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51.
52.
Hossein Mohammadifard Seyyed Sina Banifatemi 《Chemical Engineering Communications》2016,203(9):1165-1172
Many studies have been conducted to study the various polymorphs and morphologies of calcium carbonate crystals in nature and living organisms. In this experimental work, a novel method has been employed to crystallize calcium carbonate by using colloidal gas aphron dispersion. The polymorph and morphology of prepared particles were investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectrometry techniques. SEM and XRD analyses demonstrated that the morphology of synthesized CaCO3 can be changed from spherical (vaterite phase) to novel rod and plate-like shapes (mixture of vaterite and calcite phases) with changes in the surfactant concentration. The quantitative examination results of different calcium carbonate polymorph orientations showed that the precursor concentrations had no significant effect on the orientation of calcite phase, but rather they affected the orientation development of vaterite phase at a higher surfactant concentration. 相似文献
53.
《Ceramics International》2020,46(8):11689-11697
In this research, vapor phase transport (VPT) was introduced as a facile, inexpensive method to produce ZnO micro/nanostructures from various Zn sources such as pure Zn and alpha brass pre-alloyed powders (Cu–20Zn and Cu–28Zn) at different processing temperatures of 930 °C–1050 °C. Simultaneous thermal analysis (STA) was carried out to investigate Zn evaporation and ZnO micro/nanostructure formation. STA results showed an exothermic peck at 711 °C and 728 °C for Cu–20Zn and Cu–28Zn, respectively, due to oxidation of the evaporated Zn element and formation of ZnO micro/nanostructures. X-ray diffraction results showed that high purity ZnO micro/nanostructures were successfully synthesized via VPT process and the crystallite size was increased from ~60 nm to ~100 nm with increasing processing temperature. Field emission scanning electron microscopy observations showed morphology (e.g. rods, column, tetrapods, and combs) and size of the synthesized micro/nanostructures were dependent on the Zn sources and processing temperature, in which average diameter of the synthesized ZnO structures was increased with increasing the processing temperature. The smallest (98 nm) and largest (603 nm) average diameters of synthesized ZnO micro/nanostructures were attained from the pure Zn and Cu–28Zn brass powders at 930 °C and 1050 °C, respectively. 相似文献
54.
Using the extrusion blown film process, we obtained linear low density polyethylene (LLDPE)/ethylenevinyl alcohol copolymer
(EVOH) blends with an improved barrier property by generating a laminar structure of the dispersed phase in the matrix phase.
This laminar morphology induced by drawing and blowing was found to result in a significant decrease in toluene permeability
with only 10 wt% EVOH. Effects of compatibilizer content and processing parameters such as blending sequence, screw configuration,
and stretch ratio on the toluene permeability and morphology of the blends were investigated. It was revealed that the optimum
amount of compatibilizer, maleic anhydride grafted LLDPE, should be used to improve the barrier property of the LLDPE/EVOH
blends with a well developed laminar structure. The blending sequence had a significant influence on the permeability of the
blends. The blend films exhibited a more pronounced laminar structure when all blend components were simultaneously melt blended
in a single screw extruder. In addition, the screw configuration designed to impart a low shear stress and the balanced stretching
in the machine and transverse directions were more favorable processing conditions in obtaining high barrier blends. 相似文献
55.
Yidong Hou 《Powder Technology》2010,203(3):440-160
Nanostructured β-Ga2O3 samples were prepared by a combination of the solvothermal processes and subsequent heat treatments. β-Ga2O3 samples with various morphologies were obtained by using different kinds of solvent, including water, isopropanol and ethylene glycol. One-dimensional β-Ga2O3 nanorods were obtained in water medium, while β-Ga2O3 spheres were prepared in alcohol. The possible mechanism related to the phase formation and morphology of the as-prepared materials was discussed. Photocatalytic performance of the synthesized β-Ga2O3 samples was also examined. Results revealed that β-Ga2O3 sample prepared with ethylene glycol showed the highest photocatalytic activity for the degradation of salicylic acid. This could be ascribed to the high surface area, abundant hydroxyl groups, and wide band gap of β-Ga2O3 sample synthesized in ethylene glycol. 相似文献
56.
ABS/PC/MMA类共聚物Q三元共混体系的性能和形态 总被引:3,自引:0,他引:3
本文研究了ABS/PC甲基丙烯酸甲酯(MMA)共聚物Q三元共混物的性能与Q含量的关系,对不同Q含量下共混物的拉伸、冲击、弯曲、耐热、熔体指数等性能进行了测试,并用扫描电镜观察了该三元共混物的形态。结果表明,加入共聚物Q可增加共混体系的相容性,在适当组成下可使共混物的弯曲强度提高到原来的1.7倍,同时其他力学性能有所提高或不受损失;共混物的熔体指数能符合工业生产要求。从经济角度看,Q价格也较低。因而ABS/PC/Q三元共混物可望开发为具有重要实际意义的塑料合金。 相似文献
57.
Rapid pyrolysis was conducted in a drop tube reactor using seven coals under various operating conditions. In addition to dense char, porous chars (network char and cenospheric char) were formed by the rapid pyrolysis under certain conditions. Porous char was mainly composed of film-like carbon and skeleton carbon. The pyrolyzed coal char particles were characterized in detail. Morphology and bulk density of porous char were quite different from the dense char formed under the same conditions, but elemental composition and BET surface area were similar to each other. CO2 gasification reactivity of porous char was lower than dense char in the later gasification stage, and this was ascribed to the low reactivity of skeleton carbon. 相似文献
58.
从改善低铬白口铸铁碳化物形貌出发,研究了稀土变质处理和热处理的作用。结果表明:综合运用稀土变质处理和热处理是改善低铬白口铸铁共晶碳化物形貌、提高综合力学性能的有效途径。 相似文献
59.
60.
Qingli Hao Wu Lei Xifeng Xia Zhenzhen Yan Xujie Yang Lude Lu Xin Wang 《Electrochimica acta》2010,55(3):632-640
Mobile counter anion exchange of electropolymerized polyaniline (PANI) films with the anions in acid solutions has been investigated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), scanning electron microscopy, Raman, UV-vis, and fluorescence spectra. The studied acids include camphorsulfonic acid, p-toluene sulfonic acid, HCl, HClO4, H2SO4 and H3PO4. In two cases of small and large counter ions of PANI films, CV tests have been performed alternately three times in each of two electrolytes containing organic or inorganic acid. The investigation of electrochemical and spectrophotometric measurements reveals that large counter anions can be easily replaced by the small anions; and the reverse exchange also occurs, but shows very low efficiency. This indicates that the achieved anion exchange in both cases leads to the remarkable alteration in electrochemical behavior and electrical conductance of PANI films. This implies counter anions, whatever the original or redoping ones, play an important role in the electrical, electrochemical, even optical properties of PANI. However, the polymer morphology does not be changed after exchange tests. This allows us to point out a ‘morphology-memory’ effect which is very significant for the development and application of PANI films with the same morphology and different properties. 相似文献