全文获取类型
收费全文 | 3100篇 |
免费 | 76篇 |
国内免费 | 104篇 |
学科分类
数理化 | 3280篇 |
出版年
2024年 | 2篇 |
2023年 | 43篇 |
2022年 | 83篇 |
2021年 | 100篇 |
2020年 | 69篇 |
2019年 | 108篇 |
2018年 | 111篇 |
2017年 | 91篇 |
2016年 | 111篇 |
2015年 | 98篇 |
2014年 | 182篇 |
2013年 | 237篇 |
2012年 | 195篇 |
2011年 | 189篇 |
2010年 | 173篇 |
2009年 | 246篇 |
2008年 | 196篇 |
2007年 | 192篇 |
2006年 | 118篇 |
2005年 | 122篇 |
2004年 | 103篇 |
2003年 | 83篇 |
2002年 | 62篇 |
2001年 | 33篇 |
2000年 | 42篇 |
1999年 | 32篇 |
1998年 | 36篇 |
1997年 | 36篇 |
1996年 | 24篇 |
1995年 | 30篇 |
1994年 | 29篇 |
1993年 | 23篇 |
1992年 | 19篇 |
1991年 | 22篇 |
1990年 | 8篇 |
1989年 | 7篇 |
1988年 | 3篇 |
1987年 | 7篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有3280条查询结果,搜索用时 15 毫秒
101.
《Journal of Saudi Chemical Society》2020,24(11):906-914
The aim of this research paper was the preparation of aluminum chloride bonded to silica gel catalyst and its application in the modification of steroidal molecules. Steroidal oxazolidinethiones were prepared using silica-supported aluminum chloride (SiO2-AlCl3) under Microwave irradiation, which is common in organic synthesis to achieve high yields in shorter reaction times. The advantage of this method is that the usual procedure can be carried out without tiring and without a secondary product at the end of the reaction. Physicochemical techniques were used to identify the chemical structure of the prepared oxazolidinethiones. A rationalization of the conversion pathways from steroidal epoxides to oxazolidinethiones is sketched on the basis of current and previous results. Antioxidant activities i.e. DPPH assay, total antioxidant capacity and total reductive capability were performed for steroidal compounds, including reactants, and the results indicated that steroidal oxazolidinethione with acetoxy group had a promising activity among the tested steroids. In correlation with antioxidant activity, a promising steroid derivative was subjected to a molecular docking study for binding to tyrosine kinases, the target protein and showed a negative binding energy −7.8 Kcal/mol suggesting good affinity to the active pocket and can be considered as a better antioxidant in the biological system. 相似文献
102.
Three hydrogen bonding complexes of the gauche‐1PA dimer (GG), trans‐1PA dimer (TT) and mixed dimer (GT) have been calculated for the geometry conformations and excited‐state energies. The electron distribution at the site of C‐O of H‐donor moiety in HOMO transfers to the direction of O‐H of H‐acceptor moiety in LUMO. The hydrogen bond between two 1PAs is the bridge of the intermolecular charge transfer. By the Zhao and Han's excited‐state hydrogen bonding dynamics rule, the first excited‐state hydrogen bonding change has been discussed without optimizing the excited‐state geometry conformations. According to the distinct difference between GT and GG (TT), we concluded that two gauche‐1PA monomers of one dimer are transformed at the same time to two trans‐1PA monomers. 相似文献
103.
R. Malhotra M. R. H. Mandjes W. R. W. Scheinhardt J. L. van den Berg 《Mathematical Methods of Operations Research》2009,70(1):149-169
Feedback fluid queues play an important role in modeling congestion control mechanisms for packet networks. In this paper
we present and analyze a fluid queue with a feedback-based traffic rate adaptation scheme which uses two thresholds. The higher
threshold B
1 is used to signal the beginning of congestion while the lower threshold B
2 signals the end of congestion. These two parameters together allow to make the trade-off between maximizing throughput performance
and minimizing delay. The difference between the two thresholds helps to control the amount of feedback signals sent to the
traffic source. In our model the input source can behave like either of two Markov fluid processes. The first applies as long
as the upper threshold B
1 has not been hit from below. As soon as that happens, the traffic source adapts and switches to the second process, until
B
2 (smaller than B
1) is hit from above. We analyze the model by setting up the Kolmogorov forward equations, then solving the corresponding balance
equations using a spectral expansion, and finally identifying sufficient constraints to solve for the unknowns in the solution.
