micro-channel under the action of an alternating electric field: Estimates of flow in bio-fluidic devices

The paper is devoted to a study of the electro-osmotic flow of a micropolar bio-fluid, when the flow takes place between two plates that are in a state of periodic vibrations. Considering blood as a micropolar fluid, it is found that the amplitude of oscillation of the microparticles of blood increases when the micropolar effect is pronounced more and more and that a rise in DebyeHückel parameter enhances both the velocity and microrotation gradient. The results provide guidelines for the improvement of design of bio-sensing and micro-fluidic devices. The study leads to the conclusion that electrical double layers formed in the vicinity of the wall can significantly alter the flow dynamics of physiological fluids in micro-bio-fluidic devices.     

半滑舌鳎工厂化循环水养殖模式能值评价

为了更好地评价半滑舌鳎(Cynoglossus semilaevis Günther)在工厂化循化水养殖模式下的养殖效果及环境可持续性,运用能值理论及分析方法构建了半滑舌鳎循环水养殖模式能值流程图,并对此养殖模式各能值分布进行分析。结果表明:循环水养殖模式环境能值投入只占比1.08%,能值产出率(EYR)为2.433,环境负载率(ELR)为0.313 4,能值可持续发展指标(ESI)为7.763,表明此种养殖模式已经将农业生产提升至工业化水平,其经济系统发展程度高,生产效率较高;同时该养殖模式极大地减轻了对环境的压力,其可持续性和环境容纳量均较高。     

脂类对反应型香精风味形成影响的研究

根据3种不同原料所含主要脂肪酸及不饱和度的不同,通过反应所生成主要风味物质差异来进一步探讨反应型香精风味形成机理。     

Advanced fluid-typing methods for NMR logging

In recent years,nuclear magnetic resonance(NMR) has been increasingly used for fluidtyping in well-logging because of the improved generations of NMR logging tools.This paper first discusses the applicable conditions of two one-dimensional NMR methods:the dual TW method and dual TE method.Then,the two-dimensional(T2,D) and(T2,T1) NMR methods are introduced.These different typing methods for hydrocarbon are compared and analyzed by numerical simulation.The results show that the dual TW method is not suitable for identifying a macroporous water layer.The dual TE method is not suitable for typing gas and irreducible water.(T2,T1) method is more effective in typing a gas layer.In an oil-bearing layer of movable water containing big pores,(T2,T1) method can solve the misinterpretation problem in the dual TW method between a water layer with big pores and an oil layer.The(T2,T1) method can distinguish irreducible water from oil of a medium viscosity,and the viscosity range of oil becomes wide in contrast with that of the dual TW method.The(T2,D) method is more effective in typing oil and water layers.In a gas layer,when the SNR is higher than a threshold,the(T2,D) method can resolve the overlapping T2 signals of irreducible water and gas that occurs due to the use of the dual TE method.Twodimensional NMR for fluid-typing is an important development of well logging technology.     

乐山-龙女寺古隆起震旦系超深井快速钻井技术

四川盆地乐山-龙女寺古隆起震旦系埋藏深度在5 000～6 000 m,地层可钻性差、纵向上多产层多压力系统等复杂地质条件制约了钻井速度。针对钻井提速难点,重点从井身结构、钻头个性化设计及有机盐钻井液体系等方面进行了攻关研究与现场试验,初步形成了适应该地区的钻井提速技术模式：①优化井身结构,较传统井身结构缩短了大尺寸井眼长度,减少了作业时间,同时又能够满足完井与后期生产作业的要求。②个性化设计PDC钻头,应用效果表明较已完钻井机械钻速提高了31%～473%,在侏罗系沙溪庙组试验刚体PDC钻头平均机械钻速16.57 m/h,已接近空气钻进效果;在适合井段试验等壁厚长寿命螺杆配合PDC钻头复合钻进,机械钻速较常规转盘钻机械钻速提高44%。③配合使用有机盐低固相钻井液,抑制性较聚磺钻井液更强,亚微米粒子含量减少,实现了辅助提高机械钻速的效果,井壁较使用聚磺钻井液的更稳定。2012年完钻的6口深井平均机械钻速由1.69 m/h提高到2.54 m/h,平均钻井周期从302 d 缩短到189 d,实现了该区震旦系超深井的安全快速钻井。     

蠡测漆之由经济作物到工艺思想——以《吕氏春秋》为例

《吕氏春秋》是成书于战国末期的一部集体性著作,其中不乏大漆种植、用漆计划、用漆制度、用漆科学等珍贵农业史料。笔者拟就《吕览》之用漆农业史料为切入对象,并结合出土的战国与秦代时期的漆器,阐释其用漆制度与思想,以期解析战国秦代漆器艺术繁荣背后的经济制度、农业技术与艺术文化等一般性社会发展动力,为古代农业与古典工艺文化的现代转译提供一种农业史与工艺史以外的诠释视角。     

基于原子力显微镜和流变学特性的葛仙米多糖构象分析

通过原子力显微镜观察葛仙米多糖的单分子形态,发现葛仙米多糖包括柔性分支链和刚性分支链,主要以带分支的柔性长链、无分支或分支较少的刚性分支链、3条链缠绕而成的发散结构等形态存在,同时观察到部分分支链的单螺旋结构。葛仙米多糖主要以丰富分支的状态存在,可见螺旋结构,分支长度一般在200~600 nm,单分子直径在1.0 nm以内,在多链缠绕处高度为1.3~2.3 nm左右。流变学特性分析表明,葛仙米多糖能形成弱凝胶体系,说明多糖分子间能够交联,但交联度不高,证实葛仙米多糖具有柔性的多分支结构。     

第一性原理研究Re的热力学性质

基于准谐Debye-Grüneisen模型,运用第一性原理缀加投影平面波方法研究了Re的热力学性质,拟合了Re的状态方程,计算了Re不同压强下弹性模量、吉布斯自由能、焓、熵、热容和体膨胀系数随温度的变化关系。结果表明:采用八阶Birch-Murnaghan方程拟合得到的Re压强-体积曲线与实验测量结果吻合较好;计算的零压下吉布斯自由能、焓、熵、热容和体膨胀系数随温度的变化均与实验值符合较好;在零压,50、100、150和200GPa压强下,Re的弹性模量和吉布斯自由能随温度升高而减小;焓、熵随温度升高而增加;Re的电子等容热容随温度线性增加,晶格振动等容热容在低温下符合3T幂次规律并随温度增加而迅速增大,且在高温时逐渐接近Dulong-Petit极限;预测的德拜温度约为430K,与实验结果一致。