Determination of Discrete-Structure Parameters of Coatings with Allowance for Residual Stresses

The authors suggest that the dimensions of a discrete section of a coating should be chosen on the basis of calculation of the critical crack spacing in cohesion cracking. This approach allows for residual stresses in the coating. The reliability of the calculation method has been verified experimentally by direct measurement of the crack spacing.     

薄膜包衣技术及应用

对薄膜包衣技术及其在制剂生产中应用的研究进展作一综述。     

Synthesis and Evaluation of Blends Formed by Polymeric Crown Ethers and a Fullerene-Containing Primary Ammonium Salt in Organic Thin Films

The synthesis of a series of polymers and cyclopolymers bearing crown ethers of differing structure and affinities towards primary ammonium ions is discussed. These polymers have been tested in their efficiency to form structurally homogeneous thin films when blended with an amphiphilic C₆₀ compound containing a primary ammonium ion functional group. The X-ray reflectivity characterization of the films revealed that the polymer bearing the crown ether with the least affinity for primary ammonium ions, but having the highest degree of polymerization, is the most effective in forming structurally homogeneous thin films.     

Thermal Conductivity Measurement of an Electron-Beam Physical-Vapor-Deposition Coating

An industrial ceramic thermal-barrier coating designated PWA 266, processed by electron-beam physical-vapor deposition, was measured using a steady-state thermal conductivity technique. The thermal conductivity of the mass fraction 7 % yttria-stabilized zirconia coating was measured from 100 °C to 900 °C. Measurements on three thicknesses of coatings, 170 μm, 350 μm, and 510 μm resulted in thermal conductivity in the range from 1.5 W/(m·K) to 1.7 W/(m·K) with a combined relative standard uncertainty of 20 %. The thermal conductivity is not significantly dependent on temperature.     

Ideally selective diisocyanate building blocks: New perspectives for dendrimers and coating binders

Using zirconium (IV) salts as catalyst, the reaction of a diisocyanate carrying one tertiary and one primary isocyanate group (IMCI, DIMP) with alcohols can be conducted with complete regioselectivity. This unique selectivity enables the use of a diisocyanate building block in unprecedented ways. Incomplete regioselectivity of diisocyanates, as commonly encountered in currently commercial ones like IPDI and TDI, inevitably leads to polydisperse products in reaction with polyols. The ultimate monodisperse polymer architecture, dendrimers, can now be made in a facile, straightforward manner using IMCI as the ideal diisocyanate building block. Coating applications of this unique building block are not restricted to these perfect branching polymers, but also include isocyanate-functional coating resins. Without any increase in polydispersity, a hydroxyl-functional polyester can be end-capped with the IMCI diisocyanate and subsequently serve as a crosslinker in powder coatings.     

In situ polymerization and characterization of polyester‐based polyurethane/nano‐silica composites

Polyester‐based polyurethane/nano‐silica composites were obtained via in situ polymerization and investigated by Fourier‐transform infrared spectroscopy (FTIR), or FTIR coupled with attenuated total reflectance (FTIR‐ATR), Transmission electron microscopy (TEM), atomic force microscopy (AFM), an Instron testing machine, dynamic mechanical analysis (DMA) and ultraviolet‐visible spectrophotometry (UV‐vis). FTIR analysis showed that in situ polymerization provoked some chemical reactions between polyester molecules and nano‐silica particles. FTIR‐ATR, TEM and AFM analyses showed that both surface and interface contained nano‐silica particles. Instron testing and DMA data showed that introducing nano‐silica particles into polyurethane enhanced the hardness, glass temperature and adhesion strength of polyurethane to the substrate, but also increased the resin viscosity. UV‐vis spectrophotometry showed that nano‐silica obtained by the fumed method did not shield UV radiation in polyurethane films. Copyright © 2003 Society of Chemical Industry     

Surface structural change of ZnO-coated LiNi0.5Mn1.5O4 spinel as 5 V cathode materials at elevated temperatures

LiNi_0.5Mn_1.5O₄ powder was synthesized via sol-gel method and coated with ZnO in order to test the electrochemical cyclability of the material as a cathode for the secondary Li battery in the 5 V range at 55 °C. The ZnO-coated LiNi_0.5Mn_1.5O₄ powder nearly maintained its initial capacity of 137 mA h g⁻¹ after 50 cycles whereas the uncoated powder was able to retain no more than 10% of the initial capacity after 30 cycles. TEM analysis of the cycled cathodes suggests that the formation of the graphitic surface phase, hindering the Li migration, may be responsible for the rapid capacity loss of the uncoated material while no such phase was observed on the surface of the ZnO coated LiNi_0.5Mn_1.5O₄ powder.     

埋地管道三层PE外覆盖层及其检测方法研究

文章介绍了埋地管道三层PE外覆盖层系统的构造参数和性能特点,论述了两种用于埋地钢质管道外覆盖层状况检测的方法,一种是多频管中电流法,另一种是DCVG/CIPS组合检测技术。分别介绍了两种方法的工作原理、操作方法和设备,并结合工程实例进行了说明。这些方法和设备可分别或同时用于管道不开挖检测防腐层破损点的位置以及漏点大小。     

纳米涂层的研究现状与展望

简述了纳米表面涂层制备工艺的研究现状，分析了气相沉积、热喷涂、电刷镀、化学镀和电沉积等不同工艺在制备纳米表面层中的应用情况。介绍了纳米涂层在超硬耐磨、耐腐蚀、耐高温热稳定性等方面研究的新进展，并对纳米涂层的应用范围和领域作了展望。