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11.
The dye-sensitized TiO2 complex films were prepared by the dye coat onto TiO2 surfaces,and the sensitizing mechanism and adsorption properties of the dye-sensitized TiO2 complex films were inverstigated.The influence of the application conditions of dye adsorbed on TiO2 films on the amount of dye adsorption was discussed.Experimental results show that the concentration,the temperature of dye solutions and the dipping time of TiO2 films in the dye solutions have a significant influence on the amount of dye adsorption.Cell test indicates that the conversion efficiency of light to electricity increases with the amount of dye adsorption. 相似文献
12.
13.
S. Abiraman H. K. Varma T. V. Kumari P. R. Umashankar Annie John 《Bulletin of Materials Science》2002,25(5):419-429
This study investigates quantitatively and qualitatively the sol-gel derived bioactive glass-ceramic system (BGS)—apatite-wollastonite
(AW) type granules in the size range of 0.5–1 mm, as an effective graft material for bone augmentation and restoration. Scanning
electron micrographs (SEM) of the sintered granules revealed the rough material surface with micropores in the range 10–30
μm. X-ray diffraction (XRD) pattern of the granules revealed the presence of crystalline phases of the hydroxyapatite and
wollastonite, and the functional groups of the silicate and phosphates were identified by Fourier transform infrared spectroscopy
(FT-IR). Thein vitro cell culture studies with L929 mouse fibroblast cell line showed very few cells adhered on the BGS disc after 24 h. This
could be due to the highly reactive surface of the disc concomitant with the crystallization but not due to the cytotoxicity
of the material, since the cellular viability (MTT assay) with the material was 80‰ Cytotoxicity and cytocompatibility studies
proved that the material was non-toxic and biocompatible. After 12 weeks of implantation of the BGS granules in the tibia
bone of New Zealand white rabbits, the granules were found to be well osteointegrated, as observed in the radiographs. Angiogram
with barium sulphate and Indian ink after 12 weeks showed the presence of microcapillaries in the vicinity of the implant
site implicating high vascularity. Gross observation of the implant site did not show any inflammation or necrosis. SEM of
the implanted site after 24 weeks revealed good osteointegration of the material with the newly formed bone and host bone.
New bone was also observed within the material, which was degrading. Histological evaluation of the bone healing with the
BGS granules in the tibial defect at all time intervals was without inflammation or fibrous tissue encapsulation. After 2
weeks the new bone was observed as a trabeculae network around the granules, and by 6 weeks the defect was completely closed
with immature woven bone. By 12 weeks mature woven bone was observed, and new immature woven bone was seen within the cracks
of the granules. After 24 weeks the defect was completely healed with lamellar bone and the size of the granules decreased.
Histomorphometrically the area percentage of new bone formed was 67.77% after 12 weeks and 63.37% after 24 weeks. Less bone
formation after 24 weeks was due to an increased implant surface area contributed by the material degradation and active bone
remodeling. The osteostimulative and osteoconductive potential of the BGS granules was established by tetracycline labelling
of the mineralizing areas by 2 and 6 weeks. This sol-gel derived BGS granules proved to be bioactive and resorbable which
in turn encouraged active bone formation. 相似文献
14.
Strategies to increase CdTe solar-cell voltage 总被引:1,自引:0,他引:1
There is a significant difference in performance between today's highest efficiency of CdTe solar cells and single-crystal cells of comparable band gap. The largest contribution to this difference is the voltage, where the values for the best CdTe cells are about 230 mV below the best GaAs cells when an appropriate adjustment is made for band gap. CdTe voltage and fill-factor are currently compromised by low recombination lifetime (near 1 ns), low hole density (near 1014 cm− 3), and in some cases an excessive back-contact barrier. Numerical simulation is used to evaluate how combinations of lifetime, carrier density, back electron reflection, and interfacial properties affect voltage and cell performance. Two different strategies for improving voltage and performance are explored. 相似文献
15.
晶体硅薄膜电池制备技术及研究现状 总被引:2,自引:0,他引:2
晶体硅薄膜太阳电池近些年来得到广泛的研究和初步的商业化探索。根据所采用的晶体硅薄膜沉积工艺中温度范围的不同,晶体硅薄膜电池研究可分为高温路线和低温路线两个不同发展方向。本文分别从这两个方向综述了目前国外晶体硅薄膜电池制备技术的最新进展,最新实验室研究结果。报导了晶体硅薄膜电池商业化进展状况,指出了晶体硅薄膜电池实现产业化必须解决的问题。 相似文献
16.
光催化氧化后四环素的分解率与COD去除率之间关系的探讨 总被引:1,自引:0,他引:1
以粉状无机半导体(ZnO)为催化剂,探讨了水溶液中四环素经光催化氧化分解率和COD去除率之间的关系。实验表明,在本实验中四环素的分解率和COD去除率之间有较好的正相关性。当反庆系统中有足量的活性催化剂和足够的光照时间时,绝大部分四环素将被较彻底地氧化分解成CO2,这不仅有助于光催化反应机理的研究,助于今后在环保中的实际应用。 相似文献
17.
用电刷镀的方法,对尺寸为2000mm×1000mm×0.8mm 的 A_3钢板电刷镀锌保护层;并对影响镀锌层质量的因素进行了充分的研究。 相似文献
18.
The synthesis of rare-earth perovskite-type composition thin films of LaNiO3 by means of the inorganic-sol-gel (ISG) method was studied. The structural stability under high temperature in reducing atmospheres and the oxygen-sensitivity mechanism of the LaNiO3 thin films were examined. It is shown that under the experimental conditions, LaNiO3 decomposes and the valance states of nickel are +2 and +3. 相似文献
19.
Lanthanum doped nickel and YSZ composite anode (LaNi–YSZ) exhibited a greatly reduced polarization resistance and high performance for electrochemical oxidation of hydrogen and methane, which resulted from a fine anode structure with a high dispersion of nickel catalyst and a high catalytic activity towards methane. 相似文献
20.