气相色谱法监测氧化钙催化制备生物柴油的反应进度

建立了一种通过检测氧化钙催化制备生物柴油过程中产生的甘油来监测反应进度的方法. 在反应样品中加入草酸、硫酸溶液, 除掉由催化剂引入的钙离子, 释放与氧化钙结合的甘油, 利用气相色谱方法检测甘油的含量. 讨论了实验中加入草酸、硫酸的目的及对结果的影响. 实验结果表明, 此法可用于氧化钙催化制备生物柴油过程中反应进度监测的研究.     

高温氧化-化学发光检测法测定水中总氮

采用高温氧化-化学发光检测法（high temperature oxidation ＆ chemiluminescence, HTO-CL）进行水质总氮（TN）的在线测定。总氮浓度（CN）与化学发光的强度（IN）呈良好的线性关系,线性区间为0．05～100mg／L。对真实水样采用本方法进行测定,其结果与国标方法相符,回收率在90％～110％之间。以本方法为工作原理的TN-2000型总氮测定仪可用于地表水质及污水的在线监测。     

高效凝胶过滤色谱法分离测定豆薯种子蛋白

用高效凝胶蛋白往分离豆薯种子蛋白租提液,结合光电二极管阵列检测器对分离的蛋白峰进行紫外光谱扫描来确认蛋白的纯度,测定了3种蛋白的分子量,采用邻苯二甲醛（OPA）柱后衍生法测定了豆薯种子蛋白的氨基酸含量。     

流动注射-分光光度法测定自来水中游离氯的研究

设计了游离氯流动注射自动在线检测仪,并研究了仪器的最佳测试条件.该仪器采用改进的N,N-二乙基-1,4-苯二胺(DPD)比色原理,通过流动注射进样技术,结合光电转化、数字信号处理及自动化控制技术,克服了DPD分光光度法中手工操作的缺陷,实现了样品分析的自动化.结果证明,此系统的试剂用量少、测定范围宽(0.05～6.00...     

气相色谱-质谱法测定食品中黄樟素及其衍生物含量

建立了调味制品(调味料、番茄酱、酱油、花椒)、饮料(碳酸饮料、乳饮料、果汁)、肉制品(香肠、肉罐头、肉汤)、水果制品(果冻、果酱)、水产品(干鱼肉、鱼罐头、鱼肉泥)、小吃类(油炸薯片、糖果、巧克力)等18种食品中黄樟素、异黄樟素、二氢黄樟素含量的分析方法。样品在氯化钠盐析作用下,经二氯甲烷-乙腈提取,无水硫酸钠-氟罗里硅土柱吸附极性物质和水分。复杂样品需再经PRi ME HLB固相萃取柱(SPE)净化,5%苯基-95%甲基聚硅氧烷毛细管气相色谱柱分离,选择离子质谱技术监测,内标法定量。在最佳实验条件下,3种黄樟素在25~5 000μg/kg范围内呈良好的线性关系,相关系数(r2)≥0.9981,方法检出限(LOD)和定量下限(LOQ)分别为20μg/kg和50μg/kg,3个加标水平的回收率为77.6%~100.9%,相对标准偏差(RSD)为3.7%~13.6%。多种实际样品的测定结果表明,该方法准确可靠,适用于食品中3种黄樟素及其衍生物的定量和定性分析。     

机构投资者参与公司治理监督的非合作对策

本文研究了 n个机构投资者在参与公司治理 ,对公司实施监督的过程中非合作博弈情况 .在 n个机构投资者不卖出股份等相关假设下 ,其非合作博弈结果是 ,持有股份最大机构投资者才会对公司进行监督 ,其他股东采取搭便车策略 .     

A notion of robustness and stability of manifolds

Starting from the notion of thickness of Parks we define a notion of robustness for arbitrary subsets of Rk and we investigate its relationship with the notion of positive reach of Federer. We prove that if a set M is robust, then its boundary ∂M is of positive reach and conversely (under very mild restrictions) if ∂M is of positive reach, then M is robust. We then prove that a closed non-empty robust set in Rk (different from Rk) is a codimension zero submanifold of class C¹ with boundary. As a partial converse we show that any compact codimension zero submanifold with boundary of class C² is robust. Using the notion of robustness we prove a kind of stability theorem for codimension zero compact submanifolds with boundary: two such submanifolds, whose boundaries are close enough (in the sense of Hausdorff distance), are diffeomorphic.     

XRF法定量分析合金薄膜材料的厚度及组成

本文采用ＸＲＦ分析技术，用Ｃ语言设计运算软件，快速和精确地同时检测合金薄膜材料的质量厚度及组成含量，并呆计算合金膜的体积密度和线性厚度，检测结果的相对误差在３％左右。     

Fourier-inversion and wavelet-transform methods applied to X-ray reflectometry and HRXRD profiles from complex thin-layered heterostructures

We show that X-ray scattering techniques can be used for the assessment of individual layer thicknesses inside complicated semi-conductor heterostructures dedicated to the opto-electronic domain. To this end, we propose methods to overcome two main drawbacks coming from: (1) the complexity of the X-ray profiles and, hence the difficulty to use model-dependent tools such as fitting procedures and (2) large dynamics in intensity due to numerous high diffraction superlattice peaks from superlattices which limit the use of the model-independent Fourier-inversion method.We demonstrate first the reliability of the Fourier-inversion method applied to high-resolution X-ray diffraction profiles curve from quantum well infrared photodetectors heterostructures, complementary to the model-dependent fitting tools. Then, a wavelet-transform-based procedure has been successfully used on X-ray reflectometry profiles containing intense SL Bragg peaks.     

Effect of preparation conditions on the optical and physical properties of an epoxy-functional inorganic-organic hybrid material system

A hybrid material system consisting of (3-glycidyloxypropyl)trimethoxysilane, dimethyldimethoxysilane and zirconium(IV) n-propoxide was prepared. The influence of processing parameters including Zr content, UV irradiation and sol ageing on the properties of the resultant thin films was discussed. Refractive index, at 633 nm, and reflectance measurements were performed and near-field waveguide images of the samples were taken. Optical propagation loss measurements, at 633 nm, were studied. Film thickness and cross-sectional scanning electron microscopy images were obtained as a function of process conditions. FT-IR spectroscopy was used to monitor chemical reaction pathways in the system during processing. It was demonstrated that the crosslinking of epoxy groups in the structure, along with inorganic network formation as a result of sol-gel reactions, was the primary reason for the changes in the optical and physical properties of the system. As Zr containing species and/or UV irradiation may be employed to crosslink the epoxy groups in the structure, the optical and physical properties of the system can be tuned by optimal combination of these two crosslinking methods, as well as sol ageing process.