09CuPTiRe耐候钢冶炼技术研究

介绍新标准条件下耐候钢09CuPTiRe试制情况。及该种钢新标准的内容、冶炼要点、工艺装备等。试制成品各项性能指标符合新标准的要求，同时结合工艺参数对冶炼结果、成品质量进行了分析。     

灰关联度综合评价法及在大气环境质量评价中的应用

以灰色系统理论为基础，提出了以层次分析法进行赋权的灰色加权关联度综合评价法。经大气实例分析表明，该方法可较好地反映出环境系统的灰以性特征，使评价结果更为客观，合理。     

用MODIS影像反演环渤海地区的大气水汽含量

主要介绍通过遥感影像来反演大气水汽的算法，两通道比值法和三通道比值法。并用环渤海地区的MODIS影像对该地区的水汽进行了反演。     

Mineralogy of clean coal combustion by-products

Coal combustion technologies are changing in order to burn coal more cleanly. Many “clean combustion“ and postcombustion technologies are developed to remove SO2 and NOx gases, particulate matter during combustion, or from the flue gases leaving the furnace. This paper focuses on three types of fly ash (flue gas desulfurization (FGD) residuals, atmospheric fluidized bed combustion (AFBC) residuals and sorbent duct injection (SDI) residuals) which produced by “the clean combustion“ and postcombustion technologies. The residuals formed by FGD are PCFA (pulverized coal fly ash) grains entrained with reacted and unreacted sorbent and have lower bulk densities than PCFA grains because it contains higher concentrations of calcium and sulfur, and lower concentrations of silicon, aluminum and iron than PCFAs. AFBC residuals consist of spent bed which is a heterogeneous mixture of coarse-grained bed material and irregularly shaped, unfused, spherical PCFAs. The main crystalline phases in AFBC residuals are anhydrite (reacted sorbent), quartz and lime (unreacted sobent), calcite, hematite, periclase, magnetite and feldspars.The residuals produced by SDI contained 65%-70% PCFA with the larger sizes material being irregularly shaped, fused or roughedged. The reaction products of sorbent (portlandite and lime) included calcium sulfate (anhydrite) and calcium sulfate. The chemical properties of these residuals are similar to those of high calcium PCFAs because of the high alkalinity and high pH of these residuals.     

基于高精度星敏感器的船载雷达海上精度鉴定

航天测量船海上航行时主要通过精度校飞进行雷达精度鉴定,针对其周期长、耗费大和组织协调困难的缺点,提出了一种采用高精度星敏感器与雷达捷联跟踪测量空间目标进行海上精度鉴定的方法。雷达在跟踪空间目标的同时,星敏感器实时拍摄天线指向附近星图。首先,星敏感器利用雷达输出的编码器角度计算视轴的初始指向,通过快速星图识别和目标定位获取天线地心坐标系精确指向;然后,经坐标变换到地平系,根据蒙气差模型修正地平系俯仰角,再经过船摇修正转换到甲板坐标系;最后,进行轴系误差及脱靶量修正,实现雷达指向精度鉴定。试验结果表明:利用该方法测量的船载雷达相对于星敏感器方位、俯仰随机残差优于50″,满足雷达精度鉴定要求,证明该方法的可行性。     

Mass spectrometry of atmospheric aerosols--recent developments and applications. Part I: Off-line mass spectrometry techniques

Many of the significant advances in our understanding of atmospheric particles can be attributed to the application of mass spectrometry. Mass spectrometry provides high sensitivity with a fast response time to probe chemically complex particles. This review focuses on recent developments and applications in the field of mass spectrometry of atmospheric aerosols. In Part I of this two-part review, we concentrate on off-line mass spectrometry techniques, which require sample collection on filters but can provide detailed molecular speciation. In particular, off-line mass spectrometry techniques utilizing tandem mass spectrometry experiments and high resolution mass analyzers provide improved insight into secondary organic aerosol formation and heterogeneous reaction pathways through detailed structural elucidation at the molecular level.     

