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91.
Alloys of Pd-Au-Sn and Pd-Cu-Sn systems were investigated using metallography,electron microprobe,X ray diffraction and DTA.Partial isothermal sections were plots at 800oС and 500oС.Ternary τ-phase having tetragonal structure has been established in each systems.The region of existence of phases in equilibrium with the solid solution based on palladium. 相似文献
92.
《Calphad》2021
Metallic coatings can improve the high temperature resistance of superalloys serving in the gas turbines. In general they are Al–Co–Cr–Ni alloys with small Y additions to improve oxide scale adherence.In order to complete the construction of a thermodynamic database for coatings, thermodynamic assessments of four ternary systems have been performed by means of the CALPHAD method, namely Al–Co–Y, Al–Ni–Y, Al–Cr–Y and Co–Ni–Y. All of the experimental phase diagrams and thermodynamic data available in the literature were critically reviewed. The liquid, fcc, bcc and hcp phases were modeled as substitutional solutions. The order-disorder model has been adopted to describe the A1/L12 and A2/B2 phase relations. A series of ternary compounds have been modeled during the present work according to the crystal structure or composition. As a result a satisfactory agreement was obtained between our calculations and the experimental data used in the assessment.Finally, interaction parameters calculated in this work have been merged in the thermodynamic database for the simulation of Al–Co–Cr–Ni–Y alloys. This has been validated by comparing our calculations with experimental data regarding selected Ni-based and Co-based alloy coatings. 相似文献
93.
《Calphad》2019
The C-Co-Mo-W and C-Mo-Ni-W quaternary systems have been critically evaluated by means of the CALPHAD approach, in which the Co-Mo-W system was readjusted to ensure the model consistency. The thermodynamic models of Gibbs energies for individual phases in the ternary and quaternary systems are described, including substitutional solution model, sublattice model and linear compound model. The modeling covers the whole temperature and composition ranges, and a set of self-consistent thermodynamic parameters for the C-Co-Mo-W and C-Mo-Ni-W quaternary systems is obtained. According to the comprehensive comparisons between the reported and calculated phase diagram data, the reliable equilibria information is satisfactorily accounted for by the modeling. Based on the present work together with the previously reported assessments of binary, ternary and quaternary sub-systems, a thermodynamic database for the C-Co-Mo-Ni-W quinary system is constructed and applied to calculate the sintering region phase equilibria of the (W,Mo)C-(Co,Ni) cemented carbides. 相似文献
94.
O.A. Kornienko O.R. Andrievskaya O.I. Bykov A.V. Samelyuk Yu. M. Bataiev 《Journal of the European Ceramic Society》2021,41(6):3603-3613
According to the results of the samples studied by X-ray diffraction and microstructural analyzes the phase equilibria in the binary La2O3 – Sm2O3 and ternary ZrO2 – La2O3 – Sm2O3 systems were studied. The boundaries of the phase fields of the binary system are specified and an isothermal cross section of the ternary state diagram of the ZrO2 – La2O3 – Sm2O3 system at a temperature of 1500 °C is constructed. No new phases have been identified in the studied systems. It is established that in the ternary system ZrO2 – La2O3 – Sm2O3 at 1500 °C fields of solid solutions on the basis of cubic (F) modification with structure of fluorite type, tetragonal (T) modification of ZrO2, monoclinic (B) modifications of Sm2O3, hexagonal (A) are formed. La2O3, as well as an ordered phase with a structure of the type of pyrochlore Ln2Zr2O7 (Py). The boundaries of the phase fields and the parameters of the unit cells of the formed phases are determined. A characteristic feature of this isothermal cross section is the formation of a continuous series of solid solutions based on the phase of the pyrochlore type La2Zr2O7 (Sm2Zr2O7). The limiting solubility of Sm2O3 in the ordered phase La2Zr2O7 is 16 mol. % along the section Sm2O3- (67 mol.% ZrO2 - 33 mol.% La2O3). The solubility of La2O3 in the solid solution Sm2Zr2O7 is slightly less and is 11 mol. % along the section La2O3- (67 mol.% ZrO2 - 33 mol.% Sm2O3). The isothermal cross-section of the state diagram of the ZrO2 – La2O3 – Sm2O3 system at 1500 °C is characterized by the presence of three three-phase (Py + T + F), (A + Py + B), (Py + F + B) and eight two-phase (A + Py), (B + A), (B + Py), (F + B), (T + F), (Py + T), (F + Py-two) areas. 相似文献
95.
