Synthesis of Hexagonal‐Phase NaYF4:Yb,Er and NaYF4:Yb,Tm Nanocrystals with Efficient Up‐Conversion Fluorescence

IR‐to‐visible up‐conversion fluorescent nanocrystals of hexagonal‐phase NaYF₄:20 %Yb,2 %Er and NaYF₄:20 %Yb,2 %Tm have been synthesized by decomposition of multiprecursors of CF₃COONa, (CF₃COO)₃Y, (CF₃COO)₃Yb, and (CF₃COO)₃Er/(CF₃COO)₃Tm in oleylamine at 330 °C. The average particle size is 10.5 ± 0.7 nm (from random measurements of 200 particles from five transmission electron microscopy images) and 11.1 ± 1.3 nm (from dynamic‐light‐scattering measurements). The up‐conversion fluorescence intensity of the hexagonal nanocrystals in this work is much higher than that of other cubic‐phase NaYF₄:Yb,Er nanocrystals, including the ones in this work (by a factor of 7.5). Mechanisms for nucleation and growth of the hexagonal‐phase nanoparticles are proposed. These nanocrystals are easily dispersed in organic solvents, producing a transparent colloidal solution. The hydrophobic surfaces of the particles are made hydrophilic using a bipolar surfactant. These nanoparticles and their dispersions in various media have potential applications in optical nanodevices and bioprobes.     

厦门市气源转换的技术分析

分析了气源转换时原有输配系统的管道、调压设备、计量设备、用气设备与天然气系统相适应的问题，提出了相应的措施。     

LD泵浦Nd：YVO4内腔倍频激光器获得120mW绿光连续输出

利用半导体激光器（ＬＤ）端面泵浦Ｎｄ：ＹＶＯ＿４和用ＫＴＰ内腔倍频的绿激光器获得了１２０ｍＷ连续、稳定的５３２ｎｍ绿激光输出。泵浦阈值Ｐ＿（ｔｈ）＝１６０ｍＷ，光－光转换效率η＿ｓ＝８．１％。换用激光腔输出耦合镜，在不加ＫＴＰ晶体倍频时，可连续输出１．０６μｍ的红外激光，输出功率为４５０ｍＷ，光－光转换效率为３１％。     

Probing acid sites in MAPO-36 by solid state NMR

An ordering of magnesium is observed in the as-synthesized MAPO-36 molecular sieve. Upon calcination, part of the magnesium is removed from the sample and part occupies extraframework positions thus rendering a random distribution of magnesium in the lattice. The shoulder observed in the³¹P spectrum of the calcined sample is assigned to P(3Al, 1Mg) sites in conflict with the earlier assignment to P-OH groups. The bridging hydroxyl groups located at these sites are detected in the¹H MAS spectrum at 3.6 ppm. Further, MAPO-36 catalyzed acetone conversion to mesityloxide that cracked at elevated temperature to yield acetic acid and aliphatics.     

Volumetric three‐dimensional up‐conversion display medium

Abstract— Several rare‐earth‐doped fluoride crystals that are excited to emit visible light by sequential two‐photon absorption have been investigated as display‐medium candidates for static volumetric three‐dimensional displays. Dispersion of powders of these materials in a refractive‐index‐matched polymer is reported because such a medium may result in a scalable display. The scattering problem in such a medium is greatly reduced by index‐matching the polymer to the crystalline particles. An index‐matching condition that optimizes the performance is identified.     

A simplified cascade current‐source inverter interconnected to a single‐phase three‐wire distribution system and its application to electric energy storage systems with batteries

A novel current source inverter system interconnected to the single‐phase grid is proposed. It has the same construction as the conventional three‐phase current source inverter that is interconnected to the single‐phase three‐wire distribution system. Though the proposed circuit has no output transformer, it can be equivalently performed as the single‐phase double cascade inverter by diverting the pole transformer in the utility system. By controlling the appropriate scheme, the output currents can be obtained as the five‐level waveforms and their distortions can be decreased sufficiently. It is applied to the interactive electric energy storage system with batteries and the basic discharging characteristics are discussed experimentally. © 2004 Wiley Periodicals, Inc. Electr Eng Jpn, 150(2): 50–61, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10380     

后工业时代米兰单功能城区更新

在物化的形式上,解释米兰城市发展历史上的单功能城区的改造意义,并由此分析单功能城区更新的经验:单功能城区向混合居住模式的更新是发展方向;城区的功能重新定义对城区发展有重要意义;以新的建设为基础,发展城区自身的特色,做到城市在更新和特色之间的协调。     

应用于矿井LED电子显示牌的点阵式绘图软件设计

针对矿井LED电子显示牌采用矢量图技术绘图存在的图形绘制不精确、可视性差等问题,提出一种可应用于不同型号电子显示牌的点阵式绘图软件设计方案,介绍了该软件的总体设计及BMP图像的灰度化步骤。点阵式绘图软件基于组件的设计理念,实现了所见即所得的绘图功能、文字点阵转换功能、BMP图片导入/转换功能、ICO图标导入/导出功能、模拟显示功能及对外通用接口功能。比较发现,采用点阵式绘图软件绘制的原始图形及实际显示效果均明显好于采用矢量图技术绘制的图形。     

SVG的3D实现

针对SVG在3D图形的描述与绘制上存在局限性的问题,提出了一种SVG的3D实现方法;详细介绍了SVG的2D坐标系到3D坐标系的转换原理,给出了转换到3D坐标系后的SVG-3D图形的绘制与操控流程,并以在3D场景中绘制一个正立方体和圆球体为例,介绍了在HTML页面中采用JavaScript创建3D场景和绘制与操控这2个图形的实现。     

Report on a new OED project: A study of the history of new words in the new OED

The study of the history of new words in theNewOED described in this paper was undertaken in 1986-87, and is based on the material then available. Since then, theNewOED has been finished, and PAT, the inquiry system developed at the University of Waterloo for the investigation of theNewOED data base, has been much altered and improved. Nevertheless, this report should prove useful in indicating the potentiality for analyzing the computerizedNewOED and some of the problems. This project is a study of the ways in which new words are created in English at various periods of time. A chronological dictionary 's created listing words introduced into the language over 50 year increments. These words are then classified by the processes used in forming them to show, in proportional terms, if certain processes are more common at some times than at others.H. M. Logan, Associate Professor, Department of English, University of Waterloo, Waterloo, Ontario, Canada, has written The Dialect of the Middle English Life of St. Katherine (Mouton, 1973), making use of the computer in a study of medieval dialectology. He has also written articles on computer stylistics and literary analysis inCHum, ALLC Journal, Language and Style, College Literature, and on the dictionary inDictionaries.