GeS2-Ga2S3-PbCl2硫系玻璃光学及析晶特征的研究

采用熔融-淬冷法制备了GeS2-Ga2S3-PbCl2系列样品玻璃,测试了样品从可见到中远红外的透过光谱和不同升温速率下的DTA曲线,用Kissinger法计算了析晶活化能E和晶体生长指数n.结果表明:该系列玻璃具有较宽光谱,引入PbCl2使玻璃的短波截止波长蓝移,长波截止基本不变.玻璃具有较好的热稳定性,以体积晶化一维生长方式.其中,90 (0.85GeS2-0.15Ga2S3) -10 PbCl2玻璃具有最大的析晶活化能E=134.44 kJ·mol-1,可作为研究硫系玻璃基质与微晶玻璃非线性效应的理想材料.     

MicroJet Reactor Technology: An Automated,Continuous Approach for Nanoparticle Syntheses

A new design of a confined impinging jet microreactor has been applied for continuous‐flow syntheses of metal chalcogenide nanomaterials. The microjet reactor is an automated, flexible, scalable, and thus industrially viable technology allowing a strict control over process parameters for the design of materials with tunable properties. Due to the short mixing times in the µs to ms range, crystallite nucleation and crystal growth are well separated and enable concentration‐limited particle growth and thus nanoparticle synthesis. The first approaches on the microjet reactor setup presented here were focused on the synthesis of nanocrystalline Ta‐doped tin dioxides and cadmium sulfide nanoparticles. The nanomaterials were characterized by a number of methods like powder X‐ray diffraction and conductivity measurements.     

硫系玻璃红外光纤

本文简述了硫系玻璃的种类、性质以及硫系玻璃原料的常用几种提纯方法,概括介绍了玻璃的熔制以及光纤和传像束的制备方法,并讨论了硫系玻璃光纤在民用、医学、军事领域上的应用及发展前景.     

若干硫系玻璃黏度变化速率的结构起源探索

用熔融淬冷法制备Ge33 As12 Se55、Ge22 As20 Se58、Ge10 As40 Se50、As40 Se60、Se硫系玻璃,采用流变仪测试样品黏弹状态的黏度,计算各样品黏度的Vogel-Fulcher-Tammann方程和黏度变化速率(即料性).结合拉曼光谱,根据玻璃微观结构对料性的影响规律进行系统分析...     

Cd(Zn,S)Se quaternary thin films for electrochemical photovoltaic cell application

In this study, Cd_1−xZn_xS_ySe_1−y (0 ≤ x = y ≤ 0.35) photoelectrodes are deposited via inexpensive facile chemical bath deposition. The effects of Zn and S doping on the compositional, microstructural, electrical, and optical properties of thin films were analysed. The electrochemical photovoltaic (EPV) cell of configuration Cd_1−xZn_xS_ySe_1−y/0.25M sulfide/polysulfide/C was assembled to examine the different performance parameters in light and in dark conditions. An EPV cell fabricated with the Cd_1−xZn_xS_ySe_1−y (0 ≤ x = y ≤ 0.075) photoelectrode exhibited a maximum photoconversion efficiency of 3.18%. This performance can be attributed primarily to the enhanced light-absorption ability of the material because of the enhanced rough microstructure and low recombination of photo-injected electrons with the electrolyte. The photovoltaic (PV) performance is significantly enhanced after doping CdSe with Zn and S.     

Large third-order optical nonlinearity of chalcogenide glasses within gallium-tin-selenium ternary system

We explore the third-order optical nonlinear properties of arsenic- and germanium-free chalcogenide glasses (ChGs) within a gallium-tin-selenium (Ga-Sn-Se, GSS) ternary system at wavelength of 1.064 μm in the picosecond region. A classical characterization showing the values of the absorption and the linear index will be given. Then, using D4σ-Z-scan technique, both nonlinear refractive index (n₂) and nonlinear absorption coefficient (β) of the GSS ChGs will be measured. A comparison of the results is made with other families of chalcogenide glasses considering the figure of merit calculation. The first results show that GSS system would give better NL performance promising high potential for n₂(β)-based photonic devices performed under clean production and green/sustainable chemistry.     

Multifunctional device with an integration of light emitting,photo detective,and energy harvesting

In this work, we present a multifunctional device based on a heterojunction active layer formed between the halide perovskite and chalcogenide quantum dots. The device is demonstrated with an integration of proof‐of‐concept functions, including a voltage controllable multicolor light‐emitting diode, an efficient energy harvesting device, and a photosensitive detector. The concept of the heterojunction active layer provides a feasible route to design efficient multifunctional devices in the future.     

透红外硫系玻璃微压印工艺的仿真研究

为了获得更好的微压印工艺填充效果,利用有限元方法研究模压工艺的主要参数压印温度、压印力和压印时间对压印效果的影响,并对工艺参数进行优化;对压印过程中不同的模具结构的应力分布进行了研究.仿真结果表明,工艺参数优化为480℃,30N,1800s后,模具的填充率达到97.2%;对不同的模具结构,有相同的应力分布区域,在模具拐...     

柔性硫系玻璃红外光纤传像束的制备与性能测试

讨论了红外光纤传像束的学术意义和制备工艺,制备了一种硫系玻璃红外光纤传像束并进行了专门的性能测试。选用As40S58Se2、As40S60作为芯棒和皮管玻璃组分,采用管棒法拉制成纤,利用人机结合的排丝工艺制备出了单丝直径为50μm,纤芯直径为40μm,576元正方形排列的红外光纤传像束。搭建了相应的实验测试平台,对光纤束排列规则度、断丝率、光学效率及传像束引起系统调制传递函数(MTF)下降量等指标进行了测试。测试表明,传像束断丝率为2.7%,衰减损耗低于0.5dB/m,光学效率约为31%,在红外光纤传像系统中光纤传像束引起的MTF下降量小于10%。最后,利用研制的红外传像束完成了红外成像实验,结果表明,红外光纤传像束能够实现良好的红外成像。     

全光开关用硫系玻璃研究进展

随着人类社会步入高速信息时代,高速的通讯信息系统对材料性能提出了更高要求。详细分析了全光开关器件对非线性光学材料性能的要求,综述了硫系玻璃作为全光开关器件用材料性能方面的优势,并总结了近年来人们对硫系玻璃在全光开关应用方面的研究成果。