《Ceramics International》2022,48(11):15124-15135
Phase equilibria of the PbO-“FeO”-SiO2-ZnO, PbO-“FeO”-SiO2-Al2O3 and PbO-“FeO”-SiO2-MgO slags with liquid Pb metal, solid or liquid Fe metal and solid oxides (cristobalite and tridymite SiO2, willemite (Zn,Fe)2SiO4, wustite (Fe,Al)O1+x, spinel (Fe,Al)3O4, olivine Fe2SiO4, corundum (Al,Fe)2O3, mullite Al6Si2O13 and pyroxene (Mg,Fe)SiO3) were investigated at 1125–1670 °C. These conditions correspond to the minimum solubility of PbO in slag in presence of Pb and Fe metals at reducing conditions and represent the limit of lead smelting and slag cleaning process. High-temperature equilibration on silica, corundum or iron foil substrates, followed by quenching and direct measurement of Pb, Fe, Si, Zn, Al and Mg concentrations in the liquid and solid phases with the electron probe X-ray microanalysis (EPMA) was used. Present data can be used to improve the thermodynamic models for all phases in this system. 相似文献
96.
《Calphad》2020
Phase equilibria in the ternary Cu–Zr–Si system at 750 and 900 °C have been experimentally investigated via electron probe micro-analyzer (EPMA) and X-ray diffraction (XRD) analysis on the equilibrated alloys. The results show the presence of eight three-phase regions at 750 °C and seven three-phase regions at 900 °C. Four ternary phase: τ1 (Zr3Cu4Si6, tI26-Zr3Cu4Si6), τ4 (Zr3Cu4Si4, oI22-Gd3Cu4Ge4), τ5 (ZrCuSi, oP12-Co2Si), and τ6 (Zr3Cu4Si2, 2hP9-Fe2P) were confirmed to exist in the Cu–Zr–Si ternary system at 750 and 900 °C. At 900 °C, the dark gray phase, the chemical composition of which is close to η-Cu3Si, is confirmed to be the liquid phase. Moreover, the solubilities of Cu in ZrSi2, SiZr and Zr3Si2 are considerably small. The solubility of Zr in η-Cu3Si is determined to be negligible. The newly determined phase equilibria of the Cu–Zr–Si system in this work can provide important experimental data for the thermodynamic assessment of the Cu–Zr–Si system and to develop the Cu–Zr–Si alloys and related transition metal silicides. 相似文献
97.
98.
99.
Václav Doležal Ladislav Nádherný Kateřina Rubešová Vít Jakeš Alena Michalcová Ondřej Jankovský Morgane Poupon 《Ceramics International》2019,45(9):11233-11240
Polycrystalline LaMgAl11O19 (LMA) was prepared by four different non-hydrolytic sol-gel methods. From stable solutions, four powder precursors containing an amorphous and nanocrystalline phase with specific reactivity were obtained. The particle size, morphology, thermal behaviour, and phase composition of the powder precursors were studied using DLS, TEM, DSC/TG and XRD. Bulk ceramic samples containing LMA were prepared at 1200?°C for 16?h and examined in terms of phase purity and microstructure using XRD, SEM, and TEM. Raman spectroscopy of pure LMA was used to study the structure in detail. A mechanism of LMA formation and a relation between powder precursor properties and final phase composition is proposed. These findings may be useful for designing modern technologies for fabrication of LMA for optical or protective coating applications. 相似文献
100.
A generalized approach for the calculation of complex chemical and phase equilibria is presented that is based on the simulation of the dynamic evolution of a mixture from non-equilibrium initial composition towards the final equilibrium composition. The proposed method is able to solve pure chemical or phase equilibria as well as simultaneous chemical/phase equilibria. The advantage of our approach compared to conventional equilibrium calculations is the fact that the approach is physically motivated and can handle chemical and phase equilibria as well as simultaneous chemical and phase equilibria. 相似文献