In particular, our analysis yields expressions for the stationary distribution of the buffer occupancy, the buffer delay distribution,
and the throughput. 相似文献
104.
In this paper we study the Riesz transform on complete and connected Riemannian manifolds M with a certain spectral gap in the L2 spectrum of the Laplacian. We show that on such manifolds the Riesz transform is Lp bounded for all p∈(1,∞). This generalizes a result by Mandouvalos and Marias and extends a result by Auscher, Coulhon, Duong, and Hofmann to the case where zero is an isolated point of the L2 spectrum of the Laplacian. 相似文献
105.
We present an eigen-based high-order expansion basis for the spectral element approach with structured elements. The new basis exhibits a numerical efficiency significantly superior, in terms of the conditioning of coefficient matrices and the number of iterations to convergence for the conjugate gradient solver, to the commonly-used Jacobi polynomial-based expansion basis. This basis results in extremely sparse mass matrices, and it is very amenable to the diagonal preconditioning. Ample numerical experiments demonstrate that with the new basis and a simple diagonal preconditioner the number of conjugate gradient iterations to convergence has essentially no dependence or only a very weak dependence on the element order. The expansion bases are constructed by a tensor product of a set of special one-dimensional (1D) basis functions. The 1D interior modes are constructed such that the interior mass and stiffness matrices are simultaneously diagonal and have identical condition numbers. The 1D vertex modes are constructed to be orthogonal to all the interior modes. The performance of the new basis has been investigated and compared with other expansion bases. 相似文献
106.
This note studies the iterative solutions to the coupled Sylvester-transpose matrix equation with a unique solution. By using the hierarchical identification principle, an iterative algorithm is presented for solving this class of coupled matrix equations. It is proved that the iterative solution consistently converges to the exact solution for any initial values. Meanwhile, sufficient conditions are derived to guarantee that the iterative solutions given by the proposed algorithm converge to the exact solution for any initial matrices. Finally, a numerical example is given to illustrate the efficiency of the proposed approach. 相似文献
107.
In this paper we study spectral sets which are unions of finitely many intervals in R. We show that any spectrum associated with such a spectral set Ω is periodic, with the period an integral multiple of the measure of Ω. As a consequence we get a structure theorem for such spectral sets and observe that the generic case is that of the equal interval case. 相似文献
108.
The quest for higher peak focused intensities and better temporal contrast drives one to improve the design of all possible stages of the chirped pulse amplification (CPA) system. In this paper, we have analyzed the role of dispersion and spectral profile on the temporal shape and contrast ratio of the output pulse of a CPA system. The simulations indicate that an initial sech2 or a Gaussian pulse in the CPA system is best for a good contrast ratio. Incorporating a four-grating based pulse compressor in the CPA system improves the contrast as well as provides the flexibility to compensate the dispersion upto the fourth order. The simulations also detail the effect of spectral profile tailoring on the contrast ratio and peak power. 相似文献
109.
Here we present a simple yet effective gas chromatography-mass spectrometry (GC-MS) identification approach for the detection of heteroatom-containing compounds (HACCs) in petroleum fractions. The MS/AMDIS (Automated Mass Spectral Deconvolution and Identification System) program was used to identify parts per million (ppm) HACC concentrations in petroleum fractions in place of traditional techniques (extraction and standard injection). Polycyclic aromatic sulfur heterocycles (S-PAHs) were used as model compounds to confirm the validity of the AMDIS identifiers, which were compared with extracted results using the off-line X-calibur software. AMDIS was able to identify ppm concentrations of S-PAHs in oil condensate. There was good agreement between experimental and AMDIS identification results for S-PAHs in oil condensate. AMDIS was also used to detect nitrogen-containing compounds (NCCs) and alkylphenols in oil condensate. Our results confirmed the presence of 2-methylbenzothiazole, carbazole, and 2,4-ditertbutyl phenol. In a crude oil sample, AMDIS identification of m/z=191 biomarkers was consistent with empirical results. Therefore, AMDIS can help to reduce the number of experimental steps in identification protocols. 相似文献
110.