下喷自吸环流反应器中气-液局部相际传质模型

引言 下喷自吸环流反应器是在结合喷射、环流、自吸等优点基础上而开发出的一种新型高效反应器,开展该反应器内局部气液传质模型的研究,对于该反应器的优化设计及放大具有极重要的理论意义.多年来,经典传质理论的不足与局限都在经历不断的修正与改进.其中,激光多普勒测试在传质研究中的应用使得人们对湍流在传质中的重要性有了     

基于深度学习的恶意文档可视化检测

为了更加准确、快速地检测恶意PDF与DOCX格式文档,提出一种基于深度学习的恶意文档可视化检测方法。该方法通过马尔可夫模型将文档的字节序列转化为三通道的彩色图,从而获取更能区分恶意文档和良性文档的视觉表征,并采用当前主流的EfficientNet-B0模型对提取的可视化特征进行分类。结合迁移学习领域中的微调技术,将ImageNet上的分类权重应用到EfficientNet-B0模型的训练中,加快检测模型的收敛速度,缩短模型的训练时间。实验证明,在两个数据集上,模型的收敛速度快于随机初始化权重的预训练,且模型对恶意PDF文档和恶意DOCX文档的检测准确率分别达到了99.80%和98.14%,优于ResNet34、MobileNetV2等模型。与主流的恶意文档检测工具Wepawet和PJScan相比,所提出的方法具有更优的综合检测性能,进一步验证了所提出方法对恶意文档检测的有效性。     

基于特征融合的调制识别增强与迁移演化

针对调制识别中单一图像的特征信息不足,区分度不够高,识别范围受限的问题。本文提出了一种基于时频图和星座图特征融合的调制识别特征增强方法,利用深度学习神经网络提取信号图像的特征,构建特征空间,通过多维特征融合,挖掘和整合不同特征的优势,增强模型算法的鲁棒性。此外运用了模型迁移的方法,仅需对分类器进行训练,大幅节约了训练时间和资源,具有很强的实时性和实用性。仿真结果显示,在0db左右的条件下,相比于单一特征图像,采用特征融合增强的方法能将信号的平均识别率提高约25%,通过模型迁移,省去了卷积神经网络的训练,所需的训练时间约为迁移前的9.6%,消耗内存约为迁移前的7.3%,同时模型的识别率损失控制在了5%以内。     

Mass transfer coefficients of styrene and oxygen into silicone oil emulsions in a bubble reactor

The absorption of oxygen and styrene in water-silicone oil emulsions was independently studied in laboratory-scale bubble reactors at a constant gas flow rate for the whole range of emulsion compositions (0-10% v/v). The volumetric mass transfer coefficients to the emulsions were experimentally measured using a dynamic absorption method. It was assumed that the gas phase contacts preferentially the water phase. In the case of oxygen absorption, it was found that the addition of silicone oil hinders oxygen mass transfer compared to an air-water system. Decreases in k_La_oxygen of up to 25% were noted. Such decreases in the oxygen mass transfer coefficient, which imply longer aeration times to transfer oxygen, could represent a limiting step in biotechnological processes strongly dependent on oxygen concentration. Nevertheless, as the large affinity of silicone oil for oxygen enables greater amounts of oxygen to be transferred from the gas phase, it appears that the addition of more than 5% silicone oil should be beneficial to increase the oxygen transfer rate. In the case of styrene absorption, it was established that the volumetric mass transfer coefficient based on the emulsion volume is roughly constant with the increase in the emulsion composition. In spite of the relatively high cost of silicone oil, water-silicone oil emulsions remain relevant to treat low-solubility volatile organic compounds, such as styrene, in low-concentration gas streams.     