南京市冬季市区和郊区晴天大气边界层结构对比分析

应用2008年12月24—31日南京市区和郊区同步大气边界层观测资料,对晴天大气边界层结构进行对比分析．结果表明：南京地区冬季晴天,市区近地面层气温高于江北郊区近地面层的气温,市区热岛效应明显,且热岛强度夜间大于白天;市区逆温出现的时间滞后于郊区,逆温层高度也大于郊区．夜间,市、郊区风速随高度不断增大,并在一定的高度出现一个8m／s的极值中心．市区空气相对干燥．通过典型日分析,市区14：00干岛效应显著,相同高度上相对湿度一直低于郊区．在市、郊区近地面层中,愈近地面风速愈小;近地面层中白天风速最大,夜间最小;白天,大气层结不稳定,湍流混合作用强,上下层风速的差别趋于减小．市区风速在低层受建筑物影响．相同高度上小于郊区风速．     

石英晶体微天平原位研究铝的大气腐蚀

目的研究NaCl,（NH4）：SO4,Na2SO4和NH4Cl的潮解性能及其沉积铝的大气腐蚀行为,揭示盐的潮解性对铝腐蚀的影响规律．方法在温度25℃±1℃,相对湿度80％±2％的净化空气中,采用石英晶体微天平（QCM）在镀金的石英晶片上研究了NaCl,（NH4）2SO4,Na2SO4和NH4Cl的潮解性．在温度25±2±1℃,相对湿度80％±2％的净化空气和含SO2的气氛中,用石英晶体微天平（QCM）研究了盐沉积后铝的腐蚀行为,通过扫描电子显微镜、X射线能谱仪、傅立叶红外光谱手段进行表征．结果发现NH4Cl的潮解性能最强,其后依次为（NH4）2SO4,NaCl,Na2SO4．铝在含SO2的气氛中的腐蚀比在净化空气中严重,并且经NH4Cl沉积的铝腐蚀最为严重,接着依次为（NH4）2SO4,NaCl,Na2SO4．盐沉积后,铝在盐沉积区开始腐蚀,然后扩展到其他区域．结论经盐沉积后铝腐蚀的程度与盐的潮解性能有关,潮解性能越大,腐蚀越严重．对腐蚀产物结构的测定,在含SO2的气氛中铝的腐蚀产物主要是由硫酸盐组成。因而其腐蚀较为严重．     

Initial corrosion behaviors of AZ91 magnesium alloy in the presence of SO2

The effects of SO2 on the initial atmospheric corrosion of AZ91D magnesium alloy were investigated in laboratory. Met-allographic observation, SEM (Scanning Electron Microscopy), XRD (X-ray Diffraction) and XPS (X-ray Proton Spectrograph) were used to analyze and discuss the initial surface morphology of corrosion layers and corrosion products. The corrosion rate of the alloy increases with increasing the content of SO2. The initial attack has the characteristics of localized corrosion and preferentially concentrates on a phase. MgO and Mg(OH)2 form at first, which provide a protective layer, then the existence of SO2 decreases the pH of the thin solution on the alloy, accelerates dissolution process, and promotes the formation of MgSO3·6H2O and MgSO4·6H2O, meanwhile cracks were found on the corrosion products with corrosion continuation. These soluble corrosion products and the cracks provide the paths for filtering oxygen and corrosion pollutants into the matrix, which results in severe localized co     

瑞利激光雷达探测中层大气密度和温度

利用瑞利（Rayleigh）散射激光雷达探测中层大气密度和温度的原理和方法,能够探测30~90 km范围的中层大气密度和温度的垂直分布。根据这种方法和实际测量得到的数据,把反演得到的结果与标准大气模型CI-RA86观测结果进行了对比,凸显具有较好的一致性。在一般情况下,30~65 km高度范围内激光雷达获得的大气密度与CIRA86密度偏差≤5%;温度偏差〈3 k,而在75 km以上温度偏差较大。