求解(H^)=5/3(a^)+(a^)+2/3((a^)2+(a^)+2)量子系统能谱新方法

通过对形如(H^)=5/3(a^)+(a^)+2/3((a^)2+(a^)+2)哈密顿量的分析、还原和改造,给出求解该量子系统量子化能谱的两种新方法.     

氨分子逐级键解离能降低的解释

采用理论计算方法解释了氨逐级解离能降低的现象。计算结果表明,随着N与H原子结合数目的减少,键解离能降低、键长增长;随着N与H原子结合数目的增多,N的2s电子跃迁到N的2p轨道上的几率增大,减小了屏蔽作用;更多电子从H的1s轨道迁移到N的2p轨道,增大了N和H之间的静电作用;单电子或孤对电子与N-H键夹角的增大减小了排斥作用。这3个因素造成NH3的逐级键解离能有降低的趋势。     

欢迎订阅《分子催化》

正《分子催化》是由中国科学院主管、科学出版社出版,由中国科学院兰州化学物理研究所主办的向国内外公开发行的学术刊物.主要报导有关分子催化方面的最新进展与研究成果.辟有学术论文、研究简报、研究快报及进展评述等栏目.内容侧重于络合催化、酶催化、光助催化、催化过程中的立体化学问题、催化反应机理与动力学、催化剂表面态的研究及量子化学在催化学科中的应用等.工业催化过程中均相催化     

量子阱器件的原理和应用

详细地描述了量子阱器件的工作原理，并介绍了它在几个方面的应用。     

THE COMPLETE LANGLANDS PARAMETERS CORRESPONDING TO THE REPRESENTATIONS OF THE CLASSICAL GROUPS WITH INTEGRAL REGULAR INFINITESIMAL CHARACTERS

1.CompleteLanglandsParametersandL-PacketsInthissectionwereviewsomebasicfactsfrom[1].Wedenotethesetsofrealnumbers,complexnumbersandintegersbyR,CandZ,respectively.SupposethatGisaconnectedcomplexreductivealgebraicgroup.WehaveanextendedgrouPGrforG,andvGrisanE-groupforGr.WedenotethesetofLanglandsparametersandthesetofgeometricparametersforvGrbYp(vG')andX(VG'),respectively.ThereisanaturalmapfromP(VG')toX(vG').ItinducesabijectionfromequivalenceclassesofLanglandsparameterstogeometricparamet…     

INITIAL-BOUNDARY VALUE PROBLEM FOR THE UNSATURATED LANDAU-LIFSHITZ SYSTEM

51. IntroductionLet fi C Re (n = 1,2) be a bounded smooth domain. Consider the following nonhomogeneous initial-boundary value problem for the unsaturated Landau-Lifshitz systems offerromagnetic spin chain with Gilbert damping constant afl > 0,where adZ is the exchange constallt, u = (u', u', u'), "o(x) is smooth and satisfies the unsaturated condition, i.e., Ilo(~)I gi constant, and in IVuol' < co, "o(x)IOn = op(x). DenoteW(x) = luo(x)I. We assume 0 < m = mane < M ~ mpxW. Throughout t…     

Quantum Stackelberg Duopoly of Continuous Distributed Asymmetric Information

The minimal quantization structure is employed to investigate the quantum version of the Stackelberg duopoly with continuous distributed asymmetric information, i.e a continuous distribution while the second mover has the first mover has incomplete information that obeys complete information. It is found that the effects of the positive quantum entanglement on the outcomes exhibit many interesting features due to the information asymmetry. Moreover, although the first-mover advantage is counteracted by the information asymmetry, the positive quantum entanglement still enhances the first-mover advantage and improves the first-mover tolerance of the information asymmetry beyond the classical limit.     

色散耦合道光学模型对28Si的核子散射数据分析

在光学势中引入色散关系, 相比于通常的耦合道光学模型, 极大地减少了光学势 参数的个数. 采用基于软旋转子模型的耦合道方法对较轻形变核²⁸Si核的中子和质子散射实验数据进行了计算分析, 拟合得到一组色散光学势参数. 计算的中子总截面、以及中子、质子的弹性与非弹性散射微分截面与实验数据有较好的符合.     

基于实际换热的ORC亚/跨临界综合评价

本文以有机朗肯循环(ORC)跨临界与亚临界工质换热特性最新研究成果为基础,采用热力学指标热源回收(火用)效率,以及经济学中的净现值(NPV)概念,结合换热面积分析,建立了考虑实际换热情况的热力学及经济性模型,更合理、更全面地对亚临界循环与跨临界循环的热力学性能和经济性进行了统一分析,为工程实际中亚临界和跨临界的选择提供...