能效优先的用户关联与功率控制协同优化机制

在异构蜂窝网络中,针对系统的能效,提出了一种基于效用函数最大化模型的用户关联与功率控制协同优化方案,该方案表示为非线性混合整数问题。为了求得该问题的最优解,设计了一种迭代算法,首先将原问题转换为带参数的多项式形式的问题,在外层循环利用Dinkelbach方法求得最佳的能效因子,然后在内层循环分别求得最佳的用户关联矩阵和传输功率。最终实验结果表明,用户关联与功率控制协同的优化方案在能效和负载平衡方面比固定功率条件下的用户关联策略的性能更优。     

离子化对SBS/聚(苯乙烯-甲基丙烯酸甲酯)热塑性互穿聚合物网络结构与力学性能影响的研究

采用原子转移自由基聚合（ATRP）法合成了聚（苯乙烯一甲基丙烯酸甲酯）[P（St—MMA）]，采用两步法制备了SBS／P（St—MMA）热塑性互穿聚合物网络（TIPN）。在双螺杆挤出机上通过熔融挤出方法对SBS／P（St—MMA）直接进行水解，制备了含有离子键的SBS／P（St—MMA）TIPN。离子化后TIPN的拉伸强度明显增加，在离子化程度为25％时达到最大，断裂伸长率明显下降。TIPN的中PB和PS嵌段的Tg均明显增加，PS嵌段增加更加明显，提高20℃；弹性模量E’均明显提高。     

Effect of Impurities on the Syndiospecific Coordination Polymerization of Styrene

Summary: The effect of impurities on the coordination polymerization has generally been classified and discussed in different ways and has been investigated in detail in the syndiospecific homo‐ and copolymerization of styrene. With regard to impurities of styrene, phenylacetylene as an unpolar impurity containing separate multiple bonds, 1‐phenyl‐1,2‐ethanediol and ω‐hydroxyacetophenone as examples of polar impurities, and ethylbenzene as an other unpolar impurity have been investigated regarding the effect on the polymerization rate and the influence on the molecular properties of the syndiotactic polystyrenes. In the syndiospecific copolymerization with p‐methylstyrene, indene shows a different behavior regarding the decrease of the polymerization conversion depending on the comonomer concentrations present in the monomer mixture. Additionally, the effect of impurities of the catalyst system on the syndiospecific styrene polymerization has been demonstrated, particularly of octahydrofluorene as a component of the transition metal compound and of trimethylaluminium as a component of the cocatalyst methylaluminoxane. All results have been discussed with respect to the mechanisms of the effects on polymerization behavior and on polymer properties.

Dependence of the relative polymerization conversion on the amount of indene added to the monomer mixture in styrene (ST)/p‐methylstyrene (PMS) copolymerization (catalyst n‐ratio: 0.5; molar ratio MAO:Ti = 110:1; polymerization temperature: 60 °C; polymerization time: 45 min).     

相转移催化合成蔗糖硬脂酸酯

采用相转移催化的基本原理和方法合成蔗糖硬脂酸酯,考察了反应时间、反应温度、原料的不同配比和催化剂用量对蔗糖硬脂酸酯产率的影响,得出反应时间为3 h,反应温度为95-100℃、硬脂酸甲酯与蔗糖的摩尔比为1:2.5,硬脂酸甲酯与PTC之比为1:0.07时为最佳配比。     

基于加权的无人机集群组网分簇算法

在无人机集群组网中,节点的高速移动会造成网络拓扑结构更新频繁,使网络管理变得更加复杂。分簇能够增大网络容量,实现空间资源的复用,是优化网络管理的有效手段之一。针对大规模、高速移动的环境进行了研究,提出了一种多参数加权分簇算法。该算法将最大速度相似度分簇算法中的分簇指标引入到加权分簇算法中,并且对链路保持率、节点度差、节点剩余能量进行改进,综合考虑这四种参数,通过加权组合的方式选举具有最大权重的网络节点作为簇头。仿真结果表明,该分簇算法不仅能够减少簇的数量和簇间切换率,提高分簇的稳定性,而且能够延长最小节点生存时间,改善网络的整体续航能力。     

CO2在全氟羧酸离子交换膜内促进传质特性的研究

本文以全氟羧酸离子交换膜为支撑体、乙二胺(EDA)为活性络合剂、制备促进传质膜。在常用的工业条件下,测定了纯CO_2以及CO_2/N_2二元混合物在该膜内的渗透通量。实测结果表明,此膜对CO_2的促进因子可达13.8,而对CO_2/N_2的分离因子高达316。本文假设促进传质过程的控制步骤为气体在膜相的扩散,据此导出了相应的机理模型,该模型与实测结果吻合良好。