低熔点Cu-P基中间合金及其变质效果

利用差示扫描量热仪(DSC)、扫描电子显微镜(SEM)和金相显微镜等手段对Cu-P基中间合金进行了研究。结果表明，在二元共晶Cu-P中间合金中加入一定量的Sn可制成低熔点的Cu-16Sn-8P中间合金；在此基础上研制出一种熔点为630℃左右的低熔点的多元Cu-P基中间合金。与Cu-P中间合金相比，该低熔点多元Cu-P基中间合金对过共晶AI-24Si合金具有更好的变质效果。同时，该中间合金对ZL109合金也具有良好的变质效果。     

快速凝固铝硅合金粉末加热过程中硅颗粒的粗化行为

利用差示扫描量热仪(DSC)、电子显微镜等设备对Al-12.8%Si合金粉末的原始状态及热处理后的状态进行了分析。发现其显微组织有两个连续的变化过程:在156℃时,固溶在基体Al中的过饱和Si开始析出,并在340℃发生粗化,随着加热温度的升高,粗化现象仍然存在。另外,对Si颗粒的粗化机理进行了研究,发现其粗化符合经典的LSW理论。     

Zr41.5Ti14Cu13Ni10Be22.5大块非晶的耐蚀性能

用浸泡法研究了ZrTiCuNiBe大块非晶合金在酸、碱、 盐各种腐蚀性介质中的腐蚀行为.并与典型材料做了比较，结果表明：ZrTiCuNiBe大块非晶合金具有良好的耐蚀性.     

EFFECT OF COMPOSITION ON HYDROGEN EMBRITTLEMENT IN Ni-Fe FCC ALLOYS

The ductility loss and threshold stress intensity,K_(IH)during hydrogen charging were measuredfor pure Ni and four Ni-Fe fcc alloys.The results show that ductility loss in 40Ni60Fe alloyand K_(IH)a 50Ni50Fe alloy have a minimum value.The variations of the amounts of hydride,hydrogen evolution and dislocation structure with composition have been investigated.The va-riation of hydrogen embrittlement susceptibility with composition measured by ductility lossand by K_(IH)or K_(IH)/K_C can be explained by means of the synthetical effects of amount ofhydride,solutionized hydrogen and the extent of dislocation planarity on hydrogenembrittlement susceptibility.     

The internal nitriding behavior of Co-3Cr,Co-3Al,and Co-3Ti (a/o) over the range of 700–1100°C

Internal nitridation of Co containing 3 a/o of either Cr, Al, or Ti was studied over the range of 700–1100° C in NH₃/H₂ (694 ratio). The kinetics of thickening of the reaction zone followed the parabolic rate law, suggesting that solidstate diffusion was rate controlling. Activation energies obtained were 51.2 Kcal/molfor Co-3Cr, 46.6 Kcal/mol for Co-3Ti, and 27.9 Kcal/mol for Co-3Al. XRD showed only CrN, AlN, and TiN. Deep etching revealed that AlN formed hexagonal plates near the surface when formed at high temperature, the precipitates becoming more massive (blocky morphology) near the reaction front. TiN formed elongated dendritic precipitates, whereas CrN tended to form spheroids. The precipitate size varied with temperature, decreasing with decreasing temperature. In some cases, nitriding formed a case but no visible precipitates even at very high magnifications in the SEM. The solubility of nitrogen in cobalt was determined by long-time equilibration and subsequent chemical analyses. The diffusivity of nitrogen in cobalt was determined from measured permeabilities and the experimentally determined solubilities. Mechanisms are discussed, and the behavior of internal nitridation is compared with internal carburization and oxidation in cobalt alloys.     

富集化合金层对铝阳极氧化膜的影响

在铝合金与氧化膜的界面的富集化合金层，对阳极氧化膜的局部和整体结构、膜的组成以及性能有重大影响。因此，对铝合金富集化进行预测很有必要。     

铝合金凝固过程的声发射及氢气析出过程

采用声发射测试技术,对Al-Si和Al-Cu系合金凝固过程进行监测,证实合金在凝固过程中存在声发射现象,表现为两个声发射信号计数率峰,两个峰的总计数都随着合金中气体含量增加而增高。本文对Al-Si,Al-Cu合金系产生声发射现象的机理进行了探讨,同时,借助其它实验手段证实了声发射信号与合金凝固中气体析出有很好的对应性。第一个计数率峰与气泡在枝晶臂间形核相吻合。第二个计数率峰与凝固末期的枝晶间拉裂现象相对应,可能是氢在枝晶间析出和聚集产生高压氢导致的拉裂。     

Observations on the role of oxide scales in high-temperature erosion-corrosion of alloys

The results are presented of exposure to a controlled high-temperature erosive gas stream of a series of alloys, which were selected to represent the range of microstructures and mechanical properties available in commercial high-temperature alloys. Analysis of the kinetic and morphological data suggested that the high-temperature oxidation behavior of a given alloy plays a very important role in determining its erosion-corrosion behavior under the conditions studied. In terms of relative behavior, alloys which are weak but ductile at temperature, and which form tenacious oxide scales, exhibited the highest resistance to high-temperature erosion-corrosion. Simple models were developed to describe the expected interaction between high-temperature oxidation and erosion.     

稀土La对Al-Si合金复合材料凝固组织与溶质偏析的影响

利用挤压铸造法制备了Al2O3/Al-Si-La复合材料;研究了稀土La对复合材料凝固组织以及基体合金凝固时溶质偏析的影响。结果表明,稀土La可细化基体合金的凝固组织,La富集在界面附近,有利于改善铝合金液对氧化铝短纤维的润湿性,但是未发现任何富稀土相在界面上形成。稀土La对基体合金中镁的偏聚没有明显的影响,镁和稀土La均在界面处富集,且它们的分布位置大致近似。