中频数字化及数字式正交解调

本文介绍用数字式下变频法实现中频正交解调的基本原理及主要性能。     

Impurity Distribution Behavior in Caprolactam Extraction with Environmentally Benign Mixed Solvents

In a previous study a solvent mixture of heptane containing 40 mass % heptanol was selected as an alternative in the industrial extraction of caprolactam to replace benzene, toluene, or chlorinated hydrocarbons. This work reports the equilibrium distribution ratio of caprolactam and four model impurities of organic nature, namely, cyclohexanone, aniline, n‐methylcaprolactam, and cyclohexane‐carboxamide, comparing the mixed solvents with toluene as a reference. The resulting phase equilibria were interpreted using the equilibrium stage model. Based on these calculations it was found that, compared to toluene, the co‐extracted fraction of cyclohexanone and aniline was higher, that of n‐methylcaprolactam was comparable, and that of cyclohexane‐carboxamide was lower using the mixed solvent. Overall, the mixed solvent reduced the fraction of co‐extracted impurities by almost 10 %.     

Studies on the corrosion behavior of cerium-implanted zircaloy-4 with GAXRD

In order to study the influence of cerium ion implantation on the aqueous corrosion behavior of zircaloy-4, specimens were implanted by cerium ions with a fluence range from 1×10¹⁶ to 1×10¹⁷ ions/cm² at maximum 150°C, using MEVVA source at an extracted voltage of 40 kV. The valence and elements penetration distribution of the surface layer were analyzed by X-ray photoelectron spectroscopy (XPS) and auger electron spectroscopy (AES) respectively. Glancing angle X-ray diffraction (GAXRD) was employed to examine the phase transformation due to the cerium ion implantation in the oxide films. Three-sweep potentiodynamic polarization measurement was employed to value the aqueous corrosion resistance of zircaloy-4 in a 1 N H₂SO₄ solution. It was found that a significant improvement in the aqueous corrosion behavior of zircaloy-4 implanted with cerium ions compared with that of the as-received zircaloy-4. The improvement effect will declined with raising the implantation fluence. The bigger is the fluence, the less is the improvement. Finally, the mechanism of the corrosion behavior of the cerium-implanted zircaloy-4 is discussed.     

TCA785移相控制芯片应用方法的改进

TCA785是德国西门子公司生产的一种性能优秀的移相控制芯片 ,该器件具有温度适应范围宽 ,对过零点的识别更加可靠 ,输出脉冲的整齐度更好 ,移相范围更宽等优点 ,此外 ,由于TCA785的输出脉冲宽度可以手动自由调节 ,因此 ,该器件可广泛应用在晶闸管控制系统中。文章根据TCA785芯片的使用特点以及在逆变器实际运用中可能出现的一些问题 ,提出了一种改进的设计方法     

Ni_(2.5)Mo_6S_(6.7)在有机电解液中的充放电特性

利用循环伏安法、交流阻抗法和充放电曲线等方法测定了Ni_(2.5)Mo_6S_(6.7)电极在1M LiClO_4,PC DME(1:1)有机电解质溶液中的可充电性。结果表明,该材料具有高的可充电性,有可能用作二次锂电池的正极材料。     

Synthesis of Nearly Monodisperse Iron Oxide and Oxyhydroxide Nanocrystals

Uniform magnetite, hematite, and goethite nanocrystals were prepared through an attractive method based on an oleic acid/alcohol/water system. By adjusting the synthetic parameters (base concentration, alcohol content, categories of alcohols, etc.), the controlled synthesis of uniform magnetite, hematite, and goethite nanocrystals can be easily achieved. Detailed investigations on the effect of the experimental parameters on the morphology of the final products and the phase transitions among the magnetite, hematite, and goethite phases were carried out. Finally, a method of doping other metal ions into magnetite was developed and the magnetic properties of magnetite doped with different metal elements were studied.     

Phase equilibrium in solutions of star-shaped macromolecules: an improved Okada-Numasawa model

The two-region Okada-Numasawa model for solutions of star-shaped polymers has been improved by means of a change in the integration order and introduction of a concentration-dependent and molar-mass-dependent Flory-Huggins interaction parameter (the second and third approximations of the Flory-Huggins theory). To overcome calculation difficulties, a special algorithm for computing coexistence curves of polymeric systems with an UCST has been used. The agreement between the experimental and calculated coexistence curves for the star-shaped polystyrene (PS)-cyclohexane system has been improved: the difference between T_cs is ∼0.33 K against ∼12 K as given by the original model.     

纳米SnO_2固体的相变内耗和模量

系统测量了不同颗粒尺度纳米 SnO_2固体的内耗和模量,发现60℃附近存在一个内耗峰,对应的模量出现异常.烧结温度升高,峰高变化不明显,模量异常减弱.当烧结温度高于400℃时,模量曲线在-15℃附近出现异常,这种模量异常随烧结温度升高而加强,对应的内耗曲线出现一小峰.初步认为,60℃附近内耗峰和模量异常与纳米固体中的结构再有序有关,而-15℃处的模量异常为结构相变引起.     

Modeling the continuous melt transesterification of bisphenol-A and diphenyl carbonate in a continuous stirred tank reactor

A model of continuous melt transesterification of bisphenol-A and diphenyl carbonate in a continuous stirred tank reactor is developed using phase equilibria assumption and the method of molecular weight moments. The model equations can be simplified into a polynomial system that has 17 equations and 17 unknowns. Solution of the polynomial system gives out almost every aspects of the continuous transesterification process. Molecular weight and polydispersity index, end group ratio of hydroxyl to phenyl carbonate, contents of molecular species, and lost diphenyl carbonate fractions are studied in different operation parameters.     

不甩线圈的多星形移相变极

对于某些槽数和极数比的多星形移相变极电机,提出与前人不同的是在两种极数下均不甩去线圈的绕组方案,使绕组利用率高,且线圈及其联接都较简单.这种绕组方案在一种极数下并联支路略有不平衡,其所引起的电机定子铜耗的增加是极其有限的,不致影响电机的正常运行.