Immobilization of a cyclodextrin glucanotransferase (CGTase) onto polyethylene film with a carboxylic acid group and production of cyclodextrins from corn starch using CGTase‐immobilized PE film

Carboxylic acid groups were introduced onto polyethylene (PE) film by radiation‐induced graft copolymerization. Subsequently, the clodextrin glucanotransferase (CGTase) was immobilized on the PE film with a carboxylic acid group. The activity of the immobilized CGTase on PE film was in the range of 0.40–1.04 U/cm² per min. The production of cyclodextrins (CDs) from corn starch was examined using the CGTase‐immobilized PE film. The production ratios of CDs using CGTase‐immobilized PE film was in the following order: α–CD > β–CD > γ–CD. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2451–2457, 2002     

Role of sand on curing of partex surface by UV radiation

A partex surface was modified by a UV‐curing system with epoxy acrylate (EB‐600). A set of formulations was prepared with oligomer and the trifunctional monomer trimethylol propane triacrylate in different combinations of percentages (1–5%) of sand to study the role of sand in various physical properties of UV‐cured thin films, as well as partex surfaces. Increased pendulum hardness (PH), gloss, adhesion, and abrasion values were obtained by the addition of sand into the partex surfaces. The best results were obtained with the formulation containing 3% sand. An enhanced PH and a decreased percentage of gel content of the UV‐cured film was observed with an increase of the sand concentration. A simulated weathering test was performed with partex surfaces cured by a formulation containing 3% sand in the base coat. The losses of the physical properties were found to be lower over the surface treated with the formulation containing sand. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2385–2392, 2002     

Competitive removal of Pb2+, Cd2+, and Zn2+ by poly(acrylamide‐co‐maleic acid) hydrogels/differential pulse polarographic determination

Poly(acrylamide‐co‐maleic acid) [P(AAm/MA)] hydrogels, with various compositions, were prepared from ternary mixtures of acrylamide (AAm)/maleic acid (MA)/water by using ⁶⁰Co γ‐rays. The effect of composition of these hydrogels, on the competitive removal of Pb²⁺, Cd²⁺, and Zn²⁺ ions from aqueous solution, was investigated. The hydrogel compositions and their adsorption behaviors were determined by use of differential pulse polarography, a very sensitive electroanalytical technique. It was observed that the external stimuli of pH, temperature, and ionic strength have an important role on the adsorption. The increments of MA content in P(AAm/MA) hydrogels caused a significant increase in the adsorption these ions. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2401–2406, 2004     

南京地区固定式安装太阳能电池板最佳倾角设计

对于固定安装的光伏电池板,其倾角的选择直接影响到所接收到的太阳辐射量,从而决定着太阳能利用系统的性能。本文在获得南京地区辐射资料的基础上,采用太阳辐射量气象学模型,针对任意方位角固定式安装的光伏电池板给出了最佳倾角的计算结果。该结果可为南京地区太阳能系统的设计与安装提供理论依据,并为相近地区太阳辐射量计算提供参考。     

吸收剂量对二甲基硅橡胶与甲基乙烯基硅橡胶分子量和凝胶含量的影响

将ＧＰＣ和特性粘数［η］测定相结合，在室温和－７８℃下，用Ｃｏ~（６０）辐射源辐照，研究了二甲基硅橡胶（ＭＱ，吸收剂量２．０５×１０~３～３．９７×１０~４Ｇｙ）和甲基乙烯基硅橡胶（ＭＶＱ，吸收剂量１０~２～１０~４）分子量和凝胶含量的变化。结果表明，辐照ＭＶＱ较辐照ＭＱ易生成凝胶，在凝胶点前的较低吸收剂量时，溶胶的分子量出现极大值，分子量分布曲线呈单峰；随吸收剂量的增加，分子量分布变窄，分子量降低；出现凝胶的吸收剂量，ＭＱ大约是ＭＶＱ的１０倍。辐照ＭＱ时，凝胶点前的溶胶的分子量分布曲线为双峰，并随吸收剂量的增加，双峰消失，分子量下降；在凝胶点时，分子量出现极大值。     

柔软热收缩材料的研制

总结了经共混和辐射交联制备柔软耐老化的热收缩材料的研制过程。测得了不同乙丙橡胶含量和不同辐照剂量下的共混物的力学性能和凝胶含量，确定了共混物辐射交联的合适剂量。此外，还测试了ＥＰＤＭ和ＰＥ共混物经辐照后的耐油性能。在此基础上，制得了手感柔软的热收缩管材。     

无机纳米材料的改性及其在纺织工业中的应用

选用硬脂酸和钛酸丁酯对纳米级ZnO，TiO2和无机抗菌粉体进行表面处理，使硬脂酸和钛酸丁酯包覆于粉体表面，不但解决了粉体的团聚问题，而且将粉体的表面由极性变为非极性，能很好地与纤维表面相结合。加入这类粉体生产的织物，经测试达到了较好的抗菌和抗紫外线的要求。     

车联网中基于雾计算和多TA的条件隐私保护认证方案

车联网在生活中扮演着越来越重要的角色,它可以有效地防止交通拥堵从而减少交通事故。然而,在车联网中总是有非法车辆试图接入车联网并发布虚假消息。此外,现有方案多数存在计算效率低下的问题。针对上述存在的问题进行了研究,提出了一种车联网中基于雾计算和多TA的条件隐私保护认证方案。在保护车辆用户身份的条件下实现了车辆、雾节点、TA三者之间的身份认证,且在车辆追踪阶段可以还原车辆用户的真实身份,从而实现条件隐私保护。雾计算的使用降低了方案的计算和通信开销,同时多TA模型的使用也解决了单TA单点故障的问题。安全性证明和性能分析的结果表明该方案是安全且高效的。最后对当前方案进行了总结以及对未来研究作出了展望。     

核工业专用橡胶型可剥掩蔽涂料的研制和应用

介绍了核电、核能工业专用橡胶型可剥掩蔽涂料的研制和应用,选用新型含有苯基的聚丁二烯弹性体为基料,加入耐酸、耐辐照的颜填料和防黏剂、偶联剂及N-13a固化剂配成JF系列常温固化的核电、核能工业专用橡胶型可剥掩蔽涂料,该涂料耐酸碱、耐辐照,防污性能优良。     

Radiation-induced copolymerization of trioxane with tetrahydrofuran

Radiation-initiated copolymerization of solid trioxane (TOX) with tetrahydrofuran (THF) was investigated. The effects of radiation dose, THF concentration, and post-polymerization temperature and duration on copolymer yield and THF incorporation were studied. These results are compared with the results of TOX homopolymerization under identical conditions. Copolymer yield was lower than that of homopolymer. Only a fraction of charged THF entered into the polymer chain. THF content and radiation dose also altered the MW of the copolymer but it showed better thermal stability. The initial reaction rates of the copolymerization were determined and from these the activation energy was found to be 36.2 kcal mol^?1.