不可逆三源化学势变换器性能的优化分析

建立受传质和质量漏不可逆性影响的一类三源化学势变换器的新循环模型,分析这些不可逆性对化学势变换器性能的影响,导出性能系数与泵能率间的基本优化关系和其它参数的优化表式,同时确定了化学势变换器一些重要参数的最佳工作区域和性能界限。     

Influence of super-strong magnetic field on the electron chemical potential and β decay in the stellar surroundings

In this paper, considering the quantum effect of electrons in a super-strong magnetic field, the influence of a super-strong magnetic field on the chemical potential of a non-zero temperature electron is analyzed, the rates of β decay under the super-strong magnetic field are studied, and then we compare them with the case without a magnetic field. Here, the nucleus ^63Co is investigated in detail as an example. The results show that a magnetic field that is less than 1010 T has little effect on the electron chemical potential and β decay rates, but the super-strong magnetic field that is greater than 1010 T depresses the electron chemical potential and improves the β decay rates clearly.     

Transition Temperature of Lattice Quantum Chromodynamics with Two Flavors with a Small Chemical Potential

We present the results for the transition temperature of quantum chromodynamics with two degenerate flavors （Nf=2） of Wilson quarks as a function of a small baryon chemical potential μB from Monte Carlo simulations at κ=0.175, κ is the hopping parameter. By using the imaginary chemical potential for which the fermion determinant is positive and the Ferrenberg-Swendsen reweighting method, we perform simulations on lattice 83×4 with 4 being the temporal extent. By analytic continuation of the data to the real chemical potential μ, we obtain the transition temperature for the small chemical potential, and compare our results with others.     

原子的边界半径

本文建议和讨论2了原子大小的一种新量度-原子的边界半径, 经出了边界半径的周期表。对于惰性气体原子和汞原子, 有实验测得的有效半径, 它们与边界半径符合得相当好。原子的边界半径与实验的van der Waals半径有良好的线性关系。因此, 由边界半径可以预言某些原子的有效半径以及van der Waals半径。     

三个热力学偏导数〔U/n〕_(S,V)、〔H/n〕_(S,p)和〔F/n〕_(T,V)等于系统化学势的又一证明方法

对三个热力学偏导数 U n S ,V、 H n S ,p和 F n T ,V等于系统化学势给出了又一种证明方法 .     

Determination of Specific Refractive Index Increment （dn/dc）_μ at a Constant Chemical Potential,for Solutions of Polymer in Mixed Solvents by the GPC Method

A new chromatographic method is described for the determination of specific refractive index increment(dn/dc)μ at a constant chemical potential,for polymer/mixed solvent systems.In this method the(dn/dc)is obtained by measuring the areas of solvated-polymer peaks when the mixed solvent is used as an eluent.Values of(dn/dc)μ for the poly(dimethylsiloxane)(PDMS)-benzene-methanol system,determined by the proposed method are in good agreement with those determined by the conventional dialysis method.The new approach has the advantages of simplicity,fast speed,and high reproducibility.The experimental results for stearic acid-chloroform-methanol system show that this method can also be applied to nonpolymer/mixed solvent systems for the determination of(dn/dc)μ.     

一道物理化学习题的几种解法

从电化学、热力学以及化学势3方面讨论一道物理化学习题的几种解法.     

簇合物(p-H2)N-HCCCN的结构和能量

采用两体作用势模型和遗传算法对簇合物（p-H₂）_N-HCCCN的极小能量结构和能量进行了理论研究.结果表明,20 个para-H₂分子形成HCCCN周围的第一个溶剂层,第一个溶剂层包含三个溶剂环,每个溶剂环都有6 个para-H₂分子,第19和20个para-H₂分子分别聚集在HCCCN分子的N、H原子末端. 进一步计算了（p-H₂）_N-HCCCN的化学势,发现化学势随para-H₂分子个数的增加呈震荡变化.     

基于石墨烯涂覆空心光纤电光调制特性的研究

设计了一种新型的石墨烯-空心光纤可调谐结构, 将石墨烯涂覆在空心光纤的空气孔内表面上, 利用有限元法研究了该结构的电光调制特性. 通过改变石墨烯的化学势可以调控光纤的相位和开关特性, 还可以调谐光纤损耗峰与次峰的位置、强度和宽度. 然而, 空气孔半径和石墨烯层数不会改变开关点和损耗峰与次峰的位置, 只会改变损耗差和损耗峰的强度和宽度, 而且由N 层石墨烯引起的损耗差是单层的N倍. 这是因为石墨烯的介电常数决定了光纤的有效折射率和损耗, 通过改变石墨烯的化学势可以改变石墨烯的介电常数, 而石墨烯的层数和空气孔半径却不会改变石墨烯的介电常数, 但是改变了石墨烯和光的作用强度. 经过参数优化之后, 我们提出一种基于五层石墨烯涂覆空心光纤的电吸收型调制器, 工作在1180–1760 nm波段, 具有小尺寸(5 mm×125 μm)、宽光带宽(580 nm)、高消光比(16 dB)、高调制带宽(64 MHz) 和低插入损耗(1.23 dB) 特性. 研究结果对基于石墨烯的可调谐光纤光子器件的设计和应用提供了理论参考.